PMe₂ (μ₂-dimethylphosphanyl)

[B(H)₂(μ₂-PMe₂)]₃

Formula Unicode styled: 
[B(H)₂(μ₂-PMe₂)]₃
Compound name(s): 
tris-[dimethylphosphino-boron]
Central atom: 
Boron
Attached groups: 
H (hydrido)
PMe₂ (μ₂-dimethylphosphanyl)
Charge on central atom: 
0
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 4
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 8
Summary of calculated classifications: 
B«V3C4OIIIE8B4Z0X3L1»
[MLXZ]𝘲 class: 
[MX3L1]
MLXZ class (ENC, equivalent neutral class): 
MX3L1

[Zr(μ₂-PMe₂)(Cp)₂]₂

Formula Unicode styled: 
[Zr(μ₂-PMe₂)(Cp)₂]₂
Compound name(s): 
bis-[bis-(η⁵-Cyclopentadienyl)-(μ₂-dimethylphosphino-P,P)-zirconium]
Central atom: 
Zirconium
Attached groups: 
PMe₂ (μ₂-dimethylphosphanyl)
Cp (η⁵-cyclopentadienyl)
Charge on central atom: 
0
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 8
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Zr«V4C8OIIIE18B9Z0X4L5»
[MLXZ]𝘲 class: 
[MX4L5]
MLXZ class (ENC, equivalent neutral class): 
MX4L5

[W(μ₂-PMe₂)(CO)₃(PEt₃)]₂

Formula Unicode styled: 
[W(μ₂-PMe₂)(CO)₃(PEt₃)]₂
Compound name(s): 
bis-[(μ₂-Dimethylphosphido)-tricarbonyl-(trimethylphosphine)-tungsten(W—W)]
Central atom: 
Tungsten
Attached groups: 
PMe₂ (μ₂-dimethylphosphanyl)
CO (carbonyl)
PEt₃ (triethylphosphane)
Charge on central atom: 
0
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (I)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
W«V2C7OIE18B7Z0X2L5»
[MLXZ]𝘲 class: 
[MX2L5]
MLXZ class (ENC, equivalent neutral class): 
MX2L5

[V(μ₂-PMe₂)(CO)₄]₂

Formula Unicode styled: 
[V(μ₂-PMe₂)(CO)₄]₂
Compound name(s): 
bis-[μ₂-Dimethylphosphido)-bis(tetracarbonyl-vanadium(V=V)]
Central atom: 
Vanadium
Attached groups: 
PMe₂ (μ₂-dimethylphosphanyl)
CO (carbonyl)
Charge on central atom: 
0
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (I)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
V«V3C7OIE18B8Z0X3L5»
[MLXZ]𝘲 class: 
[MX3L5]
MLXZ class (ENC, equivalent neutral class): 
MX3L5

[Ti(μ₂-PMe₂)(Cp)₂]₂

Formula Unicode styled: 
[Ti(μ₂-PMe₂)(Cp)₂]₂
Compound name(s): 
bis-[(μ₂-Dimethylphosphido)-titanocene]
Central atom: 
Titanium
Attached groups: 
PMe₂ (μ₂-dimethylphosphanyl)
Cp (η⁵-cyclopentadienyl)
Charge on central atom: 
0
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 8
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 17
Summary of calculated classifications: 
Ti«V3C8OIIIE17B8Z0X3L5»
[MLXZ]𝘲 class: 
[MX3L5]
MLXZ class (ENC, equivalent neutral class): 
MX3L5

[Fe(μ₂-PMe₂)(NO)₂]₂

Formula Unicode styled: 
[Fe(μ₂-PMe₂)(NO)₂]₂
Compound name(s): 
bis-[(mu-dimethylphosphino)-dinitrosyl-iron] (Fe—Fe)
Central atom: 
Iron
Attached groups: 
PMe₂ (μ₂-dimethylphosphanyl)
(NO)₂ (dinitrosyl, (N≡O)₂ tetrahedral Ⓢ)
Charge on central atom: 
0
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (-I)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Fe«V4C5O-IE18B7Z0X4L3»
[MLXZ]𝘲 class: 
[MX4L3]
MLXZ class (ENC, equivalent neutral class): 
MX4L3

[Co(μ₂-PMe₂)(PMe₃)₂]₂

Formula Unicode styled: 
[Co(μ₂-PMe₂)(PMe₃)₂]₂
Compound name(s): 
bis-[μ₂-Dimethylphosphino)-bis(trimethylphosphino)-cobalt]
Central atom: 
Cobalt
Attached groups: 
PMe₂ (μ₂-dimethylphosphanyl)
PMe₃ (trimethylphosphane)
Charge on central atom: 
0
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (I)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Co«V3C6OIE18B6Z0X3L3»
[MLXZ]𝘲 class: 
[MX3L3]
MLXZ class (ENC, equivalent neutral class): 
MX3L3

[Co(μ₂-PMe₂)(Cp)]₂

Formula Unicode styled: 
[Co(μ₂-PMe₂)(Cp)]₂
Compound name(s): 
bis-[η⁵-Cyclopentadienyl)-(μ₂-dimethylphosphido)-cobalt]
Central atom: 
Cobalt
Attached groups: 
PMe₂ (μ₂-dimethylphosphanyl)
Cp (η⁵-cyclopentadienyl)
Charge on central atom: 
0
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Co«V3C6OIIE18B6Z0X3L3»
[MLXZ]𝘲 class: 
[MX3L3]
MLXZ class (ENC, equivalent neutral class): 
MX3L3

cis–[Mn(μ₂-PMe₂)(CO)₄]₂

Formula Unicode styled: 
cis–[Mn(μ₂-PMe₂)(CO)₄]₂
Compound name(s): 
Di-mu-dimethylphosphido-bis(tetracarbonyl-dimanganese)
Central atom: 
Manganese
Attached groups: 
PMe₂ (μ₂-dimethylphosphanyl)
CO (carbonyl)
Charge on central atom: 
0
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 1
Oxidation Number (ON) (Roman numerals): 
ON: (I)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Mn«V1C6OIE18B6Z0X1L5»
[MLXZ]𝘲 class: 
[MX1L5]
MLXZ class (ENC, equivalent neutral class): 
MX1L5