7-coordinate: pentagonal bipyramid (PBPY-7)

Dppe (1,2-bis-(diphenylphosphino)ethane-κ²P)

CO (carbonyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 1

Oxidation Number (ON) (Roman numerals):

ON: (I)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 18

Summary of calculated classifications:

V«V¹C⁷O^IE¹⁸B⁷Z⁰X¹L⁶»

[MLXZ]𝘲 class:

[MX₁L₆]

MLXZ class (ENC, equivalent neutral class):

MX₁L₆

[Ta(Cl)₂(H)(OC₆H₃Ph₂-2,6)₂(PMe₂Ph)₂]

Formula Unicode styled:

[Ta(Cl)₂(H)(OC₆H₃Ph₂-2,6)₂(PMe₂Ph)₂]

Compound name(s):

hydrido-dichloro-bis(2,6-di-isopropylphenoxy)-bis(dimethylphenylphosphane)-tantalum

Central atom:

Tantalum

Attached groups:

OC₆H₃Ph₂-2,6 (diphenylphenoxy-2,6)

PMe₂Ph (dimethylphenylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (V)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ta«V⁵C⁷O^VE¹⁴B⁷Z⁰X⁵L²»

[MLXZ]𝘲 class:

[MX₅L₂]

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

[Ta(Cl)(H)₂(OC₆H₃Ph₂-2,6)₂(PMe₂Ph)₂]

Formula Unicode styled:

[Ta(Cl)(H)₂(OC₆H₃Ph₂-2,6)₂(PMe₂Ph)₂]

Compound name(s):

dihydrido-chloro-bis(2,6-di-isopropylphenoxy)-bis(dimethylphenylphosphane)-tantalum

Central atom:

Tantalum

Attached groups:

OC₆H₃Ph₂-2,6 (diphenylphenoxy-2,6)

PMe₂Ph (dimethylphenylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (V)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ta«V⁵C⁷O^VE¹⁴B⁷Z⁰X⁵L²»

[MLXZ]𝘲 class:

[MX₅L₂]

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

[Ta(H)(PPh₂)₂(Dmpe)₂]

Formula Unicode styled:

[Ta(H)(PPh₂)₂(Dmpe)₂]

Compound name(s):

hydrido-bis-(diphenylphosphido)-bis{1,2-bis(dimethylphosphino)ethane}-tantalum

Central atom:

Tantalum

Attached groups:

PPh₂ (diphenylphosphanyl)

Dmpe (1,2-bis-(dimethylphosphino)ethane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Dedtc (diethyldithiocarbamato-κ²S)

Summary of calculated classifications:

Ta«V³C⁷O^IIIE¹⁶B⁷Z⁰X³L⁴»

[MLXZ]𝘲 class:

[MX₃L₄]

MLXZ class (ENC, equivalent neutral class):

MX₃L₄

[W(S₂)(S)(Dedtc)₂]

Formula Unicode styled:

[W(S₂)(S)(Dedtc)₂]

Compound name(s):

sulfido-(disulfur)-bis(diethylcarbamodithioato)-tungsten

Central atom:

Tungsten

Attached groups:

S₂ (disulfanediyl-κ²S)

S (thio; ⭀S)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 6

Oxidation Number (ON) (Roman numerals):

ON: (VI)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 18

Summary of calculated classifications:

W«V⁶C⁷O^VIE¹⁸B⁹Z⁰X⁶L³»

[MLXZ]𝘲 class:

[MX₆L₃]

MLXZ class (ENC, equivalent neutral class):

MX₆L₃

[Bi(Br)₃(OHMe)(Terpy-κ³N)]

Formula Unicode styled:

[Bi(Br)₃(OHMe)(Terpy-κ³N)]

Compound name(s):

tribromo-(methanol)-(terpyridine)-bismuth

Central atom:

Attached groups:

OHMe (methanol)

Terpy (terpyridine-κ³N)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Bi«V³C⁷O^IIIE¹⁶B⁷Z⁰X³L⁴»

[MLXZ]𝘲 class:

[MX₃L₄]

MLXZ class (ENC, equivalent neutral class):

MX₃L₄

[Bi(Cl)₂(Dedtc)(Py)₃]

Formula Unicode styled:

[Bi(Cl)₂(Dedtc)(Py)₃]

Compound name(s):

di-chloro-(N,N-diethyldithiocarbamato)-tris(pyridine)-bismuth

Central atom:

Attached groups:

Dedtc (diethyldithiocarbamato-κ²S)

Py (pyridine)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Bi«V³C⁷O^IIIE¹⁶B⁷Z⁰X³L⁴»

[MLXZ]𝘲 class:

[MX₃L₄]

MLXZ class (ENC, equivalent neutral class):

MX₃L₄

[Bi(I)₂(Dedtc)(Py)₃]

Formula Unicode styled:

[Bi(I)₂(Dedtc)(Py)₃]

Compound name(s):

di-iodo-(N,N-diethyldithiocarbamato)-tris(pyridine)-bismuth

Central atom:

Dedtc (diethyldithiocarbamato-κ²S)

Attached groups:

I (iodo)

Py (pyridine)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Bi«V³C⁷O^IIIE¹⁶B⁷Z⁰X³L⁴»

[MLXZ]𝘲 class:

[MX₃L₄]

MLXZ class (ENC, equivalent neutral class):

MX₃L₄

[Bi(Br)₃{S(Me)CH₂CH₂SMe}₂]

Formula Unicode styled:

[Bi(Br)₃{S(Me)CH₂CH₂SMe}₂]

Compound name(s):

tribromo-bis(1,3-bis(methylsulfanyl)ethane)-bismuth

Central atom:

Attached groups:

S(Me)CH₂CH₂SMe (2,5-dithiahexane-κ²S)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Bi«V³C⁷O^IIIE¹⁶B⁷Z⁰X³L⁴»

[MLXZ]𝘲 class:

[MX₃L₄]

MLXZ class (ENC, equivalent neutral class):

MX₃L₄

[Re(Br)₂(μ₂-I)(PPh₃)]₃

Formula Unicode styled:

[Re(Br)₂(μ₂-I)(PPh₃)]₃

Compound name(s):

tris(μ-iodo)-tris(triphenylphosphine)-hexabromo-tri-rhenium

Central atom:

Rhenium

Attached groups:

PPh₃ (triphenylphosphane)

I (μ₂-iodo)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V⁵C⁶O^IIIE¹⁶B⁷Z⁰X⁵L²»

[MLXZ]𝘲 class:

[MX₅L₂]

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

[Re(Br)₂(μ₂-I)(OH₂)]₃

Formula Unicode styled:

[Re(Br)₂(μ₂-I)(OH₂)]₃

Compound name(s):

tris(μ-iodo)-hexabromo-triaqua-tri-rhenium

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V⁵C⁶O^IIIE¹⁶B⁷Z⁰X⁵L²»

[MLXZ]𝘲 class:

[MX₅L₂]

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

[Re(Br)₂(μ₂-I)(AsPh₃)]₃

Formula Unicode styled:

[Re(Br)₂(μ₂-I)(AsPh₃)]₃

Compound name(s):

tris(μ-iodo)-tris(triphenylarsine)-hexabromo-tri-rhenium

Central atom:

Rhenium

Attached groups:

I (μ₂-iodo)

AsPh₃ (triphenylarsane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V⁵C⁶O^IIIE¹⁶B⁷Z⁰X⁵L²»

[MLXZ]𝘲 class:

[MX₅L₂]

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

[Re(Br)₂(μ₂-I)(SbPh₃)]₃

Formula Unicode styled:

[Re(Br)₂(μ₂-I)(SbPh₃)]₃

Compound name(s):

tris(μ-iodo)-tris(triphenylstibine)-hexabromo-tri-rhenium

Central atom:

Rhenium

Attached groups:

I (μ₂-iodo)

SbPh₃ (triphenylstibane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

15-crown-5 (15-crown-5-κ⁵O)

Summary of calculated classifications:

Re«V⁵C⁶O^IIIE¹⁶B⁷Z⁰X⁵L²»

[MLXZ]𝘲 class:

[MX₅L₂]

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

trans–[Mg(NCMe)₂(15-crown-5-κ⁵O)]²⊕

Formula Unicode styled:

trans–[Mg(NCMe)₂(15-crown-5-κ⁵O)]²⊕

Compound name(s):

bis(acetonitrile)-(15-crown-5)-magnesium(2+)

Central atom:

Magnesium

Attached groups:

NCMe (acetonitrile)

Charge on central atom:

2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (II)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

15-crown-5 (15-crown-5-κ⁵O)

Summary of calculated classifications:

Mg«V²C⁷O^IIE¹⁴B⁷Z⁰X⁰L⁷»^2⊕

[MLXZ]𝘲 class:

[ML₇]²⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₅

trans–[Mg(NCS-κN)₂(15-crown-5-κ⁵O)]

Formula Unicode styled:

trans–[Mg(NCS-κN)₂(15-crown-5-κ⁵O)]

Compound name(s):

(1,4,7,10,13-Pentaoxacyclopentadecane)-bis(isothiocyanato)-magnesium

Central atom:

Magnesium

Attached groups:

NCS (isothiocyanato-κN)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (II)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mg«V²C⁷O^IIE¹⁴B⁷Z⁰X²L⁵»

[MLXZ]𝘲 class:

[MX₂L₅]

MLXZ class (ENC, equivalent neutral class):

MX₂L₅

catena–2D-trans–[U{(O)₂}(OHMe)(μ₂-Cl)₂]

Formula Unicode styled:

catena–2D-trans–[U{(O)₂}(OHMe)(μ₂-Cl)₂]

Compound name(s):

catena-[bis(μ-chloro)-(methanol)-dioxo-uranium]

Central atom:

(O)₂ (di{oxo ⭀O X₂L} trans Ⓢ)

Attached groups:

OHMe (methanol)

Cl (μ₂-chloro)

Charge on central atom:

0

Compound type:

Catena-2D

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 6

Oxidation Number (ON) (Roman numerals):

ON: (VI)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 22

Summary of calculated classifications:

U«V⁶C⁷O^VIE²²B¹¹Z⁰X⁶L⁵»

[MLXZ]𝘲 class:

[MX₆L₅]

MLXZ class (ENC, equivalent neutral class):

MX₆L₅

[U(I)₄{O=CMe(OEt)}₃]

Formula Unicode styled:

[U(I)₄{O=CMe(OEt)}₃]

Compound name(s):

tris(ethyl acetate)-tetrakis(iodo)-uranium

Central atom:

O=CMe(OEt) (ethyl ethanoate-κO)

Attached groups:

I (iodo)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

U«V⁴C⁷O^IVE¹⁶B⁷Z⁰X⁴L³»

[MLXZ]𝘲 class:

[MX₄L₃]

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

[U{(O)₂}(OHEt)(S₂PPh₂)₂]

Formula Unicode styled:

[U{(O)₂}(OHEt)(S₂PPh₂)₂]

Compound name(s):

bis(diphenylphosphinodithioato)-(ethanol)-bis(oxido)-uranium

Central atom:

(O)₂ (di{oxo ⭀O X₂L} trans Ⓢ)

Attached groups:

OHEt (ethanol)

S₂PPh₂ (dithiodiphenylphosphinato)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 6

Oxidation Number (ON) (Roman numerals):

ON: (VI)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 22

Summary of calculated classifications:

U«V⁶C⁷O^VIE²²B¹¹Z⁰X⁶L⁵»

[MLXZ]𝘲 class:

[MX₆L₅]

MLXZ class (ENC, equivalent neutral class):

MX₆L₅

mer–[U(Cl)₃{O=CMe(OEt)}₄]⊕

Formula Unicode styled:

mer–[U(Cl)₃{O=CMe(OEt)}₄]⊕

Compound name(s):

trichloro-tetrakis(ethyl acetate)-uranium(1+)

Central atom:

Attached groups:

O=CMe(OEt) (ethyl ethanoate-κO)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

U«V⁴C⁷O^IVE¹⁶B⁷Z⁰X³L⁴»^⊕

[MLXZ]𝘲 class:

[MX₃L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

mer–[U(Br)₃{O=CMe(OEt)}₄]⊕

Formula Unicode styled:

mer–[U(Br)₃{O=CMe(OEt)}₄]⊕

Compound name(s):

tribromo-tetrakis(ethyl acetate)-uranium(1+)

Central atom:

Attached groups:

O=CMe(OEt) (ethyl ethanoate-κO)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: