9-coordinate: ③₂-●-3 bent metallocene

Attached groups:

CR₃ (alkyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Nb«V⁵C⁹O^IVE¹⁸B⁹Z⁰X⁵L⁴»

[MLXZ]𝘲 class:

[MX₅L₄]

MLXZ class (ENC, equivalent neutral class):

MX₅L₄

[Nb(H)(SiIMe₂)(SiMe₃)(Cp)₂]

Formula Unicode styled:

[Nb(H)(SiIMe₂)(SiMe₃)(Cp)₂]

Compound name(s):

hydrido-(dimethyliodosilyl)-(trimethylsilyl)-bis(η⁵-cyclopentadienyl)-niobium

Central atom:

Attached groups:

SiIMe₂ (dimethyliodosilyl)

SiMe₃ (trimethylsilyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Nb«V⁵C⁹O^VE¹⁸B⁹Z⁰X⁵L⁴»

[MLXZ]𝘲 class:

[MX₅L₄]

MLXZ class (ENC, equivalent neutral class):

MX₅L₄

[Nb(H)(SiBrMe₂)(SiIMe₂)(Cp)₂]

Formula Unicode styled:

[Nb(H)(SiBrMe₂)(SiIMe₂)(Cp)₂]

Compound name(s):

hydrido-(dimethylbromosilyl)-(dimethyliodosilyl)-bis(η⁵-cyclopentadienyl)-niobium

Central atom:

Attached groups:

SiBrMe₂ (dimethylbromosilyl)

SiIMe₂ (dimethyliodosilyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Nb«V⁵C⁹O^VE¹⁸B⁹Z⁰X⁵L⁴»

[MLXZ]𝘲 class:

[MX₅L₄]

MLXZ class (ENC, equivalent neutral class):

MX₅L₄

[Nb(H)(SiMe₂Ph)₂(Cp)₂]

Formula Unicode styled:

[Nb(H)(SiMe₂Ph)₂(Cp)₂]

Compound name(s):

hydrido-bis(phenyldimethylsilyl)-bis(η⁵-trimethylsilyl-cyclopentadienyl)-niobium

Central atom:

Attached groups:

SiMe₂Ph (dimethylphenylsilyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Nb«V⁵C⁹O^VE¹⁸B⁹Z⁰X⁵L⁴»

[MLXZ]𝘲 class:

[MX₅L₄]

MLXZ class (ENC, equivalent neutral class):

MX₅L₄

[Nb(H)(SiBrMe₂)₂(Cp)₂]

Formula Unicode styled:

[Nb(H)(SiBrMe₂)₂(Cp)₂]

Compound name(s):

hydrido-bis(bromodimethylsilyl)-bis(η⁵-trimethylsilyl-cyclopentadienyl)-niobium

Central atom:

Attached groups:

SiBrMe₂ (dimethylbromosilyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Nb«V⁵C⁹O^VE¹⁸B⁹Z⁰X⁵L⁴»

[MLXZ]𝘲 class:

[MX₅L₄]

MLXZ class (ENC, equivalent neutral class):

MX₅L₄

[Nb(H)(SiClMe₂)₂(Cp)₂]

Formula Unicode styled:

[Nb(H)(SiClMe₂)₂(Cp)₂]

Compound name(s):

hydrido-bis(chlorodimethylsilyl)-bis(η⁵-trimethylsilyl-cyclopentadienyl)-niobium

Central atom:

Attached groups:

SiClMe₂ (dimethylchlorosilyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Nb«V⁵C⁹O^VE¹⁸B⁹Z⁰X⁵L⁴»

[MLXZ]𝘲 class:

[MX₅L₄]

MLXZ class (ENC, equivalent neutral class):

MX₅L₄

[Nb(H)₂(SbPh₂)(Cp)₂]

Formula Unicode styled:

[Nb(H)₂(SbPh₂)(Cp)₂]

Compound name(s):

dihydrido-diphenylstibido-bis(η⁵-cyclopentadienyl)-niobium

Central atom:

Attached groups:

SbPh₂ (diphenylstibanyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Nb«V⁵C⁹O^VE¹⁸B⁹Z⁰X⁵L⁴»

[MLXZ]𝘲 class:

[MX₅L₄]

MLXZ class (ENC, equivalent neutral class):

MX₅L₄

[Nb(H)(SiClMe₂)₂(Cp)₂]

Formula Unicode styled:

[Nb(H)(SiClMe₂)₂(Cp)₂]

Compound name(s):

dihydrido-chlorodimethylsilyl-bis(η⁵-trimethylsilyl-cyclopentadienyl)-niobium

Central atom:

