Chemicals

Central atom: Vanadium
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
[V(O₂CH₆H₄)₃]²⊖ Vanadium VN: 4 CN: 6 ON: (IV) EN: 13 O₂C₆H₄-o (catecholato-κ²O) Molecular 6-coordinate: octahedron (OC-6)

[V(O₂C₆H₄)₃]²⊖
[V(O₂PPh₂-κO)(Cp)₂] Vanadium VN: 3 CN: 7 ON: (III) EN: 16 O₂PPh₂ (diphenylphosphinate-κO), Cp (η⁵-cyclopentadienyl) Molecular 7-coordinate: ③₂-●-1 bent metallocene

[V(O₂PPh₂-κO)(Cp)₂]
[V(O=CMe₂)(Cp)₂]⊕ Vanadium VN: 3 CN: 7 ON: (III) EN: 16 O=CMe₂ (acetone), Cp (η⁵-cyclopentadienyl) Molecular 7-coordinate: ③₂-●-1 bent metallocene

[V(O=CMe₂)(Cp)₂]⊕
[V(O=CMe₂)(Cp*)₂]⊕ Vanadium VN: 3 CN: 7 ON: (III) EN: 16 O=CMe₂ (acetone), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 7-coordinate: ③₂-●-1 bent metallocene

[V(O=CMe₂)(Cp*)₂]⊕
[V(O=CPh₂)(Cp*)₂]⊕ Vanadium VN: 3 CN: 7 ON: (III) EN: 16 O=CPh₂ (dibenzophenone), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 7-coordinate: ③₂-●-1 bent metallocene

[V(O=CPh₂)(Cp*)₂]⊕
[V(OC₆H₃Prⁱ₂-2,6)₃(O)] Vanadium VN: 5 CN: 4 ON: (V) EN: 10 OC₆H₃Prⁱ₂-2,6 (di-isopropylphenoxy-2,6), O (oxo X₂) Molecular 4-coordinate: tetrahedron (T-4)

[V(OC₆H₃Prⁱ₂-2,6)₃(O)]
cis–[V(OH)(O)(Bpy)₂]⊕ Vanadium VN: 4 CN: 6 ON: (IV) EN: 15 OH (hydroxo), O (oxo X₂), Bpy (bipyridine) Molecular 6-coordinate: octahedron (OC-6)

cis–[V(OH)(O)(Bpy)₂]⊕
cis–[V(OH)(O)(Phen)₂]⊕ Vanadium VN: 4 CN: 6 ON: (IV) EN: 15 OH (hydroxo), O (oxo X₂), Phen (phenanthroline) Molecular 6-coordinate: octahedron (OC-6)

cis–[V(OH)(O)(Phen)₂]⊕
[V(OH₂)(Edta-κ²N,κ⁴O)]⊖ Vanadium VN: 3 CN: 7 ON: (III) EN: 16 OH₂ (aqua), Edta (ethylenediaminetetraacetato-κ²N,κ⁴O) Molecular 7-coordinate: octahedron, face monocapped (OCF-7)

[V(OH₂)(Edta-κ²N,κ⁴O)]⊖
[V(OH₂)₂(Cp)₂]²⊕ Vanadium VN: 4 CN: 8 ON: (IV) EN: 17 OH₂ (aqua), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[V(OH₂)₂(Cp)₂]²⊕
trans–[V(OH₂)₂(Ox)₂]⊖ Vanadium VN: 3 CN: 6 ON: (III) EN: 14 OH₂ (aqua), Ox (oxalato) Molecular 6-coordinate: octahedron (OC-6)

trans–[V(OH₂)₂(Ox)₂]⊖
[V(OH₂)₃{N(CH₂CO₂)₃-κN,κ³O}] Vanadium VN: 3 CN: 7 ON: (III) EN: 16 OH₂ (aqua), Nta (2,2',2''-nitrilotriacetato-κN,κ³O) Molecular 7-coordinate: trigonal prism, square-face monocapped (TPRS-7)

[V(OH₂)₃{N(CH₂CO₂)₃-κN,κ³O}]
[V(OH₂)₆]²⊕ Vanadium VN: 2 CN: 6 ON: (II) EN: 15 OH₂ (aqua) Molecular 6-coordinate: octahedron (OC-6)

[V(OH₂)₆]²⊕
[V(OH₂)₆]³⊕ Vanadium VN: 3 CN: 6 ON: (III) EN: 14 OH₂ (aqua) Molecular 6-coordinate: octahedron (OC-6)

[V(OH₂)₆]³⊕
[V(OHMe)₆]²⊕ Vanadium VN: 2 CN: 6 ON: (II) EN: 15 OHMe (methanol) Molecular 6-coordinate: octahedron (OC-6)

[V(OHMe)₆]²⊕
catena–1D-[V(OMe)(μ₂-OMe)₂(O)] Vanadium VN: 5 CN: 6 ON: (V) EN: 14 OMe (methoxy), OMe (μ₂-methoxy), O (oxo X₂) Catena-1D 6-coordinate: octahedron (OC-6)

catena–1D-[V(OMe)(μ₂-OMe)₂(O)]
[V(OMes)₃(O)] Vanadium VN: 5 CN: 4 ON: (V) EN: 10 OMes (mesityloxy), O (oxo X₂) Molecular 4-coordinate: tetrahedron (T-4)

[V(OMes)₃(O)]
[V(ONO₂-κO)(O)(NCMe)(O₂NO-κ²O)₂] Vanadium VN: 5 CN: 7 ON: (V) EN: 16 NO₃ (nitrato-κO), O (oxo X₂), NCMe (acetonitrile), NO₃ (nitrato-κ²O) Molecular 7-coordinate (geometry not specified)

[V(ONO₂-κO)(O)(NCMe)(O₂NO-κ²O)₂]
[V(OPrⁱ)(O)(Acac)₂] Vanadium VN: 5 CN: 6 ON: (V) EN: 14 OPrⁱ (isopropoxy), O (oxo X₂), Acac (acetylacetonato) Molecular 6-coordinate: octahedron (OC-6)

[V(OPrⁱ)(O)(Acac)₂]
[V(OPrⁱ)₃(μ₂-OPrⁱ)]₂ Vanadium VN: 4 CN: 5 ON: (IV) EN: 11 OPrⁱ (isopropoxy), OPrⁱ (μ₂-isopropoxy) Oligomer 5-coordinate: trigonal bipyramid (TBPY-5)

[V(OPrⁱ)₃(μ₂-OPrⁱ)]₂