5-coordinate: square-based pyramid (SPY-5)

Se₄ (tetraseleno-κ²Se)

Charge on central atom:

-2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

(CH₂)₄ (tetramethylene-κ²C)

Summary of calculated classifications:

Mo«V⁴C⁵O^IVE¹⁶B⁷Z⁰X⁶L¹»^2⊖

[MLXZ]𝘲 class:

[MX₆L₁]^2-

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

[W{(CH₂)₄}(OSiPh₃)₂(⭀NPh)]

Formula Unicode styled:

[W{(CH₂)₄}(OSiPh₃)₂(⭀NPh)]

Compound name(s):

(butane-1,4-diyl)-bis(triphenylsilanolato)-(phenylimino)-tungsten

Central atom:

Tungsten

Attached groups:

OSiPh₃ (triphenylsiloxy)

⭀NPh (phenylimino)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Se(CH₂)₄O (selenoxane-κSe)

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 14

Summary of calculated classifications:

W«V⁶C⁵O^VIE¹⁴B⁷Z⁰X⁶L¹»

[MLXZ]𝘲 class:

[MX₆L₁]

MLXZ class (ENC, equivalent neutral class):

MX₆L₁

catena–1D-[Hg(Cl)(μ₃-Cl){Se(CH₂)₄O-κSe]

Formula Unicode styled:

catena–1D-[Hg(Cl)(μ₃-Cl){Se(CH₂)₄O-κSe]

Compound name(s):

catena-[dichloro-tetrahydroselenophene-mercury]

Central atom:

Mercury

Attached groups:

Cl (chloro)

Cl (μ₃-chloro)

Charge on central atom:

0

Compound type:

Catena-1D

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Hg«V²C⁵O^IIE¹⁰B⁵Z⁰X²L³»

[MLXZ]𝘲 class:

[MX₂L₃]

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

catena–2D-[Hg(μ₃-Br)(μ₂-SMe)]

Formula Unicode styled:

catena–2D-[Hg(μ₃-Br)(μ₂-SMe)]

Compound name(s):

catena-[(μ₃-bromo)-(μ₂-methylmercapto)-mercury]

Central atom:

Mercury

Attached groups:

Br (μ₃-bromo)

SMe (μ₂-methylthio)

Charge on central atom:

0

Compound type:

Catena-2D

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

12-crown-4 (12-crown-4-κ⁴O)

Summary of calculated classifications:

Hg«V²C⁵O^IIE¹⁰B⁵Z⁰X²L³»

[MLXZ]𝘲 class:

[MX₂L₃]

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

[Be(Ph)(12-crown-4-κ⁴O)]⊕

Formula Unicode styled:

[Be(Ph)(12-crown-4-κ⁴O)]⊕

Compound name(s):

phenyl-(12-crown-4)-beryllium(2+)

Central atom:

Beryllium

Attached groups:

Ph (phenyl)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

N(SiMe₃)₂ (bis(trimethylsilyl)amino)

Summary of calculated classifications:

Be«V²C⁵O^IIE¹⁰B⁵Z⁰X¹L⁴»^⊕

[MLXZ]𝘲 class:

[MX₁L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

[Li{N(SiMe₃)₂}(12-crown-4-κ⁴O)]

Formula Unicode styled:

[Li{N(SiMe₃)₂}(12-crown-4-κ⁴O)]

Compound name(s):

12-Crown-4)-bis(trimethylsilyl)amide-lithium

Central atom:

Lithium

Attached groups:

12-crown-4 (12-crown-4-κ⁴O)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 1

Oxidation Number (ON) (Roman numerals):

ON: (I)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Li«V¹C⁵O^IE¹⁰B⁵Z⁰X¹L⁴»

[MLXZ]𝘲 class:

[MX₁L₄]

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

[Ag(CF₃)₃(Bpy)]

Formula Unicode styled:

[Ag(CF₃)₃(Bpy)]

Compound name(s):

(2,2'-bipyridine)-tris(trifluoromethyl)-silver

Central atom:

Silver

Attached groups:

CF₃ (trifluoromethyl)

Bpy (bipyridine)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 3

Oxidation Number (ON) (Roman numerals):

ON: (III)

Coordination Number (CN, sum of attached group denticities):

NO (nitrosyl⊕, (N≡O)⊕ bent MNO)

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 18

Summary of calculated classifications:

