Chemicals

Central atom: Zirconium
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
[Zr(O₂NO-κ²O)₅]⊖ Zirconium VN: 4 CN: 10 ON: (IV) EN: 20 NO₃ (nitrato-κ²O) Molecular 10-coordinate (geometry not specified)

[Zr(O₂NO-κ²O)₅]⊖
[Zr(OBuᵗ)(Thf)(Cp)₂]⊕ Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 OBuᵗ (t-butyloxy), Thf (tetrahydrofuran), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(OBuᵗ)(Thf)(Cp)₂]⊕
[Zr(OBuᵗ)(η³-C₃H₅)(η⁸-Cot)] Zirconium VN: 4 CN: 7 ON: (IV) EN: 16 OBuᵗ (t-butyloxy), C₃H₅ (η³-allyl), Cot (η⁸-cyclooctatetraene) Molecular 7-coordinate (geometry not specified)

[Zr(OBuᵗ)(η³-C₃H₅)(η⁸-Cot)]
[Zr(OBuᵗ)₂(Cp)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 OBuᵗ (t-butyloxy), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(OBuᵗ)₂(Cp)₂]
cis–[Zr(OBuᵗ)₂(Oep)] Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 OBuᵗ (t-butyloxy), Oep (octaethylporphyrin) Molecular 6-coordinate: trigonal prism (TPR-6)

cis–[Zr(OBuᵗ)₂(Oep)]
fac–[Zr(OBuᵗ)₃(Thf)₃]⊕ Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 OBuᵗ (t-butyloxy), Thf (tetrahydrofuran) Molecular 6-coordinate: octahedron (OC-6)

fac–[Zr(OBuᵗ)₃(Thf)₃]⊕
[Zr(OBuᵗ)₃{Si(SiMe₃)₃}] Zirconium VN: 4 CN: 4 ON: (IV) EN: 8 OBuᵗ (t-butyloxy), Si(SiMe₃)₃ (tris-trimethylsilyl-silyl) Molecular 4-coordinate: tetrahedron (T-4)

[Zr(OBuᵗ)₃{Si(SiMe₃)₃}]
[Zr(OC₆F₅)₂(Cp)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 OC₆F₅ (pentafluorophenoxy), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(OC₆F₅)₂(Cp)₂]
[Zr(Oep)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 Oep (octaethylporphyrin) Molecular

[Zr(Oep)₂]
[Zr(OEt)(OEt₂)(Cp)₂]⊕ Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 OEt (ethoxy), OEt₂ (diethylether), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(OEt)(OEt₂)(Cp)₂]⊕
[Zr(OH)(NHPh)(Cp*)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 18 OH (hydroxo), NHPh (phenylamino: planar), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(OH)(NHPh)(Cp*)₂]
[Zr(OH)₂(Cp*)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 OH (hydroxo), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(OH)₂(Cp*)₂]
[Zr(OH₂)₂(Acac)₃]⊕ Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 OH₂ (aqua), Acac (acetylacetonato) Molecular 8-coordinate: trigonal prism, square-face bicapped (TPRS-8)

[Zr(OH₂)₂(Acac)₃]⊕
[Zr(OH₂)₂{NC₅H₃(CO₂)₂-κN,κ²O}₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 OH₂ (aqua), NC₅H₃(CO₂)₂ (pyridinedicarboxylato-2,6-κN,κ²O)) Molecular 8-coordinate: trigonal prism, square-face bicapped (TPRS-8)

[Zr(OH₂)₂{NC₅H₃(CO₂)₂-κN,κ²O}₂]
[Zr(OH₂)₃(Cp)₂]²⊕ Zirconium VN: 4 CN: 9 ON: (IV) EN: 18 OH₂ (aqua), Cp (η⁵-cyclopentadienyl) Molecular 9-coordinate: ③₂-●-3 bent metallocene

[Zr(OH₂)₃(Cp)₂]²⊕
[Zr(OHMe)₂{NC₅H₃(CO₂)₂-κN,κ²O}₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 OHMe (methanol), NC₅H₃(CO₂)₂ (pyridinedicarboxylato-2,6-κN,κ²O)) Molecular 8-coordinate: trigonal prism, square-face bicapped (TPRS-8)

[Zr(OHMe)₂{NC₅H₃(CO₂)₂-κN,κ²O}₂]
[Zr(OMes)(Cp*)₂]⊕ Zirconium VN: 4 CN: 7 ON: (IV) EN: 14 OMes (mesityloxy), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 7-coordinate: ③₂-●-1 bent metallocene

[Zr(OMes)(Cp*)₂]⊕
[Zr(OMes)(Thf)(Cp)₂]⊕ Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 OMes (mesityloxy), Thf (tetrahydrofuran), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(OMes)(Thf)(Cp)₂]⊕
[Zr(OMes)(Thf)(Cp*)₂]⊕ Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 OMes (mesityloxy), Thf (tetrahydrofuran), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(OMes)(Thf)(Cp*)₂]⊕
[Zr(OPh)(Dmdtc)(Cp)₂] Zirconium VN: 4 CN: 9 ON: (IV) EN: 18 OPh (phenoxy), Dmdtc (dimethyldithiocarbamato-κ²S), Cp (η⁵-cyclopentadienyl) Molecular 9-coordinate: ③₂-●-3 bent metallocene

[Zr(OPh)(Dmdtc)(Cp)₂]