Chemicals

Central atom: Vanadium
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
[V(I)₃(Cp)] Vanadium VN: 4 CN: 6 ON: (IV) EN: 13 I (iodo), Cp (η⁵-cyclopentadienyl) Molecular 6-coordinate: ③-●-3 piano stool

[V(I)₃(Cp)]
[V(Me)(CO)₂(Dmpe)₂] Vanadium VN: 1 CN: 7 ON: (I) EN: 18 Me (methyl), CO (carbonyl), Dmpe (1,2-bis-(dimethylphosphino)ethane) Molecular 7-coordinate: octahedron, face monocapped (OCF-7)

[V(Me)(CO)₂(Dmpe)₂]
[V(Me)(Dmpe)(Cp)] Vanadium VN: 2 CN: 6 ON: (II) EN: 15 Me (methyl), Dmpe (1,2-bis-(dimethylphosphino)ethane), Cp (η⁵-cyclopentadienyl) Molecular 6-coordinate: ③-●-3 piano stool

[V(Me)(Dmpe)(Cp)]
trans–[V(Me)(μ₂-NTol)(Cp)]₂ Vanadium VN: 5 CN: 7 ON: (IV) EN: 16 Me (methyl), NTol (μ₂-tolylimino X₂L), Cp (η⁵-cyclopentadienyl) Oligomer 7-coordinate (geometry not specified)

trans–[V(Me)(μ₂-NTol)(Cp)]₂
trans–[V(Me)₂(Dmpe)₂] Vanadium VN: 2 CN: 6 ON: (II) EN: 15 Me (methyl), Dmpe (1,2-bis-(dimethylphosphino)ethane) Molecular 6-coordinate: octahedron (OC-6)

trans–[V(Me)₂(Dmpe)₂]
[V(Me){N(SiMe₃)₂}₂(Thf)] Vanadium VN: 3 CN: 4 ON: (III) EN: 14 Me (methyl), N(SiMe₃)₂ (bis(trimethylsilyl)amino: planar), Thf (tetrahydrofuran) Molecular 4-coordinate: tetrahedron (T-4)

[V(Me){N(SiMe₃)₂}₂(Thf)]
[V(MeO₂C)C≡C(CO₂Me)(Cp)₂] Vanadium VN: 2 CN: 7 ON: (II) EN: 17 (MeO₂C)C≡C(CO₂Me) (dimethylacetylenedicarboxylate), Cp (η⁵-cyclopentadienyl) Molecular 7-coordinate: ③-●-4 piano stool

[V(MeO₂C)C≡C(CO₂Me)(Cp)₂]
trans–[V(Mes)(Thf)₂(Acac)₂] Vanadium VN: 3 CN: 7 ON: (III) EN: 16 Mes (mesityl), Thf (tetrahydrofuran), Acac (acetylacetonato) Molecular 6-coordinate: octahedron (OC-6)

trans–[V(Mes)(Thf)₂(Acac)₂]
[V(Mes)₂(O)(Py)₂] Vanadium VN: 4 CN: 5 ON: (IV) EN: 13 Mes (mesityl), O (oxo X₂), Py (pyridine) Molecular 5-coordinate: trigonal bipyramid (TBPY-5)

[V(Mes)₂(O)(Py)₂]
[V(Mes)₂(μ₂-NTol)]₂ Vanadium VN: 5 CN: 5 ON: (IV) EN: 12 Mes (mesityl), NTol (μ₂-tolylimino X₂L) Oligomer 5-coordinate (geometry not specified)

[V(Mes)₂(μ₂-NTol)]₂
[V(Mes)₃(O)] Vanadium VN: 5 CN: 4 ON: (V) EN: 12 Mes (mesityl), O (oxo ⭀O X₂L) Molecular 4-coordinate: tetrahedron (T-4)

[V(Mes)₃(O)]
[V(Mes)₃(Thf)] Vanadium VN: 3 CN: 4 ON: (III) EN: 10 Mes (mesityl), Thf (tetrahydrofuran) Molecular 4-coordinate: tetrahedron (T-4)

[V(Mes)₃(Thf)]
[V(Mes)₄] Vanadium VN: 4 CN: 4 ON: (IV) EN: 9 Mes (mesityl) Molecular 4-coordinate: tetrahedron (T-4)

[V(Mes)₄]
[V(Mes)₄]⊖ Vanadium VN: 3 CN: 4 ON: (III) EN: 10 Mes (mesityl) Molecular 4-coordinate: tetrahedron (T-4)

[V(Mes)₄]⊖
[V(N)(Cp*)]₄ Vanadium VN: 5 CN: 6 ON: (IV) EN: 14 N (nitrido; ≡N), Cp* (η⁵-pentamethylcyclopentadienyl) Oligomer 6-coordinate: ③-●-3 piano stool

[V(N)(Cp*)]₄
mer,cis–[V(N₂C₃H₄)₃(Ox)(O)] Vanadium VN: 4 CN: 6 ON: (IV) EN: 15 N₂C₃H₄ (Imidazole), Ox (oxalato), O (oxo X₂) Molecular 6-coordinate: octahedron (OC-6)

mer,cis–[V(N₂C₃H₄)₃(Ox)(O)]
fac–[V(N₃)(NO)₂([9]aneN₃-κ³N)] Vanadium VN: 5 CN: 6 ON: (-I) EN: 18 N₃ (azido), (NO)₂ (dinitrosyl, (N≡O)₂ cis-octahedral Ⓢ), [9]aneN₃ (1,4,7-triazacyclononane-κ³N) Molecular 6-coordinate: octahedron (OC-6)

fac–[V(N₃)(NO)₂([9]aneN₃-κ³N)]
[V(N₃)(μ₂-N)(Cp*)]₂ Vanadium VN: 5 CN: 6 ON: (V) EN: 14 N₃ (azido), N (μ₂-nitrido), Cp* (η⁵-pentamethylcyclopentadienyl) Oligomer 6-coordinate: ③-●-3 piano stool

[V(N₃)(μ₂-N)(Cp*)]₂
[V(N₃)₂(Cp)₂] Vanadium VN: 4 CN: 8 ON: (IV) EN: 17 N₃ (azido), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[V(N₃)₂(Cp)₂]
mer–[V(N₃)₃(O)(Bpy)] Vanadium VN: 5 CN: 6 ON: (V) EN: 14 N₃ (azido), O (oxo X₂), Bpy (bipyridine) Molecular 6-coordinate: octahedron (OC-6)

mer–[V(N₃)₃(O)(Bpy)]