Ag«V³C⁵O^IIIE¹⁸B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Co(NO){OC(CF₃)₂C(CF₃)₂O}(Dppe-κ²P)]

Formula Unicode styled:

[Co(NO){OC(CF₃)₂C(CF₃)₂O}(Dppe-κ²P)]

Compound name(s):

(1,1,1,4,4,4-hexafluoro-2,3-bis(trifluoromethyl)butane-2,3-diolato)-(1,2-bis(diphenylphosphino)ethane)-nitrosyl-cobalt

Central atom:

Cobalt

Attached groups:

OC(CF₃)₂C(CF₃)₂O (tetrakis-trifluoromethyl-ethanediolato-κO,κO)

Dppe (1,2-bis-(diphenylphosphino)ethane-κ²P)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (I)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

NO (nitrosyl⊕, (N≡O)⊕ bent MNO)

Summary of calculated classifications:

Co«V⁵C⁵O^IE¹⁶B⁶X³L²Z¹»

[MLXZ]𝘲 class:

[MX₃L₂Z₁]

MLXZ class (ENC, equivalent neutral class):

MX₅L₁

[Co(NO){OC(CF₃)₂C(CF₃)₂O}(Phen)]

Formula Unicode styled:

[Co(NO){OC(CF₃)₂C(CF₃)₂O}(Phen)]

Compound name(s):

(1,1,1,4,4,4-hexafluoro-2,3-bis(trifluoromethyl)butane-2,3-diolato)-(1,10-phenanthroline)-nitrosyl-cobalt

Central atom:

Cobalt

Attached groups:

OC(CF₃)₂C(CF₃)₂O (tetrakis-trifluoromethyl-ethanediolato-κO,κO)

Phen (phenanthroline)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (I)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

(O)₂ (di{oxo ⭀O X₂L} trans Ⓢ)

Summary of calculated classifications:

Co«V⁵C⁵O^IE¹⁶B⁶X³L²Z¹»

[MLXZ]𝘲 class:

[MX₃L₂Z₁]

MLXZ class (ENC, equivalent neutral class):

MX₅L₁

trans-[U(O)₂{N(SiMe₃)₂}₃]⊖

Formula Unicode styled:

trans-[U(O)₂{N(SiMe₃)₂}₃]⊖

Compound name(s):

dioxo-tris(bis(trimethylsilyl)amide)-uranium(1-)

Central atom:

Uranium

Attached groups:

N(SiMe₃)₂ (bis(trimethylsilyl)amino: planar)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 24

Summary of calculated classifications:

U«V⁶C⁵O^VIE²⁴B¹²Z⁰X⁷L⁵»^⊖

[MLXZ]𝘲 class:

[MX₇L₅]^-

MLXZ class (ENC, equivalent neutral class):

MX₆L₆

[Cu(OC{O}H-κO)(OH₂)(Terpy-κ³N)]⊕

Formula Unicode styled:

[Cu(OC{O}H-κO)(OH₂)(Terpy-κ³N)]⊕

Compound name(s):

Aqua-(formato-O)-(2,2':6',2''-terpyridine-N,N',N'')-copper(1+)

Central atom:

Oxygen

Attached groups:

CHO (formyl)

Cu group (X type)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (-II)

Coordination Number (CN, sum of attached group denticities):

CN: 2

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 8

Summary of calculated classifications:

O«V²C²O^-IIE⁸B²Z⁰L⁰X²»

[MLXZ]𝘲 class:

[MX₂]

MLXZ class (ENC, equivalent neutral class):

MX₂

[Tl(F)]

Formula Unicode styled:

[Tl(F)]

Compound name(s):

thallium fluoride

thallous fluoride

monofluoro-thallium

Central atom:

Fluorine

Attached groups:

Tl group (X type)

Charge on central atom:

Compound type:

Lattice

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 7

Oxidation Number (ON) (Roman numerals):

ON: (-I)

Coordination Number (CN, sum of attached group denticities):

CH₂SiMe₃ (trimethylsilylmethyl)

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 0

Summary of calculated classifications:

F«V⁷C⁵O^-I»

[MLXZ]𝘲 class:

MLXZ class (ENC, equivalent neutral class):

[Y(CH₂SiMe₃)₂{μ₃-OSi(OBuᵗ₃)}]₂

Formula Unicode styled:

[Y(CH₂SiMe₃)₂{μ₃-OSi(OBuᵗ₃)}]₂

Compound name(s):

bis-[(μ2-tris(t-butoxy)siloxo-O,O,O')-tetrakis(trimethylsilylmethyl)-yttrium]

