Chemicals

Central atom: Zirconium
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
[Zr(Te₂)(CO)(Cp*)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 Te₂ (pertellurido-κTe), CO (carbonyl), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(Te₂)(CO)(Cp*)₂]
[Zr(Te₃)(Cp*)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 Te₃ (tritellurido-κ²Te), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(Te₃)(Cp*)₂]
[Zr(TePh)(Py)(η⁵-C₅EtMe₄)₂] Zirconium VN: 3 CN: 8 ON: (III) EN: 17 TePh (phenyltellanyl), Py (pyridine), C₅EtMe₄ (η⁵-ethyltetramethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(TePh)(Py)(η⁵-C₅EtMe₄)₂]
[Zr(TePh)₂(Cp*)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 TePh (phenyltellanyl), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(TePh)₂(Cp*)₂]
[Zr(TeSiPh₃)(Cp)₂] Zirconium VN: 3 CN: 7 ON: (III) EN: 15 TeSiPh₃ (trisphenylsilyl-tellanyl), Cp (η⁵-cyclopentadienyl) Molecular 7-coordinate: ③₂-●-1 bent metallocene

[Zr(TeSiPh₃)(Cp)₂]
[Zr(Thf)(η⁴-Cot)(η⁸-Cot)] Zirconium VN: 2 CN: 7 ON: (II) EN: 18 Thf (tetrahydrofuran), Cot (η⁴-cyclooctatetraene), Cot (η⁸-cyclooctatetraene) Molecular 7-coordinate (geometry not specified)

[Zr(Thf)(η⁴-Cot)(η⁸-Cot)]
[Zr(Thf){η⁵-C₅H₄(SiMe₃)}(η⁷-C₇H₇)] Zirconium VN: 4 CN: 8 ON: (IV) EN: 18 Thf (tetrahydrofuran), C₅H₄(SiMe₃) (η⁵-(trimethylsilyl)cyclopentadienyl), C₇H₇ (η⁷-cycloheptatrienyl X₃L₂) Molecular 8-coordinate (geometry not specified)

[Zr(Thf){η⁵-C₅H₄(SiMe₃)}(η⁷-C₇H₇)]
[Zr(Tol-p)₂(Cp)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 Tol-p (p-tolyl), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(Tol-p)₂(Cp)₂]
[Zr(Tol-p)₂(η⁵-C₅HMe₄)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 Tol-p (p-tolyl), C₅HMe₄ (η⁵-tetramethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(Tol-p)₂(η⁵-C₅HMe₄)₂]
[Zr(Tol-p)₆]²⊖ Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 Tol-p (p-tolyl) Molecular 6-coordinate: octahedron (OC-6)

[Zr(Tol-p)₆]²⊖
[Zr(Tpp)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 Tpp (tetraphenylporphyrin) Molecular

[Zr(Tpp)₂]
[Zr(η³-C₃H₅)(η⁴-C₄H₆)(Cp)] Zirconium VN: 2 CN: 7 ON: (II) EN: 16 C₃H₅ (η³-allyl), C₄H₆ (η⁴-butadiene), Cp (η⁵-cyclopentadienyl) Molecular 7-coordinate: ③-●-4 piano stool

[Zr(η³-C₃H₅)(η⁴-C₄H₆)(Cp)]
[Zr(η³-C₃H₅)(η⁴-Cot)(Cp*)] Zirconium VN: 2 CN: 7 ON: (II) EN: 16 C₃H₅ (η³-allyl), Cot (η⁴-cyclooctatetraene), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 7-coordinate: ③-●-4 piano stool

[Zr(η³-C₃H₅)(η⁴-Cot)(Cp*)]
[Zr(η³-C₃H₅)₂(η⁸-C₈Me₆)] Zirconium VN: 4 CN: 8 ON: (IV) EN: 18 C₃H₅ (η³-allyl), C₈Me₆ (η⁸-hexamethylpentalene) Molecular 8-coordinate (geometry not specified)

[Zr(η³-C₃H₅)₂(η⁸-C₈Me₆)]
[Zr(η⁴-C₄H₆)(Cp)₂] Zirconium VN: 2 CN: 8 ON: (II) EN: 18 C₄H₆ (η⁴-butadiene), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(η⁴-C₄H₆)(Cp)₂]
[Zr(η⁴-Cot)(η⁸-Cot)] Zirconium VN: 2 CN: 6 ON: (II) EN: 16 Cot (η⁴-cyclooctatetraene), Cot (η⁸-cyclooctatetraene) Molecular 6-coordinate (geometry not specified)

[Zr(η⁴-Cot)(η⁸-Cot)]
[Zr(η⁵-C₅H₄Me)(η⁷-C₇H₇)] Zirconium VN: 4 CN: 7 ON: (IV) EN: 16 C₅H₄Me (η⁵-methylcyclopentadienyl), C₇H₇ (η⁷-cycloheptatrienyl X₃L₂) Molecular 7-coordinate: ③-●-4 piano stool

[Zr(η⁵-C₅H₄Me)(η⁷-C₇H₇)]
[Zr(η⁶-Cht)₂] Zirconium VN: 0 CN: 6 ON: (O) EN: 16 Cht (η⁶-cycloheptatriene) Molecular 6-coordinate (geometry not specified)

[Zr(η⁶-Cht)₂]
[Zr(η⁷-C₇H₇)(I)(PMe₃)₂] Zirconium VN: 4 CN: 7 ON: (IV) EN: 16 C₇H₇ (η⁷-cycloheptatrienyl X₃L₂), I (iodo), PMe₃ (trimethylphosphane) Molecular 7-coordinate: ④-●-3 piano stool

[Zr(η⁷-C₇H₇)(I)(PMe₃)₂]
[Zr(η⁸-C₈Me₆)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 18 (C₈Me₆)₂ (bis(η⁸-hexamethylpentalene) Ⓢ) Molecular 8-coordinate (geometry not specified)

[Zr(η⁸-C₈Me₆)₂]