Chemicals

Central atom: Vanadium
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
trans–[V(F)₄(O)]²⊖ Vanadium VN: 4 CN: 5 ON: (IV) EN: 13 F (fluoro), O (oxo X₂) Molecular 6-coordinate: octahedron (OC-6)

trans–[V(F)₄(O)]²⊖
trans–[V(F)₄(Py)₂]⊖ Vanadium VN: 3 CN: 6 ON: (III) EN: 14 F (fluoro), Py (pyridine) Molecular 6-coordinate: octahedron (OC-6)

trans–[V(F)₄(Py)₂]⊖
catena–1D-[V(F)₄(μ₂-F)] Vanadium VN: 5 CN: 6 ON: (V) EN: 12 F (fluoro), F (μ₂-fluoro) Catena-1D 6-coordinate: octahedron (OC-6)

catena–1D-[V(F)₄(μ₂-F)]
[V(F)₅(O)]²⊖ Vanadium VN: 5 CN: 6 ON: (V) EN: 14 F (fluoro), O (oxo X₂) Molecular 6-coordinate: octahedron (OC-6)

[V(F)₅(O)]²⊖
[V(F)₅(O)]²⊖ Vanadium VN: 5 CN: 6 ON: (V) EN: 14 F (fluoro), O (oxo X₂) Molecular 6-coordinate: octahedron (OC-6)

[V(F)₅(O)]²⊖
[V(F)₅(OH₂)]²⊖ Vanadium VN: 3 CN: 6 ON: (III) EN: 14 F (fluoro), OH₂ (aqua) Molecular 6-coordinate: octahedron (OC-6)

[V(F)₅(OH₂)]²⊖
[V(F)₆]³⊖ Vanadium VN: 3 CN: 6 ON: (III) EN: 14 F (fluoro) Molecular 6-coordinate: octahedron (OC-6)

[V(F)₆]³⊖
[V(GeH₃)(CO)₃(Cp)]⊖ Vanadium VN: 1 CN: 7 ON: (I) EN: 18 GeH₃ (germyl), CO (carbonyl), Cp (η⁵-cyclopentadienyl) Molecular 7-coordinate: ③-●-4 piano stool

[V(GeH₃)(CO)₃(Cp)]⊖
[V(H)(CO)₃(Cp)]⊖ Vanadium VN: 1 CN: 7 ON: (I) EN: 18 H (hydrido), CO (carbonyl), Cp (η⁵-cyclopentadienyl) Molecular 7-coordinate: ③-●-4 piano stool

[V(H)(CO)₃(Cp)]⊖
[V(H)(CO)₄(Dppe-κ²P)] Vanadium VN: 1 CN: 7 ON: (I) EN: 18 H (hydrido), CO (carbonyl), Dppe (1,2-bis-(diphenylphosphino)ethane-κ²P) Molecular 7-coordinate: pentagonal bipyramid (PBPY-7)

[V(H)(CO)₄(Dppe-κ²P)]
[V(H){N(SiMe₃)₂}₃]⊖ Vanadium VN: 3 CN: 4 ON: (III) EN: 16 H (hydrido), N(SiMe₃)₂ (bis(trimethylsilyl)amino: planar) Molecular 4-coordinate: tetrahedron (T-4)

[V(H){N(SiMe₃)₂}₃]⊖
[V(Hfa)₃] Vanadium VN: 3 CN: 6 ON: (III) EN: 14 Hfa (hexafluoroacetylacetonato) Molecular 6-coordinate: octahedron (OC-6)

[V(Hfa)₃]
trans–[V(I)(CO)₂(MeC≡CMe)(PMe₂Ph)₂] Vanadium VN: 1 CN: 6 ON: (I) EN: 16 I (iodo), CO (carbonyl), MeC≡CMe (butyne), PMe₂Ph (dimethylphenylphosphane) Molecular 6-coordinate: octahedron (OC-6)

trans–[V(I)(CO)₂(MeC≡CMe)(PMe₂Ph)₂]
[V(I)(Pc)] Vanadium VN: 3 CN: 5 ON: (III) EN: 12 I (iodo), Pc (phthalocyaninato) Molecular 5-coordinate: square-based pyramid (SPY-5)

[V(I)(Pc)]
[V(I)(PMe₃)₂(⭀NBuᵗ)₂] Vanadium VN: 5 CN: 5 ON: (V) EN: 18 I (iodo), PMe₃ (trimethylphosphane), ⭀NBuᵗ (⭀N t-butylimino) Molecular 5-coordinate: trigonal bipyramid (TBPY-5)

[V(I)(PMe₃)₂(⭀NBuᵗ)₂]
trans–[V(I)₂(CNXy)₄] Vanadium VN: 2 CN: 6 ON: (II) EN: 15 I (iodo), CNXy (xylyl isocyanide) Molecular 6-coordinate: octahedron (OC-6)

trans–[V(I)₂(CNXy)₄]
trans–[V(I)₂(Depe)₂] Vanadium VN: 2 CN: 6 ON: (II) EN: 15 I (iodo), Depe (1,2-bis-(diethylphosphino)ethane) Molecular 6-coordinate: octahedron (OC-6)

trans–[V(I)₂(Depe)₂]
cis–[V(I)₂(Dme)₂] Vanadium VN: 2 CN: 6 ON: (II) EN: 15 I (iodo), Dme (dimethoxyethane) Molecular 6-coordinate: octahedron (OC-6)

cis–[V(I)₂(Dme)₂]
trans–[V(I)₂(Dmpe)₂] Vanadium VN: 2 CN: 6 ON: (II) EN: 15 I (iodo), Dmpe (1,2-bis-(dimethylphosphino)ethane) Molecular 6-coordinate: octahedron (OC-6)

trans–[V(I)₂(Dmpe)₂]
cis–[V(I)₂(Thf)([9]aneS₃-κ²S)] Vanadium VN: 2 CN: 5 ON: (II) EN: 13 I (iodo), Thf (tetrahydrofuran), [9]aneS₃ (1,4,7-trithiocyclononane-κ²S) Molecular 6-coordinate: octahedron (OC-6)

cis–[V(I)₂(Thf)([9]aneS₃-κ²S)]