Chemicals

Central atom: Zirconium
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
[Zr(OPrⁱ){OC(Buᵗ)CHC(Buᵗ)O}₃] Zirconium VN: 4 CN: 7 ON: (IV) EN: 14 OPrⁱ (isopropoxy), OC(Buᵗ)CHC(Buᵗ)O (tetramethylheptane-3,5-dionato) Molecular 7-coordinate: trigonal prism, square-face monocapped (TPRS-7)

[Zr(OPrⁱ){OC(Buᵗ)CHC(Buᵗ)O}₃]
[Zr(Ox)₄]⁴⊖ Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 Ox (oxalato) Molecular 8-coordinate: trigonal prism, square-face bicapped (TPRS-8)

[Zr(Ox)₄]⁴⊖
[Zr(OXylyl)₃(Cp*)] Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 OXylyl (xylyloxy), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 7-coordinate: ③-●-4 piano stool

[Zr(OXylyl)₃(Cp*)]
fac–[Zr(OXylyl)₃(Tp*-κ³N)] Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 OXylyl (xylyloxy), Tp* (hydrotris(3,5-dimethylpyrazolyl)borato-κ³N) Molecular 6-coordinate: octahedron (OC-6)

fac–[Zr(OXylyl)₃(Tp*-κ³N)]
[Zr(Cp)₂}₂(μ₂-P)] Zirconium VN: 3 CN: 7 ON: (III) EN: 17 P group (X type), Cp (η⁵-cyclopentadienyl) Molecular 7-coordinate: ③₂-●-1 bent metallocene

[Zr(Cp)₂}₂(μ₂-P)]
[Zr(Pc)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 Pc (phthalocyaninato) Molecular

[Zr(Pc)₂]
[Zr(PEt₃)(η⁵-C₅H₅Me₂)₂] Zirconium VN: 2 CN: 7 ON: (II) EN: 16 PEt₃ (triethylphosphane), C₅H₅Me₂ (η⁵-2,4-dimethylpentadienyl) Molecular 7-coordinate: ③₂-●-1 bent metallocene

[Zr(PEt₃)(η⁵-C₅H₅Me₂)₂]
[Zr(Ph)₂(Cp)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 Ph (phenyl), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(Ph)₂(Cp)₂]
[Zr(Ph)₂(Cp*)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 Ph (phenyl), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(Ph)₂(Cp*)₂]
[Zr(Ph)₅]⊖ Zirconium VN: 4 CN: 5 ON: (IV) EN: 10 Ph (phenyl) Molecular 5-coordinate: trigonal bipyramid (TBPY-5)

[Zr(Ph)₅]⊖
[Zr(Ph)₆]²⊖ Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 Ph (phenyl) Molecular 6-coordinate: octahedron (OC-6)

[Zr(Ph)₆]²⊖
[Zr(Ph){CH(PPh₃)}(Cp)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 18 Ph (phenyl), CH(PPh₃) (triphenylphosphinylidene-methyl), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(Ph){CH(PPh₃)}(Cp)₂]
[Zr(Ph){CH(SiMe₃)₂}(Cp)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 Ph (phenyl), CH(SiMe₃)₂ (bistrimethylsilylmethyl), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(Ph){CH(SiMe₃)₂}(Cp)₂]
cis–[Zr(PhC≡CPh)(Oep)] Zirconium VN: 2 CN: 5 ON: (II) EN: 14 PhC≡CPh (diphenylethyne L₂), Oep (octaethylporphyrin) Molecular 5-coordinate: square-based pyramid (SPY-5)

cis–[Zr(PhC≡CPh)(Oep)]
[Zr(PMe₃)(C₆H₄)(Cp)₂] Zirconium VN: 2 CN: 8 ON: (II) EN: 18 PMe₃ (trimethylphosphane), C₆H₄ (benzyne), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(PMe₃)(C₆H₄)(Cp)₂]
[Zr(PMe₃)(Cp)(η⁷-C₇H₇)] Zirconium VN: 4 CN: 8 ON: (IV) EN: 18 PMe₃ (trimethylphosphane), Cp (η⁵-cyclopentadienyl), C₇H₇ (η⁷-cycloheptatrienyl X₃L₂) Molecular 8-coordinate (geometry not specified)

[Zr(PMe₃)(Cp)(η⁷-C₇H₇)]
[Zr(PMe₃)(η⁵-C₅H₅Me₂)₂] Zirconium VN: 2 CN: 7 ON: (II) EN: 16 PMe₃ (trimethylphosphane), C₅H₅Me₂ (η⁵-2,4-dimethylpentadienyl) Molecular 7-coordinate: ③₂-●-1 bent metallocene

[Zr(PMe₃)(η⁵-C₅H₅Me₂)₂]
[Zr(PMe₃)₂(Cp)₂] Zirconium VN: 2 CN: 8 ON: (II) EN: 18 PMe₃ (trimethylphosphane), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(PMe₃)₂(Cp)₂]
[Zr(PPh₂)₂{η⁵-C₅H₄(SiMe₃)}₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 PPh₂ (diphenylphosphanyl), C₅H₄(SiMe₃) (η⁵-(trimethylsilyl)cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(PPh₂)₂{η⁵-C₅H₄(SiMe₃)}₂]
[Zr(PzH)(Acac)(Cp)₂]⊕ Zirconium VN: 4 CN: 9 ON: (IV) EN: 18 PzH (pyrazole), Acac (acetylacetonato), Cp (η⁵-cyclopentadienyl) Molecular 9-coordinate: ③₂-●-3 bent metallocene

[Zr(PzH)(Acac)(Cp)₂]⊕