7-coordinate: ③-●-4 piano stool

PCy₃ (tricyclohexylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Cr«V²C⁷O^IIE¹⁸B⁷Z⁰X²L⁵»

[MLXZ]𝘲 class:

[MX₂L₅]

MLXZ class (ENC, equivalent neutral class):

MX₂L₅

[Ta(H)(Cp){Ir(H)(Cp*)}]₂

Formula Unicode styled:

[Ta(H)(Cp){Ir(H)(Cp*)}]₂

Compound name(s):

bis-[hydrido-{μ₂-(hydrido-η⁵-pentamethylcyclopentadienyl-iridium)}-(η⁵-pentamethylcyclopentadienyl)-tantalum]

Central atom:

Tantalum

Attached groups:

H (hydrido)

Ir group (X type)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 5

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 14

Summary of calculated classifications:

Ta«V⁵C⁷O^IVE¹⁴B⁷Z⁰X⁵L²»

[MLXZ]𝘲 class:

[MX₅L₂]

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

[Re₂(CO)₄(Cp)₂(μ₂-Se)]

Formula Unicode styled:

[Re₂(CO)₄(Cp)₂(μ₂-Se)]

Compound name(s):

(μ₂-selenido)-bis(η⁵-cyclopentadienyl)-tetracarbonyl-di-rhenium

Central atom:

Rhenium

Attached groups:

Se (μ₂-seleno X–X)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V³C⁷O^IIE¹⁸B⁷Z⁰X³L⁴»

[MLXZ]𝘲 class:

[MX₃L₄]

MLXZ class (ENC, equivalent neutral class):

MX₃L₄

cis–[Mo(CO)₂(NCMe)₂(Cp)]⊕

Formula Unicode styled:

cis–[Mo(CO)₂(NCMe)₂(Cp)]⊕

Compound name(s):

dicarbonyl-diactonitrile-cyclopentadienyl-molybdenum(1+)

Central atom:

Attached groups:

NCMe (acetonitrile)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V²C⁷O^IIE¹⁸B⁷Z⁰X¹L⁶»^⊕

[MLXZ]𝘲 class:

[MX₁L₆]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₅

[Mo(N₃)(NO)(η³-C₃H₄Me)(Cp)]

Formula Unicode styled:

[Mo(N₃)(NO)(η³-C₃H₄Me)(Cp)]

Compound name(s):

azido-nitrosyl-methallyl-(η⁵-cyclopentadienyl)-molybdenum

Central atom:

Attached groups:

N₃ (azido)

NO (nitrosyl, linear)

C₃H₄Me (η³-methylallyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 6

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V⁶C⁷O^IIE¹⁸B⁹X⁴L⁴Z¹»

[MLXZ]𝘲 class:

[MX₄L₄Z₁]

MLXZ class (ENC, equivalent neutral class):

MX₆L₃

[Mo(NCO)(NO)(η³-C₃H₄Me)(Cp)]

Formula Unicode styled:

[Mo(NCO)(NO)(η³-C₃H₄Me)(Cp)]

Compound name(s):

isocyanato-nitrosyl-methallyl-(η⁵-cyclopentadienyl)-molybdenum

Central atom:

Attached groups:

NCO (isocyanato-κN)

NO (nitrosyl, linear)

C₃H₄Me (η³-methylallyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 6

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V⁶C⁷O^IIE¹⁸B⁹X⁴L⁴Z¹»

[MLXZ]𝘲 class:

[MX₄L₄Z₁]

MLXZ class (ENC, equivalent neutral class):

MX₆L₃

cis–[Mo(CO)₂(Tht)₂(Cp)]⊕

Formula Unicode styled:

cis–[Mo(CO)₂(Tht)₂(Cp)]⊕

Compound name(s):

dicarbonyl-bis(tetrahydrothiophene)-cyclopentadienyl-molybdenum(1+)

Central atom:

Attached groups:

Tht (tetrahydrothiophene)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V²C⁷O^IIE¹⁸B⁷Z⁰X¹L⁶»^⊕

[MLXZ]𝘲 class:

[MX₁L₆]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₅

[W(CO)₃(NCMe)(Cp)]⊕

Formula Unicode styled:

[W(CO)₃(NCMe)(Cp)]⊕

Compound name(s):

acetonitrile-tricarbonyl-(η⁵-cyclopentadienyl)-tungsten(1+)

Central atom:

Tungsten

Attached groups:

NCMe (acetonitrile)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V²C⁷O^IIE¹⁸B⁷Z⁰X¹L⁶»^⊕

[MLXZ]𝘲 class:

[MX₁L₆]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₅

[Mo(=CF₂)(CO)₃(Cp*)]⊕

Formula Unicode styled:

[Mo(=CF₂)(CO)₃(Cp*)]⊕

Compound name(s):

Difluorocarbene-tricarbonyl-(η⁵-pentamethylcyclopentadienyl)-molybdenum

Central atom:

=CF₂ (difluoromethylidene)

Attached groups:

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

C₅(SiMe₃)Me₄ (η⁵-tetramethyl-trimethylsilyl-cyclopentadienyl)

Summary of calculated classifications:

Mo«V⁴C⁷O^IVE¹⁸B⁸Z⁰X³L⁵»^⊕

[MLXZ]𝘲 class:

[MX₃L₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Lu(C≡CPh)₂{η⁵-C₅(SiMe₃)Me₄}]₃

Formula Unicode styled:

[Lu(C≡CPh)₂{η⁵-C₅(SiMe₃)Me₄}]₃

Compound name(s):

pentakis(μ-2-phenylethyn-1-yl)-tris(1-trimethylsilyl-2,3,4,5-tetramethylcyclopentadienyl)-tri-lutetium

Central atom:

Lutetium

Attached groups:

C≡CPh (phenylethynyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 14

Summary of calculated classifications:

Lu«V³C⁷O^IIIE¹⁴B⁷Z⁰X³L⁴»

[MLXZ]𝘲 class:

[MX₃L₄]

MLXZ class (ENC, equivalent neutral class):

MX₃L₄

[V(H)(CO)₃(Cp)]⊖

Formula Unicode styled:

[V(H)(CO)₃(Cp)]⊖

Compound name(s):

tris(carbonyl)-hydrido-(η⁵-cyclopentadienyl)-vanadium(1-)

Central atom:

Hydrogen

Attached groups:

V group (X type)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 1

Oxidation Number (ON) (Roman numerals):

ON: (-I)

Coordination Number (CN, sum of attached group denticities):

CN: 1

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 2

Summary of calculated classifications:

H«V¹C¹O^-IE²B¹Z⁰L⁰X¹»

[MLXZ]𝘲 class:

[MX₁]

MLXZ class (ENC, equivalent neutral class):

MX₁

[V(H)(CO)₃(Cp)]⊖

Formula Unicode styled:

[V(H)(CO)₃(Cp)]⊖

Compound name(s):

tris(carbonyl)-hydrido-(η⁵-cyclopentadienyl)-vanadium(1-)

Central atom:

Vanadium

Attached groups:

H (hydrido)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 1

Oxidation Number (ON) (Roman numerals):

ON: (I)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

V«V¹C⁷O^IE¹⁸B⁷Z⁰X²L⁵»^⊖

[MLXZ]𝘲 class:

[MX₂L₅]^-

MLXZ class (ENC, equivalent neutral class):

MX₁L₆

[Eu(C≡CPh)(Thf)₂(Cp)]₂

Formula Unicode styled:

[Eu(C≡CPh)(Thf)₂(Cp)]₂

Compound name(s):

bis-[(μ₂-phenylacetylide)-(η⁵-pentamethyl-cyclopentadienyl)-bis(tetrahydrofuran)-europium]

Central atom:

Europium

Attached groups:

C≡CPh (phenylethynyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

CH₂SiMe₃ (trimethylsilylmethyl)

Coordination Number (CN, sum of attached group denticities):

CN: 6

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 19

Summary of calculated classifications:

Eu«V²C⁶O^IIE¹⁹B⁶Z⁰X²L⁴»

[MLXZ]𝘲 class:

[MX₂L₄]

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

[Dy(CH₂SiMe₃)(Thf)(μ₂-H){η⁵-C₅(SiMe₃)Me₄}]₂

Formula Unicode styled:

[Dy(CH₂SiMe₃)(Thf)(μ₂-H){η⁵-C₅(SiMe₃)Me₄}]₂

Compound name(s):

bis-[(μ₂-hydrido)-(trimethylsilylmethyl)-(tetrahydrofuran)-(η⁵-1,2,3,4-tetramethyl-5-trimethylsilyl-cyclopentadienyl)-dysprosium]

Central atom:

Dysprosium

Attached groups:

C₅(SiMe₃)Me₄ (η⁵-tetramethyl-trimethylsilyl-cyclopentadienyl)

H (μ₂-hydrido)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 23

Summary of calculated classifications:

Dy«V³C⁷O^IIIE²³B⁷Z⁰X³L⁴»

[MLXZ]𝘲 class:

[MX₃L₄]

MLXZ class (ENC, equivalent neutral class):

MX₃L₄

[Ho(μ₂-Me)₂(Cp*)]₃

Formula Unicode styled:

[Ho(μ₂-Me)₂(Cp*)]₃

Compound name(s):

tris-[di(μ-methyl)-(pentamethyl-cyclopentadienyl)-holmium]

Central atom:

Holmium

Attached groups:

Me (μ₂-methyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

C₅HPrⁱ₄ (η⁵-tetraisopropylcyclopentadienyl)

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 24

Summary of calculated classifications:

Ho«V³C⁷O^IIIE²⁴B⁷Z⁰X³L⁴»

[MLXZ]𝘲 class:

[MX₃L₄]

MLXZ class (ENC, equivalent neutral class):

MX₃L₄

[Tm(Cl)₂(Dme)(η⁵-C₅HPrⁱ₄)]

Formula Unicode styled:

[Tm(Cl)₂(Dme)(η⁵-C₅HPrⁱ₄)]

Compound name(s):

dichloro-(η⁵-tetraisopropylcyclopentadienyl)-(1,2-dimethoxyethane)-thulium

Central atom:

Thulium

Attached groups:

Cl (chloro)

Dme (dimethoxyethane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 26

Summary of calculated classifications:

Tm«V³C⁷O^IIIE²⁶B⁷Z⁰X³L⁴»

[MLXZ]𝘲 class:

[MX₃L₄]

MLXZ class (ENC, equivalent neutral class):

MX₃L₄

[Tb(μ₂-Me)₂(Cp*)]₃

Formula Unicode styled:

[Tb(μ₂-Me)₂(Cp*)]₃

Compound name(s):

tris-[di(μ-methyl)-(pentamethyl-cyclopentadienyl)-terbium]

Central atom:

Terbium

Attached groups:

Me (μ₂-methyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 22

Summary of calculated classifications:

Tb«V³C⁷O^IIIE²²B⁷Z⁰X³L⁴»

[MLXZ]𝘲 class:

[MX₃L₄]

MLXZ class (ENC, equivalent neutral class):

MX₃L₄

cis–[Yb(μ₂-F)(Thf)₂(η⁵-C₅HPh₄)]₂

Formula Unicode styled:

cis–[Yb(μ₂-F)(Thf)₂(η⁵-C₅HPh₄)]₂

Compound name(s):

bis-[(mu-fluoro)-(η⁵-tetraphenylcyclopentadienyl)-di(tetrahydrofuran)-ytterbium]

Central atom:

Ytterbium

Attached groups:

F (μ₂-fluoro)

C₅HPh₄ (η⁵-tetraphenylcyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 28

Summary of calculated classifications:

Yb«V²C⁷O^IIE²⁸B⁷Z⁰X²L⁵»

[MLXZ]𝘲 class:

[MX₂L₅]

MLXZ class (ENC, equivalent neutral class):

MX₂L₅

cis–[Yb(μ₂-Br)(Thf)₂(η⁵-C₅HPh₄)]₂

Formula Unicode styled:

cis–[Yb(μ₂-Br)(Thf)₂(η⁵-C₅HPh₄)]₂

Compound name(s):

bis-[(mu-bromo)-(η⁵-tetraphenylcyclopentadienyl)-di(tetrahydrofuran)-ytterbium]

Central atom:

Ytterbium

Attached groups:

Br (μ₂-bromo)

C₅HPh₄ (η⁵-tetraphenylcyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 28

Summary of calculated classifications:

Yb«V²C⁷O^IIE²⁸B⁷Z⁰X²L⁵»

[MLXZ]𝘲 class:

[MX₂L₅]

MLXZ class (ENC, equivalent neutral class):

MX₂L₅

[Sc(Ind)(Oep)]

Formula Unicode styled:

[Sc(Ind)(Oep)]

Compound name(s):

(η⁵-indenyl)-(octaethylporphyrin)-scandium

Central atom:

Scandium

Attached groups:

Ind (η⁵-indenyl)

Oep (octaethylporphyrin)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):