Chemicals

Central atom: Zirconium
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
[Zr(NMe₂)₂(=NBuᵗ)]₂ Zirconium VN: 4 CN: 3 ON: (IV) EN: 12 NMe₂ (dimethylamino: planar), =NBuᵗ (t-butylimino) Oligomer 4-coordinate: tetrahedron (T-4)

[Zr(NMe₂)₂(=NBuᵗ)]₂
[Zr(NMe₂)₃(η⁵-C₅Ph₅)] Zirconium VN: 4 CN: 6 ON: (IV) EN: 18 NMe₂ (dimethylamino: planar), C₅Ph₅ (η⁵-pentaphenylcyclopentadienyl) Molecular 6-coordinate: ③-●-3 piano stool

[Zr(NMe₂)₃(η⁵-C₅Ph₅)]
[Zr(NMe₂)₃(μ₂-NMe₂)]₂ Zirconium VN: 4 CN: 5 ON: (IV) EN: 16 NMe₂ (dimethylamino: planar), NMe₂ (μ₂-dimethylamino) Oligomer 4-coordinate: tetrahedron (T-4)

[Zr(NMe₂)₃(μ₂-NMe₂)]₂
[Zr(NPBuᵗ₃)₂(NEt₂)₂] Zirconium VN: 4 CN: 4 ON: (IV) EN: 16 NPBuᵗ₃ (tri-t-butylphosphane nitride), NEt₂ (diethylamino: planar) Molecular 4-coordinate: tetrahedron (T-4)

[Zr(NPBuᵗ₃)₂(NEt₂)₂]
[Zr(NPBuᵗ₃)₃(NMe₂)] Zirconium VN: 4 CN: 4 ON: (IV) EN: 16 NPBuᵗ₃ (tri-t-butylphosphane nitride), NMe₂ (dimethylamino: planar) Molecular 4-coordinate: tetrahedron (T-4)

[Zr(NPBuᵗ₃)₃(NMe₂)]
[Zr(O)(Py)(η⁵-C₅EtMe₄)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 18 O (oxo X₂), Py (pyridine), C₅EtMe₄ (η⁵-ethyltetramethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(O)(Py)(η⁵-C₅EtMe₄)₂]
[Zr(O₂C₇H₅-κ²O)₄] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 O₂C₇H₅ (tropolonato-κ²O) Molecular 8-coordinate: trigonal prism, square-face bicapped (TPRS-8)

[Zr(O₂C₇H₅-κ²O)₄]
[Zr(O₂CCF₃-κO)₂(Cp*)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 O₂CCF₃ (trifluoroacetato-κO), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(O₂CCF₃-κO)₂(Cp*)₂]
cis–[Zr(O₂CMe)₂(Tpp)] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 O₂CMe (acetato-κ²O), Tpp (tetraphenylporphyrin) Molecular

cis–[Zr(O₂CMe)₂(Tpp)]
[Zr(O₂CMe)₃(Cp)] Zirconium VN: 4 CN: 9 ON: (IV) EN: 18 O₂CMe (acetato-κ²O), Cp (η⁵-cyclopentadienyl) Molecular

[Zr(O₂CMe)₃(Cp)]
[Zr(O₂CMe)₃(Cp*)] Zirconium VN: 4 CN: 9 ON: (IV) EN: 18 O₂CMe (acetato-κ²O), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular

[Zr(O₂CMe)₃(Cp*)]
[Zr(O₂CNEt₂)₃(Cp)] Zirconium VN: 4 CN: 9 ON: (IV) EN: 18 O₂CNEt₂ (diethylcarbamato-κ²O), Cp (η⁵-cyclopentadienyl) Molecular

[Zr(O₂CNEt₂)₃(Cp)]
[Zr(O₂CNEt₂)₄] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 O₂CNEt₂ (diethylcarbamato-κ²O) Molecular 8-coordinate: dodecahedron (DD-8)

[Zr(O₂CNEt₂)₄]
cis–[Zr(O₂CPh-κ²O)₂(Tpp)] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 O₂CPh (benzoato-κ²O), Tpp (tetraphenylporphyrin) Molecular

cis–[Zr(O₂CPh-κ²O)₂(Tpp)]
[Zr(O₂NO-κ²O)₅]⊖ Zirconium VN: 4 CN: 10 ON: (IV) EN: 20 NO₃ (nitrato-κ²O) Molecular 10-coordinate (geometry not specified)

[Zr(O₂NO-κ²O)₅]⊖
[Zr(OBuᵗ)(Thf)(Cp)₂]⊕ Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 OBuᵗ (t-butyloxy), Thf (tetrahydrofuran), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(OBuᵗ)(Thf)(Cp)₂]⊕
[Zr(OBuᵗ)(η³-C₃H₅)(η⁸-Cot)] Zirconium VN: 4 CN: 7 ON: (IV) EN: 16 OBuᵗ (t-butyloxy), C₃H₅ (η³-allyl), Cot (η⁸-cyclooctatetraene) Molecular 7-coordinate (geometry not specified)

[Zr(OBuᵗ)(η³-C₃H₅)(η⁸-Cot)]
[Zr(OBuᵗ)₂(Cp)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 OBuᵗ (t-butyloxy), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(OBuᵗ)₂(Cp)₂]
cis–[Zr(OBuᵗ)₂(Oep)] Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 OBuᵗ (t-butyloxy), Oep (octaethylporphyrin) Molecular 6-coordinate: trigonal prism (TPR-6)

cis–[Zr(OBuᵗ)₂(Oep)]
fac–[Zr(OBuᵗ)₃(Thf)₃]⊕ Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 OBuᵗ (t-butyloxy), Thf (tetrahydrofuran) Molecular 6-coordinate: octahedron (OC-6)

fac–[Zr(OBuᵗ)₃(Thf)₃]⊕