6-coordinate: trigonal prism (TPR-6)

[Ti(CO)₄(μ₂-OPh)]⊖

Formula Unicode styled: 
[Ti(CO)₄(μ₂-OPh)]⊖
Compound name(s): 
bis-[(μ₂-phenolato)-tetracarbonyl-titanium(1-)]
Central atom: 
Titanium
Attached groups: 
CO (carbonyl)
OPh (μ₂-phenoxy)
Charge on central atom: 
-1
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 0
Oxidation Number (ON) (Roman numerals): 
ON: (O)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 16
Summary of calculated classifications: 
Ti«V0C6OOE16B6Z0X1L5»⊖
[MLXZ]𝘲 class: 
[MX1L5]-
MLXZ class (ENC, equivalent neutral class): 
ML6

[Ta(η³-C₈H₈)₃]⊖

Formula Unicode styled: 
[Ta(η³-C₈H₈)₃]⊖
Compound name(s): 
tris(η³-cycloocta-1,3,5-trienyl)-tantalum(1-)
Central atom: 
Tantalum
Attached groups: 
C₈H₈ (η³-cyclooctatetraenyl)
Charge on central atom: 
-1
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 15
Summary of calculated classifications: 
Ta«V2C6OIIE15B6Z0X3L3»⊖
[MLXZ]𝘲 class: 
[MX3L3]-
MLXZ class (ENC, equivalent neutral class): 
MX2L4

[Nb(η⁴-C₄H₆)₃]⊖

Formula Unicode styled: 
[Nb(η⁴-C₄H₆)₃]⊖
Compound name(s): 
tris(η⁴-1,3-butadiene)-niobium(1-)
Central atom: 
Niobium
Attached groups: 
C₄H₆ (η⁴-butadiene)
Charge on central atom: 
-1
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 1
Oxidation Number (ON) (Roman numerals): 
ON: (-I)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Nb«V1C6O-IE18B7Z0X0L6»⊖
[MLXZ]𝘲 class: 
[ML6]-
MLXZ class (ENC, equivalent neutral class): 
MX1L6

[Ta(η⁴-C₄H₆)₃]⊖

Formula Unicode styled: 
[Ta(η⁴-C₄H₆)₃]⊖
Compound name(s): 
tris(η⁴-1,3-butadiene)-tantalum(1-)
Central atom: 
Tantalum
Attached groups: 
C₄H₆ (η⁴-butadiene)
Charge on central atom: 
-1
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 1
Oxidation Number (ON) (Roman numerals): 
ON: (-I)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Ta«V1C6O-IE18B7Z0X0L6»⊖
[MLXZ]𝘲 class: 
[ML6]-
MLXZ class (ENC, equivalent neutral class): 
MX1L6

[Hf(η³-C₈H₈)₂(η⁴-Cot)]²⊖

Formula Unicode styled: 
[Hf(η³-C₈H₈)₂(η⁴-Cot)]²⊖
Compound name(s): 
(η⁴-1,3,5,7-cyclooctatetraene)-bis(η³-cycloocta-1,3,5-trienyl)-hafnium
Central atom: 
Hafnium
Attached groups: 
C₈H₈ (η³-cyclooctatetraenyl)
Cot (η⁴-cyclooctatetraene)
Charge on central atom: 
-2
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 0
Oxidation Number (ON) (Roman numerals): 
ON: (O)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 16
Summary of calculated classifications: 
Hf«V0C6OOE16B6Z0X2L4»2⊖
[MLXZ]𝘲 class: 
[MX2L4]2-
MLXZ class (ENC, equivalent neutral class): 
ML6

cis–[Tl(Cl)₂(Pc)]⊖

Formula Unicode styled: 
cis–[Tl(Cl)₂(Pc)]⊖
Compound name(s): 
cis-dichloro-phthalocyaninato-thallium(1-)
Central atom: 
Thallium
Attached groups: 
Cl (chloro)
Pc (phthalocyaninato)
Charge on central atom: 
-1
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 12
Summary of calculated classifications: 
Tl«V3C6OIIIE12B6Z0X4L2»⊖
[MLXZ]𝘲 class: 
[MX4L2]-
MLXZ class (ENC, equivalent neutral class): 
MX3L3