Attached groups:

SiClMe₂ (dimethylchlorosilyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Nb«V⁵C⁹O^VE¹⁸B⁹Z⁰X⁵L⁴»

[MLXZ]𝘲 class:

[MX₅L₄]

MLXZ class (ENC, equivalent neutral class):

MX₅L₄

[Nb(H)₂(SiHPh₂){η⁵-C₅H₄(SiMe₃)}₂]

Formula Unicode styled:

[Nb(H)₂(SiHPh₂){η⁵-C₅H₄(SiMe₃)}₂]

Compound name(s):

dihydrido-diphenylsilyl-bis(η⁵-trimethylsilyl-cyclopentadienyl)-niobium

Central atom:

Attached groups:

C₅H₄(SiMe₃) (η⁵-(trimethylsilyl)cyclopentadienyl)

SiHPh₂ (diphenylsilyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Nb«V⁵C⁹O^VE¹⁸B⁹Z⁰X⁵L⁴»

[MLXZ]𝘲 class:

[MX₅L₄]

MLXZ class (ENC, equivalent neutral class):

MX₅L₄

[Ta(H)₂(SMe₂)(η⁵-C₅H₄Buᵗ)₂]⊕

Formula Unicode styled:

[Ta(H)₂(SMe₂)(η⁵-C₅H₄Buᵗ)₂]⊕

Compound name(s):

dihydrido-dimethylsulfido-bis(η⁵-t-butyl-cyclopentadienyl)-tantalum(1+)

Central atom:

Attached groups:

C₅H₄Buᵗ (η⁵-t-butyl-cyclopentadienyl)

SMe₂ (dimethylthioether)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ta«V⁵C⁹O^VE¹⁸B⁹Z⁰X⁴L⁵»^⊕

[MLXZ]𝘲 class:

[MX₄L₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₅L₄

[Ta(H)₂(SeH)(η⁵-C₅H₄Buᵗ)₂]

Formula Unicode styled:

[Ta(H)₂(SeH)(η⁵-C₅H₄Buᵗ)₂]

Compound name(s):

dihydrido-hydroseleno-bis(η⁵-t-butyl-cyclopentadienyl)-tantalum

Central atom:

Attached groups:

C₅H₄Buᵗ (η⁵-t-butyl-cyclopentadienyl)

SeH (selenyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ta«V⁵C⁹O^VE¹⁸B⁹Z⁰X⁵L⁴»

[MLXZ]𝘲 class:

[MX₅L₄]

MLXZ class (ENC, equivalent neutral class):

MX₅L₄

[Ta(H)₃(Cp*){η⁵-C₅H₃(SiMe₃)₂}]

Formula Unicode styled:

[Ta(H)₃(Cp*){η⁵-C₅H₃(SiMe₃)₂}]

Compound name(s):

trihydrido-(η⁵-pentamethyl-cyclopentadienyl)-{η⁵-1,3-bis(trimethylsilyl)-cyclopentadienyl}-tantalum(v)

Central atom:

Attached groups:

Cp* (η⁵-pentamethylcyclopentadienyl)

C₅H₃(SiMe₃)₂ (η⁵-bis(trimethylsilyl)cyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ta«V⁵C⁹O^VE¹⁸B⁹Z⁰X⁵L⁴»

[MLXZ]𝘲 class:

[MX₅L₄]

MLXZ class (ENC, equivalent neutral class):

MX₅L₄

[Ta(H)₂(SiMe₂Ph)(Cp)₂]

Formula Unicode styled:

[Ta(H)₂(SiMe₂Ph)(Cp)₂]

Compound name(s):

dihydrido-dimethylphenylsilyl-bis(η⁵-cyclopentadienyl)-tantalum

Central atom:

Attached groups:

SiMe₂Ph (dimethylphenylsilyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ta«V⁵C⁹O^VE¹⁸B⁹Z⁰X⁵L⁴»

[MLXZ]𝘲 class:

[MX₅L₄]

MLXZ class (ENC, equivalent neutral class):

MX₅L₄

[Ta(H)₃{η⁵-C₅H₃(SiMe₃)₂}(Cp*)]

Formula Unicode styled:

[Ta(H)₃{η⁵-C₅H₃(SiMe₃)₂}(Cp*)]

Compound name(s):

trihydrido-(η⁵-pentamethyl-cyclopentadienyl)-{η⁵-1,3-bis(trimethylsilyl)-cyclopentadienyl}-tantalum

Central atom:

Attached groups:

C₅H₃(SiMe₃)₂ (η⁵-bis(trimethylsilyl)cyclopentadienyl)