Central atom:

Yttrium

Attached groups:

OSi(OBuᵗ)₃ (μ₃-tri-t-butoxy-siloxy)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 3

Oxidation Number (ON) (Roman numerals):

ON: (III)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Y«V³C⁵O^IIIE¹⁰B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Br(In)]

Formula Unicode styled:

[Br(In)]

Compound name(s):

bromo-indium|Indium monobromide

Central atom:

Bromine

Attached groups:

In (indium)

Charge on central atom:

Compound type:

Lattice

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 1

Oxidation Number (ON) (Roman numerals):

ON: (-I)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 0

Summary of calculated classifications:

Br«V¹C⁵O^-I»

[MLXZ]𝘲 class:

MLXZ class (ENC, equivalent neutral class):

cis–[Re(CH₂Buᵗ)₂(O)(μ₂-S)]₂

Formula Unicode styled:

cis–[Re(CH₂Buᵗ)₂(O)(μ₂-S)]₂

Compound name(s):

syn-bis[bis(neopentyl)-oxo-(μ₂-sulfido)-rhenium] (Re—Re)

Central atom:

Attached groups:

CH₂Buᵗ (t-butylmethyl)

S (μ₂-thio)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 7

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 6

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 18

Summary of calculated classifications:

Re«V⁷C⁶O^VIE¹⁸B⁹Z⁰X⁷L²»

[MLXZ]𝘲 class:

[MX₇L₂]

MLXZ class (ENC, equivalent neutral class):

MX₇L₂

[Tc(Br)₄]₂⁴⊖

Formula Unicode styled:

[Tc(Br)₄]₂⁴⊖

Compound name(s):

bis-[tetrabromo-technetium(Tc≣Tc)(2-)]

Central atom:

Technetium

Attached groups:

Br (bromo)

Charge on central atom:

-2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 17

Summary of calculated classifications:

Tc«V⁶C⁵O^IIE¹⁷B⁸Z⁰L⁰X⁸»^2⊖

[MLXZ]𝘲 class:

[MX₈]^2-

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[Ru(F)₄(O)]

Formula Unicode styled:

[Ru(F)₄(O)]

Compound name(s):

tetrafluoro-oxo-ruthenium

Central atom:

Ruthenium

Attached groups:

F (fluoro)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ru«V⁶C⁵O^VIE¹⁶B⁷Z⁰X⁶L¹»

[MLXZ]𝘲 class:

[MX₆L₁]

MLXZ class (ENC, equivalent neutral class):

MX₆L₁

[Re(η³-C₃H₅)₂]₂

Formula Unicode styled:

[Re(η³-C₃H₅)₂]₂

Compound name(s):

bis-[di(η³-Allyl)-rhenium]

Central atom:

Attached groups:

C₃H₅ (η³-allyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V⁵C⁵O^IIE¹⁶B⁷Z⁰X⁵L²»

[MLXZ]𝘲 class:

[MX₅L₂]

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

[Re(Xy)(⭀NBuᵗ)(O)(O)]₂

Formula Unicode styled:

[Re(Xy)(⭀NBuᵗ)(O)(O)]₂

Compound name(s):

bis-[(μ₂-oxo)-oxo-(t-Butylimido-N)-xylyl-rhenium]

Central atom:

Attached groups:

Xy (xylyl)

⭀NBuᵗ (⭀N t-butylimino)

O (oxo X₂)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 7

Oxidation Number (ON) (Roman numerals):

ON: (VII)

Coordination Number (CN, sum of attached group denticities):

CN: 4

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 18

Summary of calculated classifications:

Re«V⁷C⁴O^VIIE¹⁸B⁹Z⁰X⁷L²»

[MLXZ]𝘲 class:

[MX₇L₂]

MLXZ class (ENC, equivalent neutral class):

MX₇L₂

[Re(μ₂-SPh)(S₂C₆H₄-κ²S)(O)]₂

Formula Unicode styled:

[Re(μ₂-SPh)(S₂C₆H₄-κ²S)(O)]₂

Compound name(s):

bis-[(μ₂-Phenylthiolato)-oxo-(1,2-benzenedithiolato)-rhenium

Central atom:

S₂C₆H₄ (benzene-1,2-dithiolato-κ²S)

Attached groups:

SPh (μ₂-phenylthio)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (V)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: