Chemicals

Central atom: Zirconium
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
[Zr(μ₂-PCyH)(Cp)₂]₂ Zirconium VN: 3 CN: 8 ON: (III) EN: 17 PCyH (μ₂-cyclohexylphosphanyl), Cp (η⁵-cyclopentadienyl) Oligomer 8-coordinate: ③₂-●-2 bent metallocene

[Zr(μ₂-PCyH)(Cp)₂]₂
[Zr(μ₂-PHPh)(Cp)₂]₂ Zirconium VN: 3 CN: 8 ON: (III) EN: 17 PHPh (μ₂-phenylphosphanyl), Cp (η⁵-cyclopentadienyl) Oligomer 8-coordinate: ③₂-●-2 bent metallocene

[Zr(μ₂-PHPh)(Cp)₂]₂
[Zr(μ₂-PMe₂)(Cp)₂]₂ Zirconium VN: 4 CN: 8 ON: (III) EN: 18 PMe₂ (μ₂-dimethylphosphanyl), Cp (η⁵-cyclopentadienyl) Oligomer 8-coordinate: ③₂-●-2 bent metallocene

[Zr(μ₂-PMe₂)(Cp)₂]₂
[Zr(μ₂-S)(Cp)₂]₂ Zirconium VN: 4 CN: 8 ON: (IV) EN: 18 S (μ₂-thio), Cp (η⁵-cyclopentadienyl) Oligomer 8-coordinate: ③₂-●-2 bent metallocene

[Zr(μ₂-S)(Cp)₂]₂
[Zr(μ₂–O)₂] Zirconium VN: 4 CN: 7 ON: (IV) EN: 0 O (μ₂–oxo X+X) Lattice 7-coordinate (geometry not specified)

[Zr(μ₂–O)₂]
catena–2D-[Zr(μ₃-Cl)₂] Zirconium VN: 2 CN: 6 ON: (II) EN: 14 Cl (μ₃-chloro) Catena-2D 6-coordinate: trigonal prism (TPR-6)

catena–2D-[Zr(μ₃-Cl)₂]
catena–2D-[Zr(μ₃-I)₂] Zirconium VN: 2 CN: 6 ON: (II) EN: 14 I (μ₃-iodo) Catena-2D 6-coordinate: octahedron (OC-6)

catena–2D-[Zr(μ₃-I)₂]
catena–2D-[Zr(μ₃-S)₂] Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 S (μ₃-thio X₂L) Catena-2D 6-coordinate: octahedron (OC-6)

catena–2D-[Zr(μ₃-S)₂]
catena–2D-[Zr(μ₃-Se)₂] Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 Se (μ₃-seleno X₂L) Catena-2D 6-coordinate: octahedron (OC-6)

catena–2D-[Zr(μ₃-Se)₂]
[Zr(μ₃-SO₄)(μ₄-SO₄)] Zirconium VN: 4 CN: 7 ON: (IV) EN: 0 SO₄ (μ₃-sulphato), SO₄ (μ₄-sulphato) Lattice 7-coordinate: trigonal prism, square-face monocapped (TPRS-7)

[Zr(μ₃-SO₄)(μ₄-SO₄)]
catena–2D-[Zr(μ₃-Te)₂] Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 Te (μ₃-telluro X₂L) Catena-2D 6-coordinate: octahedron (OC-6)

catena–2D-[Zr(μ₃-Te)₂]
catena–2D-[Zr(μ₄-Se)(Se₂)] Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 Se (μ₄-seleno X₂L₂), Se₂ (perseleno-κ²Se) Catena-2D 6-coordinate: octahedron (OC-6)

catena–2D-[Zr(μ₄-Se)(Se₂)]
catena–2D-[Zr(μ₄-Te)(Te₂)] Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 Te (μ₄-telluro X₂L₂), Te₂ (pertellurido-κ²Te) Catena-2D 6-coordinate: octahedron (OC-6)

catena–2D-[Zr(μ₄-Te)(Te₂)]
[Zr(⭀NBuᵗ)(Py)(Cp₂)] Zirconium VN: 4 CN: 8 ON: (IV) EN: 18 ⭀NBuᵗ (⭀N t-butylimino), Py (pyridine), (Cp₂) (bis-(η⁵-cyclopentadienyl) X₂L₃ Ⓢ) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(⭀NBuᵗ)(Py)(Cp₂)]
[Zr(⭀NBuᵗ)(Thf)(Cp)(Cp*)] Zirconium VN: 4 CN: 8 ON: (IV) EN: 18 ⭀NBuᵗ (⭀N t-butylimino), Thf (tetrahydrofuran), (Cp)(Cp*) ((η⁵-cyclopentadienyl) + η⁵-pentamethylcyclopentadienyl) X₂L₃ Ⓢ), ⭀NBuᵗ (⭀N t-butylimino) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(⭀NBuᵗ)(Thf)(Cp)(Cp*)]
[Zr(⭀NBuᵗ)(Thf)(Cp₂)] Zirconium VN: 4 CN: 8 ON: (IV) EN: 18 ⭀NBuᵗ (⭀N t-butylimino), Thf (tetrahydrofuran), (Cp₂) (bis-(η⁵-cyclopentadienyl) X₂L₃ Ⓢ) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(⭀NBuᵗ)(Thf)(Cp₂)]
[Zr₂(H)₂(μ₂-Se)(Cp*)₄] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 H (hydrido), Se (μ₂-seleno X–X), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr₂(H)₂(μ₂-Se)(Cp*)₄]
[Zr{As(SiMe₃)₂}₂(Cp)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 As(SiMe₃)₂ (bistrimethylsilylarsanyl), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr{As(SiMe₃)₂}₂(Cp)₂]
[Zr{N(CH₂CO₂)₃-κN,κ³O}₂]²⊖ Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 Nta (2,2',2''-nitrilotriacetato-κN,κ³O) Molecular

[Zr{N(CH₂CO₂)₃-κN,κ³O}₂]²⊖
[Zr{N(SiMe₃)₂}(Thf)(η⁷-C₇H₇)] Zirconium VN: 4 CN: 6 ON: (IV) EN: 16 N(SiMe₃)₂ (bis(trimethylsilyl)amino: planar), Thf (tetrahydrofuran), C₇H₇ (η⁷-cycloheptatrienyl X₃L₂) Molecular 6-coordinate (geometry not specified)

[Zr{N(SiMe₃)₂}(Thf)(η⁷-C₇H₇)]