Chemicals

Central atom: Vanadium
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
[V(O)(OH₂){N(CH₂CO₂)₃-κN,κ³O}]⊖ Vanadium VN: 4 CN: 6 ON: (IV) EN: 15 O (oxo X₂), OH₂ (aqua), Nta (2,2',2''-nitrilotriacetato-κN,κ³O) Molecular 5-coordinate: trigonal bipyramid (TBPY-5)

[V(O)(OH₂){N(CH₂CO₂)₃-κN,κ³O}]⊖
[V(O)(Opp)] Vanadium VN: 4 CN: 5 ON: (IV) EN: 15 O (oxo ⭀O X₂L), Opp (octphenylporphyrin) Molecular 5-coordinate: square-based pyramid (SPY-5)

[V(O)(Opp)]
trans–[V(O)(OPPh₃)(Acac)₂] Vanadium VN: 4 CN: 6 ON: (IV) EN: 15 O (oxo X₂), OPPh₃ (triphenylphosphane oxide), Acac (acetylacetonato) Molecular 6-coordinate: octahedron (OC-6)

trans–[V(O)(OPPh₃)(Acac)₂]
mer–[V(O)(Ox)(N₂C₃H₄)₃] Vanadium VN: 4 CN: 6 ON: (IV) EN: 15 O (oxo X₂), Ox (oxalato), N₂C₃H₄ (Imidazole) Molecular 6-coordinate: octahedron (OC-6)

mer–[V(O)(Ox)(N₂C₃H₄)₃]
[V(O)(Pc)] Vanadium VN: 4 CN: 5 ON: (IV) EN: 15 O (oxo ⭀O X₂L), Pc (phthalocyaninato) Molecular 5-coordinate: square-based pyramid (SPY-5)

[V(O)(Pc)]
trans–[V(O)(Py)(Acac)₂] Vanadium VN: 4 CN: 6 ON: (IV) EN: 15 O (oxo X₂), Py (pyridine), Acac (acetylacetonato) Molecular 6-coordinate: octahedron (OC-6)

trans–[V(O)(Py)(Acac)₂]
trans–[V(O)(PzH)(Acac)₂] Vanadium VN: 4 CN: 6 ON: (IV) EN: 15 O (oxo X₂), PzH (pyrazole), Acac (acetylacetonato) Molecular 6-coordinate: octahedron (OC-6)

trans–[V(O)(PzH)(Acac)₂]
[V(O)(S₂)₂(Bpy)]⊖ Vanadium VN: 5 CN: 7 ON: (V) EN: 16 O (oxo X₂), S₂ (disulfanediyl-κ²S), Bpy (bipyridine) Molecular 5-coordinate: trigonal bipyramid (TBPY-5)

[V(O)(S₂)₂(Bpy)]⊖
[V(O)(S₂C₆H₄-κ²S)₂]²⊖ Vanadium VN: 4 CN: 5 ON: (IV) EN: 15 O (oxo ⭀O X₂L), S₂C₆H₄ (benzene-1,2-dithiolato-κ²S) Molecular 5-coordinate: square-based pyramid (SPY-5)

[V(O)(S₂C₆H₄-κ²S)₂]²⊖
[V(O)(Tren-κ⁴N)] Vanadium VN: 2 CN: 5 ON: (II) EN: 15 O (oxo X₂), Tren (tris(2-aminoethyl)amine-κ⁴N) Molecular 4-coordinate: tetrahedron (T-4)

[V(O)(Tren-κ⁴N)]
cis–[V(O)₂(Bpy)₂]⊕ Vanadium VN: 5 CN: 6 ON: (V) EN: 18 (O)₂ (dioxo-cis X₄L Ⓢ), Bpy (bipyridine) Molecular 6-coordinate: octahedron (OC-6)

cis–[V(O)₂(Bpy)₂]⊕
cis–[V(O)₂(Dmso-κO)₄]⊕ Vanadium VN: 5 CN: 6 ON: (V) EN: 18 (O)₂ (dioxo-cis X₄L Ⓢ), Dmso (dimethylsulfoxide-κO) Molecular 6-coordinate: octahedron (OC-6)

cis–[V(O)₂(Dmso-κO)₄]⊕
cis–[V(O)₂(Ox)₂]³⊖ Vanadium VN: 5 CN: 6 ON: (V) EN: 18 (O)₂ (dioxo-cis X₄L Ⓢ), Ox (oxalato) Molecular 6-coordinate: octahedron (OC-6)

cis–[V(O)₂(Ox)₂]³⊖
cis–[V(O)₂(Phen)₂]⊕ Vanadium VN: 5 CN: 6 ON: (V) EN: 18 (O)₂ (dioxo-cis X₄L Ⓢ), Phen (phenanthroline) Molecular 6-coordinate: octahedron (OC-6)

cis–[V(O)₂(Phen)₂]⊕
[V(O)₂(Terpy-κ³N)]⊕ Vanadium VN: 5 CN: 5 ON: (V) EN: 14 O (oxo X₂), Terpy (terpyridine-κ³N) Molecular 4-coordinate: tetrahedron (T-4)

[V(O)₂(Terpy-κ³N)]⊕
catena–1D-[V(O)₂(μ₂–O)]⊖ Vanadium VN: 5 CN: 4 ON: (V) EN: 12 O (oxo X₂), O (μ₂–oxo X+X), O (μ₂–oxo X+X) Catena-1D 4-coordinate: tetrahedron (T-4)

catena–1D-[V(O)₂(μ₂–O)]⊖
[V(O){O(CH₂CO₂)₂-κ³O}(Phen)] Vanadium VN: 4 CN: 6 ON: (IV) EN: 15 O (oxo X₂), O(CH₂CO₂)₂ (oxydiacetato-κ³O), Phen (phenanthroline) Molecular 6-coordinate: octahedron (OC-6)

[V(O){O(CH₂CO₂)₂-κ³O}(Phen)]
[V(O₂CCF₃-κO)₂(η⁵-C₅H₄Me)₂] Vanadium VN: 4 CN: 8 ON: (IV) EN: 17 O₂CCF₃ (trifluoroacetato-κO), C₅H₄Me (η⁵-methylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[V(O₂CCF₃-κO)₂(η⁵-C₅H₄Me)₂]
[V(O₂CEt-κO)(CO)₂(Dmpe)₂] Vanadium VN: 1 CN: 7 ON: (I) EN: 18 O₂CEt (propanoato-κO), CO (carbonyl), Dmpe (1,2-bis-(dimethylphosphino)ethane) Molecular 7-coordinate: octahedron, face monocapped (OCF-7)

[V(O₂CEt-κO)(CO)₂(Dmpe)₂]
[V(O₂CH₆H₄)₂(O)]²⊖ Vanadium VN: 4 CN: 5 ON: (IV) EN: 15 O₂C₆H₄-o (catecholato-κ²O), O (oxo ⭀O X₂L) Molecular 5-coordinate: square-based pyramid (SPY-5)

[V(O₂C₆H₄)₂(O)]²⊖