Cp* (η⁵-pentamethylcyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ta«V⁵C⁹O^VE¹⁸B⁹Z⁰X⁵L⁴»

[MLXZ]𝘲 class:

[MX₅L₄]

MLXZ class (ENC, equivalent neutral class):

MX₅L₄

[Ta(H){Zn(η⁵-C₅H₅)}₂(η⁵-C₅H₄Me)₂]

Formula Unicode styled:

[Ta(H){Zn(η⁵-C₅H₅)}₂(η⁵-C₅H₄Me)₂]

Compound name(s):

hydrido-bis(η⁵-cyclopentadienyl-zinc)-bis(η⁵-methylcyclopentadienyl)-tantalum

Central atom:

Attached groups:

C₅H₄Me (η⁵-methylcyclopentadienyl)

Zn group (X type)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

OSO₂CF₃ (μ₂-trifluoromethanesulfonato-κ²O)

Summary of calculated classifications:

Ta«V⁵C⁹O^VE¹⁸B⁹Z⁰X⁵L⁴»

[MLXZ]𝘲 class:

[MX₅L₄]

MLXZ class (ENC, equivalent neutral class):

MX₅L₄

[U(Me)(μ₂-SO₃CF₃)(Cp*₂)]₂

Formula Unicode styled:

[U(Me)(μ₂-SO₃CF₃)(Cp*₂)]₂

Compound name(s):

bis-[bis(pentamethylcyclopentadienyl)-methyl-(μ-trifluoromethanesulfonato)-uranium]

Central atom:

Uranium

Attached groups:

Me (methyl)

(Cp*₂) (bis-(η⁵-pentamethylcyclopentadienyl) X₂L₃ Ⓢ)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

U«V⁴C⁹O^IVE¹⁸B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Sm(μ₂-Cl)(Thf)(η⁵-C₅H₄Me)₂]₂

Formula Unicode styled:

[Sm(μ₂-Cl)(Thf)(η⁵-C₅H₄Me)₂]₂

Compound name(s):

bis-[(μ₂-chloro)-bis(η⁵-methylcyclopentadienyl)-(tetrahydrofuran-O)-samarium]

Central atom:

Samarium

Attached groups:

Cl (μ₂-chloro)

C₅H₄Me (η⁵-methylcyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 23

Summary of calculated classifications:

Sm«V³C⁹O^IIIE²³B⁹Z⁰X³L⁶»

[MLXZ]𝘲 class:

[MX₃L₆]

MLXZ class (ENC, equivalent neutral class):

MX₃L₆

[Gd(μ₂-Cl)(Thf)(η⁵-C₅H₄Bz)₂]₂

Formula Unicode styled:

[Gd(μ₂-Cl)(Thf)(η⁵-C₅H₄Bz)₂]₂

Compound name(s):

bis-[(μ₂-chloro)-bis(η⁵-benzyl-cyclopentadienyl)-tetrahydrofuran-gadolinium]

Central atom:

Gadolinium

Attached groups:

Cl (μ₂-chloro)

C₅H₄Bz (η⁵-benzylcyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 25

Summary of calculated classifications:

Gd«V³C⁹O^IIIE²⁵B⁹Z⁰X³L⁶»

[MLXZ]𝘲 class:

[MX₃L₆]

MLXZ class (ENC, equivalent neutral class):

MX₃L₆

[Gd(μ₂-Cl)(Thf)(Cp)₂]₂

Formula Unicode styled:

[Gd(μ₂-Cl)(Thf)(Cp)₂]₂

Compound name(s):

bis-[(μ₂-Chloro)-bis(η⁵-cyclopentadienyl)-tetrahydrofuran-gadolinium]

Central atom:

Gadolinium

Attached groups:

Cl (μ₂-chloro)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 25

Summary of calculated classifications:

Gd«V³C⁹O^IIIE²⁵B⁹Z⁰X³L⁶»

[MLXZ]𝘲 class:

[MX₃L₆]

MLXZ class (ENC, equivalent neutral class):

MX₃L₆

[Dy(μ₂-H)(Thf){η⁵-C₅H₄(SiMe₃)}₂]₂

Formula Unicode styled:

[Dy(μ₂-H)(Thf){η⁵-C₅H₄(SiMe₃)}₂]₂

Compound name(s):

bis-[(μ-hydrido)-bis(η⁵-trimethylsilylcyclopentadienyl)-(tetrahydrofuran-dysprosium]

Central atom:

Dysprosium

Attached groups:

H (μ₂-hydrido)

C₅H₄(SiMe₃) (η⁵-(trimethylsilyl)cyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):