Chemicals

Central atom: Zirconium
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
[Zr(PMe₃)(C₆H₄)(Cp)₂] Zirconium VN: 2 CN: 8 ON: (II) EN: 18 PMe₃ (trimethylphosphane), C₆H₄ (benzyne), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(PMe₃)(C₆H₄)(Cp)₂]
[Zr(PMe₃)(Cp)(η⁷-C₇H₇)] Zirconium VN: 4 CN: 8 ON: (IV) EN: 18 PMe₃ (trimethylphosphane), Cp (η⁵-cyclopentadienyl), C₇H₇ (η⁷-cycloheptatrienyl X₃L₂) Molecular 8-coordinate (geometry not specified)

[Zr(PMe₃)(Cp)(η⁷-C₇H₇)]
[Zr(PMe₃)(η⁵-C₅H₅Me₂)₂] Zirconium VN: 2 CN: 7 ON: (II) EN: 16 PMe₃ (trimethylphosphane), C₅H₅Me₂ (η⁵-2,4-dimethylpentadienyl) Molecular 7-coordinate: ③₂-●-1 bent metallocene

[Zr(PMe₃)(η⁵-C₅H₅Me₂)₂]
[Zr(PMe₃)₂(Cp)₂] Zirconium VN: 2 CN: 8 ON: (II) EN: 18 PMe₃ (trimethylphosphane), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(PMe₃)₂(Cp)₂]
[Zr(PPh₂)₂{η⁵-C₅H₄(SiMe₃)}₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 PPh₂ (diphenylphosphanyl), C₅H₄(SiMe₃) (η⁵-(trimethylsilyl)cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(PPh₂)₂{η⁵-C₅H₄(SiMe₃)}₂]
[Zr(PzH)(Acac)(Cp)₂]⊕ Zirconium VN: 4 CN: 9 ON: (IV) EN: 18 PzH (pyrazole), Acac (acetylacetonato), Cp (η⁵-cyclopentadienyl) Molecular 9-coordinate: ③₂-●-3 bent metallocene

[Zr(PzH)(Acac)(Cp)₂]⊕
[Zr(S)(Py)(η⁵-C₅EtMe₄)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 18 S (thio), Py (pyridine), C₅EtMe₄ (η⁵-ethyltetramethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(S)(Py)(η⁵-C₅EtMe₄)₂]
[Zr(S₂)(CO)(Cp*)₂] Zirconium VN: 4 CN: 9 ON: (IV) EN: 18 S₂ (disulfanediyl-κ²S), CO (carbonyl), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 9-coordinate: ③₂-●-3 bent metallocene

[Zr(S₂)(CO)(Cp*)₂]
cis,cis,cis–[Zr(S₂C₆H₄-κ²S)₃]²⊖ Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 S₂C₆H₄ (benzene-1,2-dithiolato-κ²S) Molecular 6-coordinate: octahedron (OC-6)

cis,cis,cis–[Zr(S₂C₆H₄-κ²S)₃]²⊖
[Zr(S₃)(Cp*)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 S₃ (trisulfanediyl-κ²S), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(S₃)(Cp*)₂]
[Zr(S₅)(Cp)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 S₅ (pentasulfanediyl-κ²S), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(S₅)(Cp)₂]
[Zr(SBuᵗ)(Thf)(Cp)₂]⊕ Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 SBuᵗ (t-butylthio), Thf (tetrahydrofuran), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(SBuᵗ)(Thf)(Cp)₂]⊕
[Zr(SBuᵗ)₅]⊖ Zirconium VN: 4 CN: 5 ON: (IV) EN: 10 SBuᵗ (t-butylthio) Molecular 5-coordinate: trigonal bipyramid (TBPY-5)

[Zr(SBuᵗ)₅]⊖
[Zr(SBz)₂(Cp)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 SBz (benzylthio), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(SBz)₂(Cp)₂]
[Zr(SCH₂CH₂CH₂S)(Cp)₂]₂ Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 SCH₂CH₂CH₂S (propanedithiolato-κ²S), Cp (η⁵-cyclopentadienyl) Oligomer 8-coordinate: ③₂-●-2 bent metallocene

[Zr(SCH₂CH₂CH₂S)(Cp)₂]₂
[Zr(Se)(Py)(η⁵-C₅EtMe₄)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 18 Se (selenido), Py (pyridine), C₅EtMe₄ (η⁵-ethyltetramethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(Se)(Py)(η⁵-C₅EtMe₄)₂]
[Zr(Se₂)(CO)(Cp*)₂] Zirconium VN: 4 CN: 9 ON: (IV) EN: 18 Se₂ (perseleno-κ²Se), CO (carbonyl), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 9-coordinate: ③₂-●-3 bent metallocene

[Zr(Se₂)(CO)(Cp*)₂]
[Zr(Se₂CH₆H₄-κ²Se)(η⁵-C₅H₄Buᵗ)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 Se₂C₆H₄-o (benzene-1,2-diselenolato-κ²Se), C₅H₄Buᵗ (η⁵-t-butyl-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(Se₂CH₆H₄-κ²Se)(η⁵-C₅H₄Buᵗ)₂]
[Zr(Se₃)(Cp*)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 Se₃ (triseleno-κ²Se), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(Se₃)(Cp*)₂]
[Zr(Se₅)(Cp)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 Se₅ (pentaseleno-κ²Se), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(Se₅)(Cp)₂]