[Hg([18]aneN₆-κ⁶N)]²⊕

Formula Unicode styled: 
[Hg([18]aneN₆-κ⁶N)]²⊕
Compound name(s): 
(1,4,7,10,13,16-Hexa-azacyclo-octadecane)-mercury(2+)
Central atom: 
Mercury
Attached groups: 
[18]aneN₆ (1,4,7,10,13,16-hexaaza-cyclo-octadecane-κ⁶N)
Charge on central atom: 
2
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 12
Summary of calculated classifications: 
Hg«V2C6OIIE12B6Z0X0L6»2⊕
[MLXZ]𝘲 class: 
[ML6]2+
MLXZ class (ENC, equivalent neutral class): 
MX2L4

network-[Ru(As)]

Formula Unicode styled: 
network-[Ru(As)]
Compound name(s): 
network-arsenido-ruthenium
Central atom: 
Arsenic
Attached groups: 
Ru (μ₆-ruthenio)
Charge on central atom: 
0
Compound type: 
Network
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 5
Oxidation Number (ON) (Roman numerals): 
ON: (-III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 8
Summary of calculated classifications: 
As«V5C6O-IIIE8B4L0X3Z1»
[MLXZ]𝘲 class: 
[MX3Z1]
MLXZ class (ENC, equivalent neutral class): 
MX3Z1

[Sm(μ₂-I)(Thf){N(SiMe₃)₂}(Dme)]₂

Formula Unicode styled: 
[Sm(μ₂-I)(Thf){N(SiMe₃)₂}(Dme)]₂
Compound name(s): 
bis-[μ₂-iodo-(1,2-dimethoxyethane-O,O')-tetrahydrofuran-(bis(trimethylsilyl)amide-N)-samarium]
Central atom: 
Samarium
Attached groups: 
I (μ₂-iodo)
Thf (tetrahydrofuran)
N(SiMe₃)₂ (bis(trimethylsilyl)amino: planar)
Dme (dimethoxyethane)
Charge on central atom: 
0
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 20
Summary of calculated classifications: 
Sm«V2C6OIIE20B7Z0X2L5»
[MLXZ]𝘲 class: 
[MX2L5]
MLXZ class (ENC, equivalent neutral class): 
MX2L5

[Yb(OC₆H₃Ph₂-2,6)₂(Dme)₂]

Formula Unicode styled: 
[Yb(OC₆H₃Ph₂-2,6)₂(Dme)₂]
Compound name(s): 
bis(1,2-Dimethoxyethane)-bis(2,6-diphenolato)-ytterbium
Central atom: 
Ytterbium
Attached groups: 
OC₆H₃Ph₂-2,6 (diphenylphenoxy-2,6)
Dme (dimethoxyethane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 26
Summary of calculated classifications: 
Yb«V2C6OIIE26B6Z0X2L4»
[MLXZ]𝘲 class: 
[MX2L4]
MLXZ class (ENC, equivalent neutral class): 
MX2L4

[W(η⁴-C₄H₄Me₂)₃]

Formula Unicode styled: 
[W(η⁴-C₄H₄Me₂)₃]
Compound name(s): 
tris(eta-2,3-Dimethylbutadienyl)-tungsten
Central atom: 
Tungsten
Attached groups: 
C₄H₄Me₂ (η⁴-dimethylbutadiene)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 0
Oxidation Number (ON) (Roman numerals): 
ON: (O)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
W«V0C6OOE18B6Z0X0L6»
[MLXZ]𝘲 class: 
[ML6]
MLXZ class (ENC, equivalent neutral class): 
ML6

[Ta(S)]

Formula Unicode styled: 
[Ta(S)]
Compound name(s): 
sulfido-tantalum
tantalum monosulfide
tantalum monosulphde
Central atom: 
Tantalum
Attached groups: 
S (thio)
Charge on central atom: 
Compound type: 
Lattice
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 0
Summary of calculated classifications: 
Ta«V2C6OII»
[MLXZ]𝘲 class: 
MLXZ class (ENC, equivalent neutral class): 

network–[Mo(μ₆-P)]

Formula Unicode styled: 
network–[Mo(μ₆-P)]
Compound name(s): 
phosphido-molybdenum
molybdenum phosphide
Central atom: 
Molybdenum
Attached groups: 
P (μ₆-phosphido)
Charge on central atom: 
0
Compound type: 
Network
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 15
Summary of calculated classifications: 
Mo«V3C6OIIIE15B6Z0X3L3»
[MLXZ]𝘲 class: 
[MX3L3]
MLXZ class (ENC, equivalent neutral class): 
MX3L3

catena–2D-[Zr(μ₃-Cl)₂]

