Chemicals

Central atom: Vanadium
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
[V(OSiBuᵗ₃)₃(OPPh₃)] Vanadium VN: 3 CN: 4 ON: (III) EN: 10 OSiBuᵗ₃ (tri-t-butylsiloxy), OPPh₃ (triphenylphosphane oxide) Molecular 4-coordinate: tetrahedron (T-4)

[V(OSiBuᵗ₃)₃(OPPh₃)]
[V(OSiMe₃)(SCH₂CH₂S)₂]⊖ Vanadium VN: 4 CN: 5 ON: (IV) EN: 11 OSiMe₃ (trimethylsiloxy), SCH₂CH₂S (ethanedithiolato-κ²S) Molecular 5-coordinate: square-based pyramid (SPY-5)

[V(OSiMe₃)(SCH₂CH₂S)₂]⊖
[V(OSiMe₃)₂(O)₂]⊖ Vanadium VN: 5 CN: 4 ON: (V) EN: 12 OSiMe₃ (trimethylsiloxy), O (oxo X₂) Molecular 4-coordinate: tetrahedron (T-4)

[V(OSiMe₃)₂(O)₂]⊖
[V(OSiPh₃)₂(O)₂]⊖ Vanadium VN: 5 CN: 4 ON: (V) EN: 12 OSiPh₃ (triphenylsiloxy), O (oxo X₂) Molecular 4-coordinate: tetrahedron (T-4)

[V(OSiPh₃)₂(O)₂]⊖
[V(OSiPh₃)₃(O)] Vanadium VN: 5 CN: 4 ON: (V) EN: 10 OSiPh₃ (triphenylsiloxy), O (oxo X₂) Molecular 4-coordinate: tetrahedron (T-4)

[V(OSiPh₃)₃(O)]
[V(Ox)(Cp)₂] Vanadium VN: 4 CN: 8 ON: (IV) EN: 17 Ox (oxalato), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[V(Ox)(Cp)₂]
[V(PbPh₃)(CO)₆] Vanadium VN: 1 CN: 7 ON: (I) EN: 18 PbPh₃ (triphenylplumbyl), CO (carbonyl) Molecular 7-coordinate: octahedron, face monocapped (OCF-7)

[V(PbPh₃)(CO)₆]
trans–[V(Ph)(⭀NBuᵗ)₂(PMe₃)₂] Vanadium VN: 5 CN: 5 ON: (V) EN: 18 Ph (phenyl), ⭀NBuᵗ (⭀N t-butylimino), PMe₃ (trimethylphosphane) Molecular 5-coordinate: trigonal bipyramid (TBPY-5)

trans–[V(Ph)(⭀NBuᵗ)₂(PMe₃)₂]
[V(PH₂Ph)₂(Cp)₂]⊕ Vanadium VN: 3 CN: 8 ON: (III) EN: 18 PH₂Ph (phenylphosphane), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[V(PH₂Ph)₂(Cp)₂]⊕
[V(PhC≡CPh)(PMe₃)₂(Cp)] Vanadium VN: 1 CN: 6 ON: (I) EN: 16 PhC≡CPh (diphenylethyne), PMe₃ (trimethylphosphane), Cp (η⁵-cyclopentadienyl) Molecular 6-coordinate: ③-●-3 piano stool

[V(PhC≡CPh)(PMe₃)₂(Cp)]
[V(Phen)(Cp)₂]²⊕ Vanadium VN: 4 CN: 8 ON: (IV) EN: 17 Phen (phenanthroline), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[V(Phen)(Cp)₂]²⊕
[V(Phen)(η⁵-C₅H₄Me)₂]²⊕ Vanadium VN: 4 CN: 8 ON: (IV) EN: 17 Phen (phenanthroline), C₅H₄Me (η⁵-methylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[V(Phen)(η⁵-C₅H₄Me)₂]²⊕
[V(Phen)₃]³⊕ Vanadium VN: 3 CN: 6 ON: (III) EN: 14 Phen (phenanthroline) Molecular 6-coordinate: octahedron (OC-6)

[V(Phen)₃]³⊕
trans–[V(PMe₂Ph)₂(Oep)] Vanadium VN: 2 CN: 6 ON: (II) EN: 15 PMe₂Ph (dimethylphenylphosphane), Oep (octaethylporphyrin) Molecular 6-coordinate: octahedron (OC-6)

trans–[V(PMe₂Ph)₂(Oep)]
[V(Py)(Cp)₂]⊕ Vanadium VN: 3 CN: 7 ON: (III) EN: 16 Py (pyridine), Cp (η⁵-cyclopentadienyl) Molecular 7-coordinate: ③₂-●-1 bent metallocene

[V(Py)(Cp)₂]⊕
[V(Py)(Cp*)₂]⊕ Vanadium VN: 3 CN: 7 ON: (III) EN: 16 Py (pyridine), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 7-coordinate: ③₂-●-1 bent metallocene

[V(Py)(Cp*)₂]⊕
[V(S)₄]³⊖ Vanadium VN: 5 CN: 4 ON: (V) EN: 18 (S)₄ (tetrathio X₈L Ⓢ) Molecular 4-coordinate: tetrahedron (T-4)

[V(S)₄]³⊖
[V(S₂)(Cp)₂] Vanadium VN: 4 CN: 8 ON: (IV) EN: 17 S₂ (disulfanediyl-κ²S), Cp (η⁵-cyclopentadienyl) Molecular 7-coordinate: ③₂-●-1 bent metallocene

[V(S₂)(Cp)₂]
[V(S₂)₂(Terpy-κ³N)] Vanadium VN: 4 CN: 7 ON: (IV) EN: 15 S₂ (disulfanediyl-κ²S), Terpy (terpyridine-κ³N) Molecular 4-coordinate: tetrahedron (T-4)

[V(S₂)₂(Terpy-κ³N)]
[V(S₂CMe)₄] Vanadium VN: 4 CN: 8 ON: (IV) EN: 17 S₂CMe (dithioacetato-κ²S) Molecular 8-coordinate: trigonal prism, square-face bicapped (TPRS-8)

[V(S₂CMe)₄]