Chemicals

Central atom: Vanadium
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
[V(O)(Acac)([9]aneN₃-1,4,7-Me₃-κ³N)]⊕ Vanadium VN: 4 CN: 6 ON: (IV) EN: 15 O (oxo X₂), Acac (acetylacetonato), [9]aneN₃-1,4,7-Me₃ (1,4,7-trimethyl-1,4,7-triazacyclononane-κ³N) Molecular 6-coordinate: octahedron (OC-6)

[V(O)(Acac)([9]aneN₃-1,4,7-Me₃-κ³N)]⊕
[V(O)(Acac)₂] Vanadium VN: 4 CN: 5 ON: (IV) EN: 15 O (oxo ⭀O X₂L), Acac (acetylacetonato) Molecular 5-coordinate: square-based pyramid (SPY-5)

[V(O)(Acac)₂]
[V(O)(Bpy){O(CH₂CO₂)₂-κ³O}] Vanadium VN: 4 CN: 6 ON: (IV) EN: 15 O (oxo X₂), Bpy (bipyridine), O(CH₂CO₂)₂ (oxydiacetato-κ³O) Molecular 6-coordinate: octahedron (OC-6)

[V(O)(Bpy){O(CH₂CO₂)₂-κ³O}]
[V(O)(Dedtc)₂] Vanadium VN: 4 CN: 5 ON: (IV) EN: 15 O (oxo ⭀O X₂L), Dedtc (diethyldithiocarbamato-κ²S) Molecular 5-coordinate: square-based pyramid (SPY-5)

[V(O)(Dedtc)₂]
[V(O)(Dmso-κO)₅]²⊕ Vanadium VN: 4 CN: 6 ON: (IV) EN: 15 O (oxo X₂), Dmso (dimethylsulfoxide-κO) Molecular 6-coordinate: octahedron (OC-6)

[V(O)(Dmso-κO)₅]²⊕
[V(O)(O₂)(Phen)]⊖ Vanadium VN: 3 CN: 4 ON: (III) EN: 14 O (oxo X₂), O₂ (peroxo), Phen (phenanthroline) Molecular 6-coordinate: octahedron (OC-6)

[V(O)(O₂)(Phen)]⊖
[V(O)(O₂)(PzH)(Tp-κ³N)] Vanadium VN: 5 CN: 6 ON: (V) EN: 16 O (oxo X₂), O₂ (peroxo), PzH (pyrazole), Tp (hydrotris(pyrazolyl)borato-κ³N) Molecular 6-coordinate: octahedron (OC-6)

[V(O)(O₂)(PzH)(Tp-κ³N)]
[V(O)(O₂)₂(Bpy)]⊖ Vanadium VN: 5 CN: 5 ON: (V) EN: 16 O (oxo X₂), O₂ (peroxo), Bpy (bipyridine) Molecular 5-coordinate: trigonal bipyramid (TBPY-5)

[V(O)(O₂)₂(Bpy)]⊖
[V(O)(O₂)₂(NH₃)]⊖ Vanadium VN: 5 CN: 4 ON: (V) EN: 14 O (oxo X₂), O₂ (peroxo), NH₃ (ammine) Molecular 4-coordinate: tetrahedron (T-4)

[V(O)(O₂)₂(NH₃)]⊖
[V(O)(O₂)₂(Phen)]⊖ Vanadium VN: 5 CN: 5 ON: (V) EN: 16 O (oxo X₂), O₂ (peroxo), Phen (phenanthroline) Molecular 5-coordinate: trigonal bipyramid (TBPY-5)

[V(O)(O₂)₂(Phen)]⊖
[V(O)(O₂CH₆H₄)₂]²⊖ Vanadium VN: 4 CN: 5 ON: (IV) EN: 15 O (oxo ⭀O X₂L), O₂C₆H₄-o (catecholato-κ²O) Molecular 5-coordinate: square-based pyramid (SPY-5)

[V(O)(O₂C₆H₄)₂]²⊖
[V(O)(Oep)] Vanadium VN: 4 CN: 5 ON: (IV) EN: 15 O (oxo ⭀O X₂L), Oep (octaethylporphyrin) Molecular 5-coordinate: square-based pyramid (SPY-5)

[V(O)(Oep)]
trans–[V(O)(OH₂)(Oep)]⊕ Vanadium VN: 5 CN: 6 ON: (V) EN: 14 O (oxo X₂), OH₂ (aqua), Oep (octaethylporphyrin) Molecular 6-coordinate: octahedron (OC-6)

trans–[V(O)(OH₂)(Oep)]⊕
[V(O)(OH₂)(Ox)(Bpy)] Vanadium VN: 4 CN: 6 ON: (IV) EN: 15 O (oxo X₂), OH₂ (aqua), Ox (oxalato), Bpy (bipyridine) Molecular 6-coordinate: octahedron (OC-6)

[V(O)(OH₂)(Ox)(Bpy)]
[V(O)(OH₂)(Ox)(Phen)] Vanadium VN: 4 CN: 6 ON: (IV) EN: 15 O (oxo X₂), OH₂ (aqua), Ox (oxalato), Phen (phenanthroline) Molecular 6-coordinate: octahedron (OC-6)

[V(O)(OH₂)(Ox)(Phen)]
cis–[V(O)(OH₂)(Ox)₂]²⊖ Vanadium VN: 4 CN: 6 ON: (IV) EN: 15 O (oxo X₂), OH₂ (aqua), Ox (oxalato) Molecular 6-coordinate: octahedron (OC-6)

cis–[V(O)(OH₂)(Ox)₂]²⊖
trans–[V(O)(OH₂)₂{O(CH₂CO₂)₂-κ³O}] Vanadium VN: 4 CN: 6 ON: (IV) EN: 15 O (oxo X₂), OH₂ (aqua), O(CH₂CO₂)₂ (oxydiacetato-κ³O) Molecular 6-coordinate: octahedron (OC-6)

trans–[V(O)(OH₂)₂{O(CH₂CO₂)₂-κ³O}]
[V(O)(OH₂)₃(Ox)] Vanadium VN: 4 CN: 6 ON: (IV) EN: 15 O (oxo X₂), OH₂ (aqua), Ox (oxalato) Molecular 6-coordinate: octahedron (OC-6)

[V(O)(OH₂)₃(Ox)]
[V(O)(OH₂)₅]²⊕ Vanadium VN: 4 CN: 6 ON: (IV) EN: 15 O (oxo X₂), OH₂ (aqua) Molecular 6-coordinate: octahedron (OC-6)

[V(O)(OH₂)₅]²⊕
[V(O)(OH₂){N(CH₂CO₂)₃-κN,κ³O}]⊖ Vanadium VN: 4 CN: 6 ON: (IV) EN: 15 O (oxo X₂), OH₂ (aqua), Nta (2,2',2''-nitrilotriacetato-κN,κ³O) Molecular 6-coordinate: octahedron (OC-6)

[V(O)(OH₂){N(CH₂CO₂)₃-κN,κ³O}]⊖