Chemicals

Central atom: Zirconium
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
[Zr(μ₂-C≡CSiMe₃)(Cp)₂]₂ Zirconium VN: 3 CN: 8 ON: (III) EN: 17 C≡CSiMe₃ (μ₂-trimethylsilylalkynyl), Cp (η⁵-cyclopentadienyl) Oligomer 8-coordinate: ③₂-●-2 bent metallocene

[Zr(μ₂-C≡CSiMe₃)(Cp)₂]₂
[Zr(μ₂-F)₄] Zirconium VN: 4 CN: 8 ON: (IV) EN: 0 F (μ₂-fluoro) Lattice 8-coordinate (geometry not specified)

[Zr(μ₂-F)₄]
[Zr(μ₂-H)(Me)(Cp)₂]₂ Zirconium VN: 4 CN: 9 ON: (IV) EN: 18 H (μ₂-hydrido), Me (methyl), Cp (η⁵-cyclopentadienyl) Oligomer 9-coordinate: ③₂-●-3 bent metallocene

[Zr(μ₂-H)(Me)(Cp)₂]₂
[Zr(μ₂-H)(OC₆H₃Buᵗ₂-2,6)(η⁸-Cot)]₂ Zirconium VN: 4 CN: 7 ON: (IV) EN: 16 H (μ₂-hydrido), OC₆H₃Buᵗ₂-2,6 (di-t-butylphenoxy-2,6), Cot (η⁸-cyclooctatetraene) Oligomer 7-coordinate: ④-●-3 piano stool

[Zr(μ₂-H)(OC₆H₃Buᵗ₂-2,6)(η⁸-Cot)]₂
[Zr(μ₂-I)(Cp)₂]₂ Zirconium VN: 3 CN: 8 ON: (III) EN: 17 I (μ₂-iodo), Cp (η⁵-cyclopentadienyl) Oligomer 8-coordinate: ③₂-●-2 bent metallocene

[Zr(μ₂-I)(Cp)₂]₂
[Zr(μ₂-I)(η⁵-C₅H₄Me)₂]₂ Zirconium VN: 3 CN: 8 ON: (III) EN: 17 I (μ₂-iodo), C₅H₄Me (η⁵-methylcyclopentadienyl) Oligomer 8-coordinate: ③₂-●-2 bent metallocene

[Zr(μ₂-I)(η⁵-C₅H₄Me)₂]₂
catena–1D-[Zr(μ₂-I)₃] Zirconium VN: 3 CN: 6 ON: (III) EN: 13 I (μ₂-iodo) Catena-1D 6-coordinate: octahedron (OC-6)

catena–1D-[Zr(μ₂-I)₃]
[Zr(μ₂-I){η⁵-C₅H₄(SiMe₃)}₂]₂ Zirconium VN: 3 CN: 8 ON: (III) EN: 17 I (μ₂-iodo), C₅H₄(SiMe₃) (η⁵-(trimethylsilyl)cyclopentadienyl) Oligomer 8-coordinate: ③₂-●-2 bent metallocene

[Zr(μ₂-I){η⁵-C₅H₄(SiMe₃)}₂]₂
[Zr(μ₂-NXy){η⁸-C₈H₆(SiMe₃)₂}]₂ Zirconium VN: 4 CN: 6 ON: (IV) EN: 16 NXy (μ₂-xylylimino X₂L), C₈H₆(SiMe₃)₂ (η⁸-bistrimethylsilyl-cyclooctatetraene) Oligomer 6-coordinate: ④-●-2 piano stool

[Zr(μ₂-NXy){η⁸-C₈H₆(SiMe₃)₂}]₂
[Zr(μ₂-OH)₂(Tpp)]₂ Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 OH (μ₂-hydroxy), Tpp (tetraphenylporphyrin) Oligomer 8-coordinate: square antiprism (SAPR-8)

[Zr(μ₂-OH)₂(Tpp)]₂
[Zr(μ₂-OSiPh₃)(η⁷-C₇H₇)]₂ Zirconium VN: 4 CN: 6 ON: (IV) EN: 14 OSiPh₃ (μ₂-triphenylsiloxy), C₇H₇ (η⁷-cycloheptatrienyl X₃L₂) Oligomer 6-coordinate: ④-●-2 piano stool

[Zr(μ₂-OSiPh₃)(η⁷-C₇H₇)]₂
[Zr(μ₂-PBuᵗH)(η⁵-C₅H₄Me)₂]₂ Zirconium VN: 3 CN: 8 ON: (III) EN: 17 PBuᵗH (μ₂-t-butylphosphanyl), C₅H₄Me (η⁵-methylcyclopentadienyl) Oligomer 8-coordinate: ③₂-●-2 bent metallocene

[Zr(μ₂-PBuᵗH)(η⁵-C₅H₄Me)₂]₂
[Zr(μ₂-PCyH)(Cp)₂]₂ Zirconium VN: 3 CN: 8 ON: (III) EN: 17 PCyH (μ₂-cyclohexylphosphanyl), Cp (η⁵-cyclopentadienyl) Oligomer 8-coordinate: ③₂-●-2 bent metallocene

[Zr(μ₂-PCyH)(Cp)₂]₂
[Zr(μ₂-PHPh)(Cp)₂]₂ Zirconium VN: 3 CN: 8 ON: (III) EN: 17 PHPh (μ₂-phenylphosphanyl), Cp (η⁵-cyclopentadienyl) Oligomer 8-coordinate: ③₂-●-2 bent metallocene

[Zr(μ₂-PHPh)(Cp)₂]₂
[Zr(μ₂-PMe₂)(Cp)₂]₂ Zirconium VN: 4 CN: 8 ON: (III) EN: 18 PMe₂ (μ₂-dimethylphosphanyl), Cp (η⁵-cyclopentadienyl) Oligomer 8-coordinate: ③₂-●-2 bent metallocene

[Zr(μ₂-PMe₂)(Cp)₂]₂
[Zr(μ₂-S)(Cp)₂]₂ Zirconium VN: 4 CN: 8 ON: (IV) EN: 18 S (μ₂-thio), Cp (η⁵-cyclopentadienyl) Oligomer 8-coordinate: ③₂-●-2 bent metallocene

[Zr(μ₂-S)(Cp)₂]₂
[Zr(μ₂–O)₂] Zirconium VN: 4 CN: 7 ON: (IV) EN: 0 O (μ₂–oxo X+X) Lattice 7-coordinate (geometry not specified)

[Zr(μ₂–O)₂]
catena–2D-[Zr(μ₃-Cl)₂] Zirconium VN: 2 CN: 6 ON: (II) EN: 14 Cl (μ₃-chloro) Catena-2D 6-coordinate: trigonal prism (TPR-6)

catena–2D-[Zr(μ₃-Cl)₂]
catena–2D-[Zr(μ₃-I)₂] Zirconium VN: 2 CN: 6 ON: (II) EN: 14 I (μ₃-iodo) Catena-2D 6-coordinate: octahedron (OC-6)

catena–2D-[Zr(μ₃-I)₂]
catena–2D-[Zr(μ₃-S)₂] Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 S (μ₃-thio X₂L) Catena-2D 6-coordinate: octahedron (OC-6)

catena–2D-[Zr(μ₃-S)₂]