Chemicals

Central atom: Vanadium
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
cis–[V(SO₄-κO)(O)(PzH)₄] Vanadium VN: 4 CN: 6 ON: (IV) EN: 15 SO₄ (sulphato-κO), O (oxo X₂), PzH (pyrazole) Molecular 6-coordinate: octahedron (OC-6)

cis–[V(SO₄-κO)(O)(PzH)₄]

cis–[V(SO₄-κ²O)(Bpy)₂] Vanadium VN: 2 CN: 6 ON: (II) EN: 15 SO₄ (sulphato-κ²O), Bpy (bipyridine) Molecular 6-coordinate: octahedron (OC-6)

cis–[V(SO₄-κ²O)(Bpy)₂]

[V(SPh)(S)₂(S₂)]²⊖ Vanadium VN: 5 CN: 5 ON: (V) EN: 18 SPh (phenylthio), S (thio; ⭀S), S₂ (disulfanediyl-κ²S) Molecular 4-coordinate: tetrahedron (T-4)

[V(SPh)(S)₂(S₂)]²⊖

[V(SPh)₂(Cp)₂] Vanadium VN: 4 CN: 8 ON: (IV) EN: 17 SPh (phenylthio), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[V(SPh)₂(Cp)₂]

[V(SPh)₂(O)(Cp)] Vanadium VN: 5 CN: 6 ON: (V) EN: 14 SPh (phenylthio), O (oxo X₂), Cp (η⁵-cyclopentadienyl) Molecular 6-coordinate: ③-●-3 piano stool

[V(SPh)₂(O)(Cp)]

[V(SPh)₄]²⊖ Vanadium VN: 2 CN: 4 ON: (II) EN: 11 SPh (phenylthio) Molecular 4-coordinate: tetrahedron (T-4)

[V(SPh)₄]²⊖

[V(Terpy-κ³N)₂] Vanadium VN: 4 CN: 6 ON: (IV) EN: 13 Terpy (terpyridine-κ³N 2⊖) Molecular 6-coordinate: octahedron (OC-6)

[V(Terpy-κ³N)₂]

[V(Thf)(Cp*)₂]⊕ Vanadium VN: 3 CN: 7 ON: (III) EN: 16 Thf (tetrahydrofuran), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 7-coordinate: ③₂-●-1 bent metallocene

[V(Thf)(Cp*)₂]⊕

[V(Thf)₂(Acac)₂] Vanadium VN: 2 CN: 6 ON: (II) EN: 15 Thf (tetrahydrofuran), Acac (acetylacetonato) Molecular 6-coordinate: octahedron (OC-6)

[V(Thf)₂(Acac)₂]

trans–[V(Thf)₂(Oep)] Vanadium VN: 2 CN: 6 ON: (II) EN: 15 Thf (tetrahydrofuran), Oep (octaethylporphyrin) Molecular 6-coordinate: octahedron (OC-6)

trans–[V(Thf)₂(Oep)]

[V(Thf)₆]²⊕ Vanadium VN: 2 CN: 6 ON: (II) EN: 15 Thf (tetrahydrofuran) Molecular 6-coordinate: octahedron (OC-6)

[V(Thf)₆]²⊕

[V(Tp-κ³N)₂]⊕ Vanadium VN: 3 CN: 6 ON: (III) EN: 14 Tp (hydrotris(pyrazolyl)borato-κ³N) Molecular 6-coordinate: octahedron (OC-6)

[V(Tp-κ³N)₂]⊕

[V(η⁴-Cot)(η⁸-Cot)] Vanadium VN: 2 CN: 6 ON: (II) EN: 17 Cot (η⁴-cyclooctatetraene), Cot (η⁸-cyclooctatetraene) Molecular 6-coordinate (geometry not specified)

[V(η⁴-Cot)(η⁸-Cot)]

[V(η⁵-C₅H₄Ph)(η⁷-C₇H₇)] Vanadium VN: 4 CN: 7 ON: (IV) EN: 17 C₅H₄Ph (η⁵-phenylcyclopentadienyl), C₇H₇ (η⁷-cycloheptatrienyl X₃L₂) Molecular 7-coordinate: ④-●-③ metallocene

[V(η⁵-C₅H₄Ph)(η⁷-C₇H₇)]

[V(η⁶-C₆H₃Me₃)₂] Vanadium VN: 0 CN: 6 ON: (O) EN: 17 C₆H₃Me₃ (mesitylene) Molecular 6-coordinate (geometry not specified)

[V(η⁶-C₆H₃Me₃)₂]

[V(η⁶-C₆H₃Me₃)₂]⊕ Vanadium VN: 1 CN: 6 ON: (I) EN: 16 C₆H₃Me₃ (mesitylene) Molecular 6-coordinate (geometry not specified)

[V(η⁶-C₆H₃Me₃)₂]⊕

[V(η⁶-C₆H₆)₂]⊕ Vanadium VN: 1 CN: 6 ON: (I) EN: 16 C₆H₆ (benzene) Molecular 6-coordinate: ③-●-③ sandwich

[V(η⁶-C₆H₆)₂]⊕

[V(η⁶-C₇H₈)₂]⊕ Vanadium VN: 1 CN: 6 ON: (I) EN: 16 C₇H₈ (toluene) Molecular 6-coordinate (geometry not specified)

[V(η⁶-C₇H₈)₂]⊕

[V(η⁸-C₈Me₆)]₂ Vanadium VN: 5 CN: 7 ON: (II) EN: 16 C₈Me₆ (η⁸-hexamethylpentalene) Oligomer 7-coordinate: ③₂-●-1 bent metallocene

[V(η⁸-C₈Me₆)]₂

[V(μ₂-Br)₂(η⁵-C₅EtMe₄)]₂ Vanadium VN: 4 CN: 8 ON: (III) EN: 17 Br (μ₂-bromo), C₅EtMe₄ (η⁵-ethyltetramethylcyclopentadienyl) Oligomer 8-coordinate: ③-●-4-1 half-sandwich

[V(μ₂-Br)₂(η⁵-C₅EtMe₄)]₂