Chemicals

Central atom: Zirconium
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
trans–[Zr(NHMe)₃(Thf)₂]⊕ Zirconium VN: 4 CN: 5 ON: (IV) EN: 16 NHMe (methylamino: planar), Thf (tetrahydrofuran) Molecular 5-coordinate: trigonal bipyramid (TBPY-5)

trans–[Zr(NHMe)₃(Thf)₂]⊕

fac–[Zr(NHMe)₃(Thf)₃]⊕ Zirconium VN: 4 CN: 6 ON: (IV) EN: 18 NHMe (methylamino: planar), Thf (tetrahydrofuran) Molecular 6-coordinate: octahedron (OC-6)

fac–[Zr(NHMe)₃(Thf)₃]⊕

fac–[Zr(NHMe)₃(Tp-κ³N)] Zirconium VN: 4 CN: 6 ON: (IV) EN: 18 NHMe (methylamino: planar), Tp (hydrotris(pyrazolyl)borato-κ³N) Molecular 6-coordinate: octahedron (OC-6)

fac–[Zr(NHMe)₃(Tp-κ³N)]

[Zr(NHPh)₂(Cp*)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 NHPh (phenylamino), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(NHPh)₂(Cp*)₂]

[Zr(NHPh)₂(OC₆H₃Buᵗ₂-2,6)₂] Zirconium VN: 4 CN: 4 ON: (IV) EN: 12 NHPh (phenylamino: planar), OC₆H₃Buᵗ₂-2,6 (di-t-butylphenoxy-2,6) Molecular 4-coordinate: tetrahedron (T-4)

[Zr(NHPh)₂(OC₆H₃Buᵗ₂-2,6)₂]

[Zr(NMe₂)(NPh₂)₃] Zirconium VN: 4 CN: 4 ON: (IV) EN: 16 NMe₂ (dimethylamino: planar), NPh₂ (diphenylamino: planar) Molecular 4-coordinate: tetrahedron (T-4)

[Zr(NMe₂)(NPh₂)₃]

[Zr(NMe₂)₂(μ₂-NBuᵗ)]₂ Zirconium VN: 4 CN: 4 ON: (IV) EN: 14 NMe₂ (dimethylamino: planar), NBuᵗ (μ₂-t-butylimino X₂L) Oligomer 4-coordinate: tetrahedron (T-4)

[Zr(NMe₂)₂(μ₂-NBuᵗ)]₂

[Zr(NMe₂)₃(η⁵-C₅Ph₅)] Zirconium VN: 4 CN: 6 ON: (IV) EN: 18 NMe₂ (dimethylamino: planar), C₅Ph₅ (η⁵-pentaphenylcyclopentadienyl) Molecular 6-coordinate: ③-●-3 piano stool

[Zr(NMe₂)₃(η⁵-C₅Ph₅)]

[Zr(NMe₂)₃(μ₂-NMe₂)]₂ Zirconium VN: 4 CN: 5 ON: (IV) EN: 16 NMe₂ (dimethylamino: planar), NMe₂ (μ₂-dimethylamino) Oligomer 5-coordinate: trigonal bipyramid (TBPY-5)

[Zr(NMe₂)₃(μ₂-NMe₂)]₂

[Zr(NPBuᵗ₃)₂(NEt₂)₂] Zirconium VN: 4 CN: 4 ON: (IV) EN: 16 NPBuᵗ₃ (tri-t-butylphosphane nitride), NEt₂ (diethylamino: planar) Molecular 4-coordinate: tetrahedron (T-4)

[Zr(NPBuᵗ₃)₂(NEt₂)₂]

[Zr(NPBuᵗ₃)₃(NMe₂)] Zirconium VN: 4 CN: 4 ON: (IV) EN: 16 NPBuᵗ₃ (tri-t-butylphosphane nitride), NMe₂ (dimethylamino: planar) Molecular 4-coordinate: tetrahedron (T-4)

[Zr(NPBuᵗ₃)₃(NMe₂)]

[Zr(O)(Py)(η⁵-C₅EtMe₄)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 18 O (oxo X₂), Py (pyridine), C₅EtMe₄ (η⁵-ethyltetramethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(O)(Py)(η⁵-C₅EtMe₄)₂]

[Zr(O₂C₇H₅-κ²O)₄] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 O₂C₇H₅ (tropolonato-κ²O) Molecular 8-coordinate: trigonal prism, square-face bicapped (TPRS-8)

[Zr(O₂C₇H₅-κ²O)₄]

[Zr(O₂CCF₃-κO)₂(Cp*)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 O₂CCF₃ (trifluoroacetato-κO), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(O₂CCF₃-κO)₂(Cp*)₂]

cis–[Zr(O₂CMe)₂(Tpp)] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 O₂CMe (acetato-κ²O), Tpp (tetraphenylporphyrin) Molecular

cis–[Zr(O₂CMe)₂(Tpp)]

[Zr(O₂CMe)₃(Cp)] Zirconium VN: 4 CN: 9 ON: (IV) EN: 18 O₂CMe (acetato-κ²O), Cp (η⁵-cyclopentadienyl) Molecular

[Zr(O₂CMe)₃(Cp)]

[Zr(O₂CMe)₃(Cp*)] Zirconium VN: 4 CN: 9 ON: (IV) EN: 18 O₂CMe (acetato-κ²O), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular

[Zr(O₂CMe)₃(Cp*)]

[Zr(O₂CNEt₂)₃(Cp)] Zirconium VN: 4 CN: 9 ON: (IV) EN: 18 O₂CNEt₂ (diethylcarbamato-κ²O), Cp (η⁵-cyclopentadienyl) Molecular

[Zr(O₂CNEt₂)₃(Cp)]

[Zr(O₂CNEt₂)₄] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 O₂CNEt₂ (diethylcarbamato-κ²O) Molecular 8-coordinate: dodecahedron (DD-8)

[Zr(O₂CNEt₂)₄]

cis–[Zr(O₂CPh-κ²O)₂(Tpp)] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 O₂CPh (benzoato-κ²O), Tpp (tetraphenylporphyrin) Molecular

cis–[Zr(O₂CPh-κ²O)₂(Tpp)]