7-coordinate: ③₂-●-1 bent metallocene

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

C₆Me₆ (hexamethylbenzene)

Summary of calculated classifications:

Bi«V³C⁷O^IIIE¹⁶B⁷Z⁰X³L⁴»

[MLXZ]𝘲 class:

[MX₃L₄]

MLXZ class (ENC, equivalent neutral class):

MX₃L₄

[Ga(η⁶-C₆Me₆)₂]⊕

Formula Unicode styled:

[Ga(η⁶-C₆Me₆)₂]⊕

Compound name(s):

bis(hexamethylbenzene)-gallium(1+)

Central atom:

Gallium

Attached groups:

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ga«V¹C⁶O^IE¹⁴B⁶Z⁰X⁰L⁶»^⊕

[MLXZ]𝘲 class:

[ML₆]⁺

MLXZ class (ENC, equivalent neutral class):

MX₁L₅

[Ga(η⁶-C₆H₆)₂]⊕

Formula Unicode styled:

[Ga(η⁶-C₆H₆)₂]⊕

Compound name(s):

di(benzene)-gallium(1+)

Central atom:

Gallium

Attached groups:

C₆H₆ (benzene)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ga«V¹C⁶O^IE¹⁴B⁶Z⁰X⁰L⁶»^⊕

[MLXZ]𝘲 class:

[ML₆]⁺

MLXZ class (ENC, equivalent neutral class):

MX₁L₅

[Nb(CO)(η⁶-C₆H₃Me₃)₂]⊕

Formula Unicode styled:

[Nb(CO)(η⁶-C₆H₃Me₃)₂]⊕

Compound name(s):

bis(η⁶-mesitylene)-carbonyl-niobium(1+)

Central atom:

Niobium

Attached groups:

CO (carbonyl)

C₆H₃Me₃ (mesitylene)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Nb«V¹C⁷O^IE¹⁸B⁷Z⁰X⁰L⁷»^⊕

[MLXZ]𝘲 class:

[ML₇]⁺

MLXZ class (ENC, equivalent neutral class):

MX₁L₆

[Zr(Cp)₂}₂(μ₂-P)]

Formula Unicode styled:

[Zr(Cp)₂}₂(μ₂-P)]

Compound name(s):

(μ₂-phosphido)-tetrakis(η⁵-pentamethyl-cyclopentadienyl)-di-zirconium

Central atom:

Zirconium

Attached groups:

P group (X type)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

C₅HPrⁱ₄ (η⁵-tetraisopropylcyclopentadienyl)

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 17

Summary of calculated classifications:

Zr«V³C⁷O^IIIE¹⁷B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Tm(I)(η⁵-C₅HPrⁱ₄)₂]

Formula Unicode styled:

[Tm(I)(η⁵-C₅HPrⁱ₄)₂]

Compound name(s):

iodo-bis(η⁵-tetraisopropylcyclopentadienyl)-thulium

Central atom:

Thulium

Attached groups:

I (iodo)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

C₅H₂(Buᵗ)₃ (η⁵-tris(t-butyl)cyclopentadienyl)

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 26

Summary of calculated classifications:

Tm«V³C⁷O^IIIE²⁶B⁷Z⁰X³L⁴»

[MLXZ]𝘲 class:

[MX₃L₄]

MLXZ class (ENC, equivalent neutral class):

MX₃L₄

[Lu(Cl){η⁵-C₅H₂(Buᵗ)₃}₂]

Formula Unicode styled:

[Lu(Cl){η⁵-C₅H₂(Buᵗ)₃}₂]

Compound name(s):

bis(1,2,4-tri-t-butyl-cyclopentadienyl)-chloro-lutetium

Central atom:

Lutetium

Attached groups:

Cl (chloro)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

C₅HMe₄ (μ₂-η⁵,η⁵-tetramethylcyclopentadienyl)

Summary of calculated classifications:

Lu«V³C⁷O^IIIE¹⁴B⁷Z⁰X³L⁴»

[MLXZ]𝘲 class:

[MX₃L₄]

MLXZ class (ENC, equivalent neutral class):

MX₃L₄

catena–1D-[In(μ₂-η⁵,η⁵-C₅HMe₄)]

Formula Unicode styled:

catena–1D-[In(μ₂-η⁵,η⁵-C₅HMe₄)]

Compound name(s):

catena-[(μ₂-η⁵,η⁵-Tetramethyl-cyclopentadienyl)-indium]

Central atom:

Indium

Attached groups:

Charge on central atom:

0

Compound type:

Catena-1D

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

C₆Me₆ (η⁴-hexamethylbenzene)

Summary of calculated classifications:

In«V¹C⁶O^IE¹⁴B⁶Z⁰X¹L⁵»

[MLXZ]𝘲 class:

[MX₁L₅]

MLXZ class (ENC, equivalent neutral class):

MX₁L₅

[Tl(η⁴-C₆Me₆)₂]⊕

Formula Unicode styled:

[Tl(η⁴-C₆Me₆)₂]⊕

Compound name(s):

bis(η⁶-hexamethylbenzene)-thallium(1+)

Central atom:

Thallium

Attached groups:

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

C₅HMe₄ (η⁵-tetramethylcyclopentadienyl)

Coordination Number (CN, sum of attached group denticities):

CN: 4

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 10

Summary of calculated classifications:

Tl«V¹C⁴O^IE¹⁰B⁴Z⁰X⁰L⁴»^⊕

[MLXZ]𝘲 class:

[ML₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

[Pb(η⁵-C₅HMe₄)₂]

Formula Unicode styled:

[Pb(η⁵-C₅HMe₄)₂]

Compound name(s):

bis(η⁵-Tetramethyl-cyclopentadienyl)-lead

Central atom:

Lead

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Cp (μ₂-η⁵,η⁵-cyclopentadienyl)

Summary of calculated classifications:

Pb«V²C⁶O^IIE¹⁴B⁶Z⁰X²L⁴»

[MLXZ]𝘲 class:

[MX₂L₄]

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

catena–1D-[Tl(μ₂-η⁵,η⁵-Cp)]

Formula Unicode styled:

catena–1D-[Tl(μ₂-η⁵,η⁵-Cp)]

Compound name(s):

catena-[(η⁵-Cyclopentadienyl)-thallium]

Central atom:

Thallium

Attached groups:

Charge on central atom:

0

Compound type:

Catena-1D

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Tl«V¹C⁶O^IE¹⁴B⁶Z⁰X¹L⁵»

[MLXZ]𝘲 class:

[MX₁L₅]

MLXZ class (ENC, equivalent neutral class):

MX₁L₅

[Os(Cp)₂]₂²⊕

Formula Unicode styled:

[Os(Cp)₂]₂²⊕

Compound name(s):

bis-[bis-(η⁵-cyclopentadienyl)-osmium(Os—Os)(1+)]|Di-osmocenium(1+)

Central atom:

Osmium

Attached groups:

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

C₅HMe₄ (η⁵-tetramethylcyclopentadienyl)

Summary of calculated classifications:

Os«V⁴C⁷O^IIIE¹⁸B⁷Z⁰X³L⁴»^⊕

[MLXZ]𝘲 class:

[MX₃L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

[Os(Br)(η⁵-C₅HMe₄)₂]⊕

Formula Unicode styled:

[Os(Br)(η⁵-C₅HMe₄)₂]⊕

Compound name(s):

bromo-bis(η⁵-tetramethylcyclopentadienyl)-osmium(1+)

Central atom:

Osmium

Attached groups:

Br (bromo)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

C₈Me₆ (μ₂-hexamethylpentalene)

Summary of calculated classifications:

Os«V⁴C⁷O^IVE¹⁸B⁷Z⁰X³L⁴»^⊕

[MLXZ]𝘲 class:

[MX₃L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

[Mn(μ₂-C₈Me₆)]₂

Formula Unicode styled:

[Mn(μ₂-C₈Me₆)]₂

Compound name(s):

bis-[(μ₂-η⁵,η⁵-1,2,3,4,5,6-Hexamethylpentalene)-manganese]

Central atom:

Manganese

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

(C₆F₅)C≡C(C₆F₅) (bis-pentafluorophenyl-ethyne)

Summary of calculated classifications:

Mn«V³C⁷O^IIE¹⁸B⁷Z⁰X³L⁴»

[MLXZ]𝘲 class:

[MX₃L₄]

MLXZ class (ENC, equivalent neutral class):

MX₃L₄

[V{(C₆F₅)C≡C(C₆F₅)}(Cp)₂]

Formula Unicode styled:

[V{(C₆F₅)C≡C(C₆F₅)}(Cp)₂]

Compound name(s):

bis(eta-Cyclopentadienyl)-bis(pentafluorophenyl)-acetylene-vanadium

Central atom:

Vanadium

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

C₈Me₆ (η⁸-hexamethylpentalene)

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 17

Summary of calculated classifications:

V«V²C⁷O^IIE¹⁷B⁷Z⁰X²L⁵»

[MLXZ]𝘲 class:

[MX₂L₅]

MLXZ class (ENC, equivalent neutral class):

MX₂L₅

[V(η⁸-C₈Me₆)]₂

Formula Unicode styled:

[V(η⁸-C₈Me₆)]₂

Compound name(s):

bis-[(μ₂-η⁵,η⁵-1,2,3,4,5,6-Hexamethylpentalene)-vanadium(V≡V)]

Central atom:

Vanadium

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 5

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

O₂PPh₂ (diphenylphosphinate-κO)

Summary of calculated classifications:

V«V⁵C⁷O^IIE¹⁶B⁸Z⁰X⁵L³»

[MLXZ]𝘲 class:

[MX₅L₃]

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

[V(O₂PPh₂-κO)(Cp)₂]

Formula Unicode styled:

[V(O₂PPh₂-κO)(Cp)₂]

Compound name(s):

(diphenylphosphinato)-bis(η⁵-cyclopentadienyl)-vanadium

Central atom:

Vanadium

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

C₈H₆(SiMe₃)₂ (η⁸-bistrimethylsilyl-cyclooctatetraene)

Summary of calculated classifications:

V«V³C⁷O^IIIE¹⁶B⁷Z⁰X³L⁴»

[MLXZ]𝘲 class:

[MX₃L₄]

MLXZ class (ENC, equivalent neutral class):

MX₃L₄

[Ti{η⁸-C₈H₆(SiMe₃)₂}]₂

Formula Unicode styled:

[Ti{η⁸-C₈H₆(SiMe₃)₂}]₂

Compound name(s):

bis-[(μ₂-μ₅-,μ₅-1,4-bis(Trimethylsilyl)cyclo-octatetraene)-titanium(Ti=Ti)]

Central atom:

Titanium

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Me₃SiC≡CPh (trimethylsilyl-phenyl-ethyne)

Summary of calculated classifications:

Ti«V⁴C⁷O^IIE¹⁴B⁷Z⁰X⁴L³»

[MLXZ]𝘲 class:

[MX₄L₃]

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

[Hf(Me₃SiC≡CPh)(Cp*)₂]

Formula Unicode styled:

[Hf(Me₃SiC≡CPh)(Cp*)₂]

Compound name(s):

bis(η⁵-pentamethylcyclopentadienyl)-(η²-phenyl(trimethylsilyl)acetylene)-hafnium

Central atom:

Hafnium

Attached groups:

Cp* (η⁵-pentamethylcyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

C₈Me₆ (μ₂-hexamethylpentalene)

Summary of calculated classifications:

Hf«V²C⁷O^IIE¹⁶B⁷Z⁰X²L⁵»

[MLXZ]𝘲 class:

[MX₂L₅]

MLXZ class (ENC, equivalent neutral class):

MX₂L₅

[Cr(μ₂-C₈Me₆)]₂

Formula Unicode styled:

[Cr(μ₂-C₈Me₆)]₂

Compound name(s):

bis-[(μ₂-η⁵,η⁵-1,2,3,4,5,6-Hexamethylpentalene)-chromium(Cr=Cr)]

Central atom:

Chromium

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: