Chemicals

Central atom: Vanadium
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
[V(N₃)₅(O)]²⊖ Vanadium VN: 5 CN: 6 ON: (V) EN: 14 N₃ (azido), O (oxo X₂) Molecular 6-coordinate: octahedron (OC-6)

[V(N₃)₅(O)]²⊖
[V(N₃)₆]²⊖ Vanadium VN: 4 CN: 6 ON: (IV) EN: 13 N₃ (azido) Molecular 6-coordinate: octahedron (OC-6)

[V(N₃)₆]²⊖
trans–[V(NCMe)₂(Acac)₂]⊕ Vanadium VN: 3 CN: 6 ON: (III) EN: 14 NCMe (acetonitrile), Acac (acetylacetonato) Molecular 6-coordinate: octahedron (OC-6)

trans–[V(NCMe)₂(Acac)₂]⊕
trans–[V(NCMe)₂(Dmpe)₂]²⊕ Vanadium VN: 2 CN: 6 ON: (II) EN: 15 NCMe (acetonitrile), Dmpe (1,2-bis-(dimethylphosphino)ethane) Molecular 6-coordinate: octahedron (OC-6)

trans–[V(NCMe)₂(Dmpe)₂]²⊕
[V(NCMe)₆]²⊕ Vanadium VN: 2 CN: 6 ON: (II) EN: 15 NCMe (acetonitrile) Molecular 6-coordinate: octahedron (OC-6)

[V(NCMe)₆]²⊕
[V(NCNCN)₂(Cp)₂] Vanadium VN: 4 CN: 8 ON: (IV) EN: 17 NCNCN (dicyanamido⊖), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[V(NCNCN)₂(Cp)₂]
[V(NCO)₂(η⁵-C₅H₄Me)₂] Vanadium VN: 4 CN: 8 ON: (IV) EN: 17 NCO (isocyanato-κN), C₅H₄Me (η⁵-methylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[V(NCO)₂(η⁵-C₅H₄Me)₂]
[V(NCS-κN)₂(Cp)₂] Vanadium VN: 4 CN: 8 ON: (IV) EN: 17 NCS (isothiocyanato-κN), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[V(NCS-κN)₂(Cp)₂]
trans–[V(NCS-κN)₂(Thf)₄] Vanadium VN: 2 CN: 6 ON: (II) EN: 15 NCS (isothiocyanato-κN), Thf (tetrahydrofuran) Molecular 6-coordinate: octahedron (OC-6)

trans–[V(NCS-κN)₂(Thf)₄]
trans–[V(NCS-κN)₄(O)(OH₂)]²⊖ Vanadium VN: 4 CN: 6 ON: (IV) EN: 15 NCS (isothiocyanato-κN), O (oxo X₂), OH₂ (aqua) Molecular 6-coordinate: octahedron (OC-6)

trans–[V(NCS-κN)₄(O)(OH₂)]²⊖
trans–[V(NEt₂)₂(Thf)₄]²⊕ Vanadium VN: 4 CN: 6 ON: (IV) EN: 17 NEt₂ (diethylamino: planar), Thf (tetrahydrofuran) Molecular 6-coordinate: octahedron (OC-6)

trans–[V(NEt₂)₂(Thf)₄]²⊕
[V(NEt₂)₄]⊕ Vanadium VN: 5 CN: 4 ON: (V) EN: 16 NEt₂ (diethylamino: planar) Molecular 4-coordinate: tetrahedron (T-4)

[V(NEt₂)₄]⊕
[V(NH₃)₆]²⊕ Vanadium VN: 2 CN: 6 ON: (II) EN: 15 NH₃ (ammine) Molecular 6-coordinate: octahedron (OC-6)

[V(NH₃)₆]²⊕
[V(NH₃){N(CH₂CH₂S)₃}] Vanadium VN: 3 CN: 5 ON: (III) EN: 12 NH₃ (ammine), N(CH₂CH₂S)₃ (tris(2-thiolatoethyl)amine) Molecular 5-coordinate: trigonal bipyramid (TBPY-5)

[V(NH₃){N(CH₂CH₂S)₃}]
[V(NMe₂)₂(μ₂-NBuᵗ)]₂ Vanadium VN: 5 CN: 5 ON: (IV) EN: 16 NMe₂ (dimethylamino: planar), NBuᵗ (μ₂-t-butylimino X₂L) Oligomer 5-coordinate (geometry not specified)

[V(NMe₂)₂(μ₂-NBuᵗ)]₂
[V(NMe₂)₂(μ₂-NXy)]₂ Vanadium VN: 5 CN: 5 ON: (IV) EN: 16 NMe₂ (dimethylamino: planar), NXy (μ₂-xylylimino X₂L) Oligomer 5-coordinate (geometry not specified)

[V(NMe₂)₂(μ₂-NXy)]₂
[V(NPh₂)₃(Thf)] Vanadium VN: 3 CN: 4 ON: (III) EN: 16 NPh₂ (diphenylamino: planar), Thf (tetrahydrofuran) Molecular 4-coordinate: tetrahedron (T-4)

[V(NPh₂)₃(Thf)]
[V(NPh₂)₃(⭀NMe)] Vanadium VN: 5 CN: 4 ON: (V) EN: 18 NPh₂ (diphenylamino: planar), ⭀NMe (⭀NMe methylimino) Molecular 4-coordinate: tetrahedron (T-4)

[V(NPh₂)₃(⭀NMe)]
[V(NPh₂)₄]⊖ Vanadium VN: 3 CN: 4 ON: (III) EN: 18 NPh₂ (diphenylamino: planar) Molecular 4-coordinate: tetrahedron (T-4)

[V(NPh₂)₄]⊖
[V(O)(Acac)(Tp*-κ³N)] Vanadium VN: 4 CN: 6 ON: (IV) EN: 15 O (oxo X₂), Acac (acetylacetonato), Tp* (hydrotris(3,5-dimethylpyrazolyl)borato-κ³N) Molecular 6-coordinate: octahedron (OC-6)

[V(O)(Acac)(Tp*-κ³N)]