Chemicals

Central atom: Zirconium
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
catena–2D-[Zr(μ₃-S)₂] Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 S (μ₃-thio X₂L) Catena-2D 6-coordinate: octahedron (OC-6)

catena–2D-[Zr(μ₃-S)₂]
catena–2D-[Zr(μ₃-Se)₂] Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 Se (μ₃-seleno X₂L) Catena-2D 6-coordinate: octahedron (OC-6)

catena–2D-[Zr(μ₃-Se)₂]
[Zr(μ₃-SO₄)(μ₄-SO₄)] Zirconium VN: 4 CN: 7 ON: (IV) EN: 0 SO₄ (μ₃-sulphato), SO₄ (μ₄-sulphato) Lattice 7-coordinate: trigonal prism, square-face monocapped (TPRS-7)

[Zr(μ₃-SO₄)(μ₄-SO₄)]
catena–2D-[Zr(μ₃-Te)₂] Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 Te (μ₃-telluro X₂L) Catena-2D 6-coordinate: octahedron (OC-6)

catena–2D-[Zr(μ₃-Te)₂]
catena–2D-[Zr(μ₄-Se)(Se₂)] Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 Se (μ₄-seleno X₂L₂), Se₂ (perseleno-κ²Se) Catena-2D 6-coordinate: octahedron (OC-6)

catena–2D-[Zr(μ₄-Se)(Se₂)]
catena–2D-[Zr(μ₄-Te)(Te₂)] Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 Te (μ₄-telluro X₂L₂), Te₂ (pertellurido-κ²Te) Catena-2D 6-coordinate: octahedron (OC-6)

catena–2D-[Zr(μ₄-Te)(Te₂)]
[Zr(⭀NBuᵗ)(Py)(Cp₂)] Zirconium VN: 4 CN: 8 ON: (IV) EN: 18 ⭀NBuᵗ (⭀N t-butylimino), Py (pyridine), (Cp₂) (bis-(η⁵-cyclopentadienyl) X₂L₃ Ⓢ) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(⭀NBuᵗ)(Py)(Cp₂)]
[Zr(⭀NBuᵗ)(Thf)(Cp)(Cp*)] Zirconium VN: 4 CN: 8 ON: (IV) EN: 18 ⭀NBuᵗ (⭀N t-butylimino), Thf (tetrahydrofuran), (Cp)(Cp*) ((η⁵-cyclopentadienyl) + η⁵-pentamethylcyclopentadienyl) X₂L₃ Ⓢ), ⭀NBuᵗ (⭀N t-butylimino) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(⭀NBuᵗ)(Thf)(Cp)(Cp*)]
[Zr(⭀NBuᵗ)(Thf)(Cp₂)] Zirconium VN: 4 CN: 8 ON: (IV) EN: 18 ⭀NBuᵗ (⭀N t-butylimino), Thf (tetrahydrofuran), (Cp₂) (bis-(η⁵-cyclopentadienyl) X₂L₃ Ⓢ) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(⭀NBuᵗ)(Thf)(Cp₂)]
[Zr₂(H)₂(μ₂-Se)(Cp*)₄] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 H (hydrido), Se (μ₂-seleno X–X), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr₂(H)₂(μ₂-Se)(Cp*)₄]
[Zr{As(SiMe₃)₂}₂(Cp)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 As(SiMe₃)₂ (bistrimethylsilylarsanyl), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr{As(SiMe₃)₂}₂(Cp)₂]
[Zr{N(CH₂CO₂)₃-κN,κ³O}₂]²⊖ Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 Nta (2,2',2''-nitrilotriacetato-κN,κ³O) Molecular

[Zr{N(CH₂CO₂)₃-κN,κ³O}₂]²⊖
[Zr{N(SiMe₃)₂}(Thf)(η⁷-C₇H₇)] Zirconium VN: 4 CN: 6 ON: (IV) EN: 16 N(SiMe₃)₂ (bis(trimethylsilyl)amino: planar), Thf (tetrahydrofuran), C₇H₇ (η⁷-cycloheptatrienyl X₃L₂) Molecular 6-coordinate (geometry not specified)

[Zr{N(SiMe₃)₂}(Thf)(η⁷-C₇H₇)]
[Zr{N(SiMe₃)₂}₃]⊕ Zirconium VN: 4 CN: 3 ON: (IV) EN: 12 N(SiMe₃)₂ (bis(trimethylsilyl)amino: planar) Molecular

[Zr{N(SiMe₃)₂}₃]⊕
[Zr{NC₅H₃(CO₂)₂-κN,κ²O}(Cp)₂] Zirconium VN: 4 CN: 9 ON: (IV) EN: 18 NC₅H₃(CO₂)₂ (pyridinedicarboxylato-2,6-κN,κ²O)), Cp (η⁵-cyclopentadienyl) Molecular 9-coordinate: ③₂-●-3 bent metallocene

[Zr{NC₅H₃(CO₂)₂-κN,κ²O}(Cp)₂]
[Zr{NC₅H₃(CO₂)₂-κN,κ²O}(η⁵-C₅H₄Me)₂] Zirconium VN: 4 CN: 9 ON: (IV) EN: 18 NC₅H₃(CO₂)₂ (pyridinedicarboxylato-2,6-κN,κ²O)), C₅H₄Me (η⁵-methylcyclopentadienyl) Molecular 9-coordinate: ③₂-●-3 bent metallocene

[Zr{NC₅H₃(CO₂)₂-κN,κ²O}(η⁵-C₅H₄Me)₂]
[Zr{NC₅H₃(CO₂)₂-κN,κ²O}₃]²⊖ Zirconium VN: 4 CN: 9 ON: (IV) EN: 18 NC₅H₃(CO₂)₂ (pyridinedicarboxylato-2,6-κN,κ²O)) Molecular 9-coordinate: trigonal prism, square-face tricapped (TPRS-9)

[Zr{NC₅H₃(CO₂)₂-κN,κ²O}₃]²⊖
[Zr{OC(Buᵗ)CHC(Buᵗ)O}₄] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 OC(Buᵗ)CHC(Buᵗ)O (tetramethylheptane-3,5-dionato) Molecular 4-coordinate: tetrahedron (T-4)

[Zr{OC(Buᵗ)CHC(Buᵗ)O}₄]
[Zr{P(SiMe₃)₂}₂(η⁵-C₅H₄Me)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 P(SiMe₃)₂ (bis(trimethylsilyl)phosphanyl), C₅H₄Me (η⁵-methylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr{P(SiMe₃)₂}₂(η⁵-C₅H₄Me)₂]
[Zr{SeSi(SiMe₃)₃}₄] Zirconium VN: 4 CN: 4 ON: (IV) EN: 8 SeSi(SiMe₃)₃ (tris-(trimethylsilyl)-selenyl) Molecular 4-coordinate: tetrahedron (T-4)

[Zr{SeSi(SiMe₃)₃}₄]