Formula Unicode styled: 
catena–2D-[Zr(μ₃-Cl)₂]
Compound name(s): 
catena-[dichloro-zirconium]
zirconium dichloride
Central atom: 
Zirconium
Attached groups: 
Cl (μ₃-chloro)
Charge on central atom: 
0
Compound type: 
Catena-2D
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 14
Summary of calculated classifications: 
Zr«V2C6OIIE14B6Z0X2L4»
[MLXZ]𝘲 class: 
[MX2L4]
MLXZ class (ENC, equivalent neutral class): 
MX2L4

catena–2D-[W(μ₃-Se)₂]

Formula Unicode styled: 
catena–2D-[W(μ₃-Se)₂]
Compound name(s): 
catena-[diselenido-tungsten]
tungsten diselenide
Central atom: 
Tungsten
Attached groups: 
Se (μ₃-seleno X₂L)
Charge on central atom: 
0
Compound type: 
Catena-2D
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 14
Summary of calculated classifications: 
W«V4C6OIVE14B6Z0X4L2»
[MLXZ]𝘲 class: 
[MX4L2]
MLXZ class (ENC, equivalent neutral class): 
MX4L2

catena–2D-[W(μ₃-S)₂]

Formula Unicode styled: 
catena–2D-[W(μ₃-S)₂]
Compound name(s): 
catena-disulfido-tungsten
|tungsten disulphide
tungsten disulfide
catena-disulphido-tungsten
Central atom: 
Tungsten
Attached groups: 
S (μ₃-thio X₂L)
Charge on central atom: 
0
Compound type: 
Catena-2D
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 14
Summary of calculated classifications: 
W«V4C6OIVE14B6Z0X4L2»
[MLXZ]𝘲 class: 
[MX4L2]
MLXZ class (ENC, equivalent neutral class): 
MX4L2

catena–1D-[Ta(μ₃-Se)₂]

Formula Unicode styled: 
catena–1D-[Ta(μ₃-Se)₂]
Compound name(s): 
catena-diselenido-tantalum]
tantalum diselenide
Central atom: 
Tantalum
Attached groups: 
Se (μ₃-seleno X₂L)
Charge on central atom: 
0
Compound type: 
Catena-1D
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 13
Summary of calculated classifications: 
Ta«V4C6OIVE13B6Z0X4L2»
[MLXZ]𝘲 class: 
[MX4L2]
MLXZ class (ENC, equivalent neutral class): 
MX4L2

catena–1D-[Ta(μ₃-S)₂]

Formula Unicode styled: 
catena–1D-[Ta(μ₃-S)₂]
Compound name(s): 
catena-[disulfido-tantalum]
catena-[disulphido-tantalum]
tantalum disulphide
tantalum disulfide
Central atom: 
Tantalum
Attached groups: 
S (μ₃-thio X₂L)
Charge on central atom: 
0
Compound type: 
Catena-1D
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 13
Summary of calculated classifications: 
Ta«V4C6OIVE13B6Z0X4L2»
[MLXZ]𝘲 class: 
[MX4L2]
MLXZ class (ENC, equivalent neutral class): 
MX4L2

catena–2D-[Nb(μ₃-Se)₂]

Formula Unicode styled: 
catena–2D-[Nb(μ₃-Se)₂]
Compound name(s): 
catena-[diselenido-niobium]
niobium diselenide
Central atom: 
Niobium
Attached groups: 
Se (μ₃-seleno X₂L)
Charge on central atom: 
0
Compound type: 
Catena-2D
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 13
Summary of calculated classifications: 
Nb«V4C6OIVE13B6Z0X4L2»
[MLXZ]𝘲 class: 
[MX4L2]
MLXZ class (ENC, equivalent neutral class): 
MX4L2

catena–2D-[Nb(μ₃-S)₂]

Formula Unicode styled: 
catena–2D-[Nb(μ₃-S)₂]
Compound name(s): 
catena-[disulfido-niobium]|catena-[disulphido-niobium]|niobium disulfide|niobium disulphide
Central atom: 
Niobium
Attached groups: 
S (μ₃-thio X₂L)
Charge on central atom: 
0
Compound type: 
Catena-2D
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 13
Summary of calculated classifications: 
Nb«V4C6OIVE13B6Z0X4L2»
[MLXZ]𝘲 class: 
[MX4L2]
MLXZ class (ENC, equivalent neutral class): 
MX4L2