Chemicals

Central atom: Zirconium
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
[Zr(SnMe₃)(CO)₄(Dppe-κ²P)]⊖ Zirconium VN: 0 CN: 7 ON: (O) EN: 18 SnMe₃ (trimethylstannyl), CO (carbonyl), Dppe (1,2-bis-(diphenylphosphino)ethane-κ²P) Molecular 7-coordinate: trigonal prism, square-face monocapped (TPRS-7)

[Zr(SnMe₃)(CO)₄(Dppe-κ²P)]⊖
[Zr(SnMe₃)₂(CO)₅]²⊖ Zirconium VN: 0 CN: 7 ON: (O) EN: 18 SnMe₃ (trimethylstannyl), CO (carbonyl) Molecular 7-coordinate: trigonal prism, square-face monocapped (TPRS-7)

[Zr(SnMe₃)₂(CO)₅]²⊖
[Zr(SnPh₃)₄(CO)₄]²⊖ Zirconium VN: 2 CN: 8 ON: (II) EN: 18 SnPh₃ (triphenylstannyl), CO (carbonyl) Molecular 8-coordinate: dodecahedron (DD-8)

[Zr(SnPh₃)₄(CO)₄]²⊖
[Zr(SO₃CF₃-κO)(Bpy)(Cp)₂]⊕ Zirconium VN: 4 CN: 9 ON: (IV) EN: 18 OSO₂CF₃ (trifluoromethanesulfonato-κO), Bpy (bipyridine), Cp (η⁵-cyclopentadienyl) Molecular 9-coordinate: ③₂-●-3 bent metallocene

[Zr(SO₃CF₃-κO)(Bpy)(Cp)₂]⊕
[Zr(SO₃CF₃-κO)(NHPh)(Cp)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 18 OSO₂CF₃ (trifluoromethanesulfonato-κO), NHPh (phenylamino: planar), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(SO₃CF₃-κO)(NHPh)(Cp)₂]
[Zr(SO₃CF₃-κO)(OH₂)₂(Cp)₂]⊕ Zirconium VN: 4 CN: 9 ON: (IV) EN: 18 OSO₂CF₃ (trifluoromethanesulfonato-κO), OH₂ (aqua), Cp (η⁵-cyclopentadienyl) Molecular 9-coordinate: ③₂-●-3 bent metallocene

[Zr(SO₃CF₃-κO)(OH₂)₂(Cp)₂]⊕
[Zr(SO₃CF₃-κO)₂(Cp)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 OSO₂CF₃ (trifluoromethanesulfonato-κO), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(SO₃CF₃-κO)₂(Cp)₂]
[Zr(SO₃CF₃-κO)₂(Cp*)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 OSO₂CF₃ (trifluoromethanesulfonato-κO), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(SO₃CF₃-κO)₂(Cp*)₂]
[Zr(SO₃CF₃-κO)₂(Thf)(Cp)₂] Zirconium VN: 4 CN: 9 ON: (IV) EN: 18 OSO₂CF₃ (trifluoromethanesulfonato-κO), Thf (tetrahydrofuran), Cp (η⁵-cyclopentadienyl) Molecular 9-coordinate: ③₂-●-3 bent metallocene

[Zr(SO₃CF₃-κO)₂(Thf)(Cp)₂]
[Zr(SO₄-κO)(SO₄-κ²O)₂(OH₂)₃]²⊖ Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 SO₄ (sulphato-κO), SO₄ (sulphato-κ²O), OH₂ (aqua) Molecular 8-coordinate (geometry not specified)

[Zr(SO₄-κO)(SO₄-κ²O)₂(OH₂)₃]²⊖
[Zr(SO₄-κ²O)₃(Dmso-κO)₂]²⊖ Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 SO₄ (sulphato-κ²O), Dmso (dimethylsulfoxide-κO) Molecular 8-coordinate (geometry not specified)

[Zr(SO₄-κ²O)₃(Dmso-κO)₂]²⊖
[Zr(SO₄-κ²O)₄]⁴⊖ Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 SO₄ (sulphato-κ²O) Molecular 8-coordinate: dodecahedron (DD-8)

[Zr(SO₄-κ²O)₄]⁴⊖
[Zr(SPh)₂(Cp)(η⁵-C₅H₄Buᵗ)] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 SPh (phenylthio), Cp (η⁵-cyclopentadienyl), C₅H₄Buᵗ (η⁵-t-butyl-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(SPh)₂(Cp)(η⁵-C₅H₄Buᵗ)]
[Zr(SPh)₂(Cp*)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 SPh (phenylthio), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(SPh)₂(Cp*)₂]
[Zr(Te₂)(CO)(Cp*)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 Te₂ (pertellurido-κTe), CO (carbonyl), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(Te₂)(CO)(Cp*)₂]
[Zr(Te₃)(Cp*)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 Te₃ (tritellurido-κ²Te), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(Te₃)(Cp*)₂]
[Zr(TePh)(Py)(η⁵-C₅EtMe₄)₂] Zirconium VN: 3 CN: 8 ON: (III) EN: 17 TePh (phenyltellanyl), Py (pyridine), C₅EtMe₄ (η⁵-ethyltetramethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(TePh)(Py)(η⁵-C₅EtMe₄)₂]
[Zr(TePh)₂(Cp*)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 TePh (phenyltellanyl), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(TePh)₂(Cp*)₂]
[Zr(TeSiPh₃)(Cp)₂] Zirconium VN: 3 CN: 7 ON: (III) EN: 15 TeSiPh₃ (trisphenylsilyl-tellanyl), Cp (η⁵-cyclopentadienyl) Molecular 7-coordinate: ③₂-●-1 bent metallocene

[Zr(TeSiPh₃)(Cp)₂]
[Zr(Thf)(η⁴-Cot)(η⁸-Cot)] Zirconium VN: 2 CN: 7 ON: (II) EN: 18 Thf (tetrahydrofuran), Cot (η⁴-cyclooctatetraene), Cot (η⁸-cyclooctatetraene) Molecular 7-coordinate (geometry not specified)

[Zr(Thf)(η⁴-Cot)(η⁸-Cot)]