Chemicals

Central atom: Zirconium
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
[Zr(Me₃SiC≡CSiMe₃)(Cp*)₂] Zirconium VN: 2 CN: 7 ON: (II) EN: 16 Me₃SiC≡CSiMe₃ (bistrimethylsilylethyne), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 7-coordinate: ③₂-●-1 bent metallocene

[Zr(Me₃SiC≡CSiMe₃)(Cp*)₂]
[Zr(Mes)₂(η⁸-Cot)] Zirconium VN: 4 CN: 6 ON: (IV) EN: 14 Mes (mesityl), Cot (η⁸-cyclooctatetraene) Molecular 6-coordinate (geometry not specified)

[Zr(Mes)₂(η⁸-Cot)]
[Zr(N₃)₄(Bpy)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 N₃ (azido), Bpy (bipyridine) Molecular 8-coordinate: trigonal prism, square-face bicapped (TPRS-8)

[Zr(N₃)₄(Bpy)₂]
[Zr(N₃)₆]²⊖ Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 N₃ (azido) Molecular 6-coordinate: octahedron (OC-6)

[Zr(N₃)₆]²⊖
[Zr(NC₄H₂Me₂)₂(Cp)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 NC₄H₂Me₂ (dimethylpyrrolyl), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(NC₄H₂Me₂)₂(Cp)₂]
[Zr(NC₄H₂Me₂)₄] Zirconium VN: 4 CN: 4 ON: (IV) EN: 8 NC₄H₂Me₂ (dimethylpyrrolyl) Molecular 4-coordinate: tetrahedron (T-4)

[Zr(NC₄H₂Me₂)₄]
[Zr(NCMe)(Cp₃)]⊕ Zirconium VN: 4 CN: 10 ON: (IV) EN: 18 NCMe (acetonitrile), (Cp₃) (tris-(η⁵-cyclopentadienyl) Ⓢ) Molecular 10-coordinate: ③₃-●-1 bent metallocene

[Zr(NCMe)(Cp₃)]⊕
[Zr(NCS-κN)₂(Cp)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 NCS (isothiocyanato-κN), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(NCS-κN)₂(Cp)₂]
[Zr(NCS-κN)₄(Bpy)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 NCS (isothiocyanato-κN), Bpy (bipyridine) Molecular 8-coordinate: trigonal prism, square-face bicapped (TPRS-8)

[Zr(NCS-κN)₄(Bpy)₂]
[Zr(NH₂){N(SiMe₃)₂}₂] Zirconium VN: 3 CN: 3 ON: (III) EN: 13 NH₂ (amino: planar), N(SiMe₃)₂ (bis(trimethylsilyl)amino: planar) Molecular 4-coordinate: tetrahedron (T-4)

[Zr(NH₂){N(SiMe₃)₂}₂]
[Zr(NH₃)(η⁴-Cot)(η⁸-Cot)] Zirconium VN: 2 CN: 7 ON: (II) EN: 18 NH₃ (ammine), Cot (η⁴-cyclooctatetraene), Cot (η⁸-cyclooctatetraene) Molecular 7-coordinate (geometry not specified)

[Zr(NH₃)(η⁴-Cot)(η⁸-Cot)]
[Zr(NH₃)₈]⁴⊕ Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 NH₃ (ammine) Molecular 8-coordinate: trigonal prism, square-face bicapped (TPRS-8)

[Zr(NH₃)₈]⁴⊕
[Zr(NHBuᵗ)₃(Cp*)] Zirconium VN: 4 CN: 6 ON: (IV) EN: 18 NHBuᵗ (t-butylamino: planar), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 6-coordinate: ③-●-3 piano stool

[Zr(NHBuᵗ)₃(Cp*)]
trans–[Zr(NHMe)₃(NHMe₂)₂]⊕ Zirconium VN: 4 CN: 5 ON: (IV) EN: 16 NHMe (methylamino: planar), NHMe₂ (dimethylamine) Molecular 5-coordinate: trigonal bipyramid (TBPY-5)

trans–[Zr(NHMe)₃(NHMe₂)₂]⊕
trans–[Zr(NHMe)₃(Thf)₂]⊕ Zirconium VN: 4 CN: 5 ON: (IV) EN: 16 NHMe (methylamino: planar), Thf (tetrahydrofuran) Molecular 5-coordinate: trigonal bipyramid (TBPY-5)

trans–[Zr(NHMe)₃(Thf)₂]⊕
fac–[Zr(NHMe)₃(Thf)₃]⊕ Zirconium VN: 4 CN: 6 ON: (IV) EN: 18 NHMe (methylamino: planar), Thf (tetrahydrofuran) Molecular 6-coordinate: octahedron (OC-6)

fac–[Zr(NHMe)₃(Thf)₃]⊕
fac–[Zr(NHMe)₃(Tp-κ³N)] Zirconium VN: 4 CN: 6 ON: (IV) EN: 18 NHMe (methylamino: planar), Tp (hydrotris(pyrazolyl)borato-κ³N) Molecular 6-coordinate: octahedron (OC-6)

fac–[Zr(NHMe)₃(Tp-κ³N)]
[Zr(NHPh)₂(Cp*)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 NHPh (phenylamino), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(NHPh)₂(Cp*)₂]
[Zr(NHPh)₂(OC₆H₃Buᵗ₂-2,6)₂] Zirconium VN: 4 CN: 4 ON: (IV) EN: 12 NHPh (phenylamino: planar), OC₆H₃Buᵗ₂-2,6 (di-t-butylphenoxy-2,6) Molecular 4-coordinate: tetrahedron (T-4)

[Zr(NHPh)₂(OC₆H₃Buᵗ₂-2,6)₂]
[Zr(NMe₂)(NPh₂)₃] Zirconium VN: 4 CN: 4 ON: (IV) EN: 16 NMe₂ (dimethylamino: planar), NPh₂ (diphenylamino: planar) Molecular 4-coordinate: tetrahedron (T-4)

[Zr(NMe₂)(NPh₂)₃]