Chemicals

Central atom: Zirconium
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
[Zr(H)(η⁴-C₄H₆)(Dppe-κ²P)(Cp*)] Zirconium VN: 2 CN: 8 ON: (II) EN: 18 H (hydrido), C₄H₆ (η⁴-butadiene), Dppe (1,2-bis-(diphenylphosphino)ethane-κ²P), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular

[Zr(H)(η⁴-C₄H₆)(Dppe-κ²P)(Cp*)]
[Zr(H)(μ₂-H)(η⁵-C₅H₄Buᵗ)₂]₂ Zirconium VN: 4 CN: 9 ON: (IV) EN: 18 H (hydrido), H (μ₂-hydrido), C₅H₄Buᵗ (η⁵-t-butyl-cyclopentadienyl) Oligomer 9-coordinate: ③₂-●-3 bent metallocene

[Zr(H)(μ₂-H)(η⁵-C₅H₄Buᵗ)₂]₂
[Zr(H)(μ₂-H)(η⁵-C₅H₄Me)₂]₂ Zirconium VN: 4 CN: 9 ON: (IV) EN: 18 H (hydrido), H (μ₂-hydrido), C₅H₄Me (η⁵-methylcyclopentadienyl) Oligomer 9-coordinate: ③₂-●-3 bent metallocene

[Zr(H)(μ₂-H)(η⁵-C₅H₄Me)₂]₂
[Zr(H)₂(Cp*)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 H (hydrido), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(H)₂(Cp*)₂]
[Zr(Hfa)₃(Cp)] Zirconium VN: 4 CN: 9 ON: (IV) EN: 18 Hfa (hexafluoroacetylacetonato), Cp (η⁵-cyclopentadienyl) Molecular

[Zr(Hfa)₃(Cp)]
[Zr(Hfa)₄] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 Hfa (hexafluoroacetylacetonato) Molecular 8-coordinate: trigonal prism, square-face bicapped (TPRS-8)

[Zr(Hfa)₄]
[Zr(I)(NMe₂)₂(μ₂-NMe₂)]₂ Zirconium VN: 4 CN: 5 ON: (IV) EN: 14 I (iodo), NMe₂ (dimethylamino: planar), NMe₂ (μ₂-dimethylamino) Oligomer 5-coordinate: trigonal bipyramid (TBPY-5)

[Zr(I)(NMe₂)₂(μ₂-NMe₂)]₂
[Zr(I)(PMe₃)₂(η⁷-C₇H₇)] Zirconium VN: 4 CN: 7 ON: (IV) EN: 16 I (iodo), PMe₃ (trimethylphosphane), C₇H₇ (η⁷-cycloheptatrienyl X₃L₂) Molecular 7-coordinate (geometry not specified)

[Zr(I)(PMe₃)₂(η⁷-C₇H₇)]
[Zr(I)(Thf)₂(η⁷-C₇H₇)] Zirconium VN: 4 CN: 7 ON: (IV) EN: 16 I (iodo), Thf (tetrahydrofuran), C₇H₇ (η⁷-cycloheptatrienyl X₃L₂) Molecular 6-coordinate (geometry not specified)

[Zr(I)(Thf)₂(η⁷-C₇H₇)]
[Zr(I)(μ₂-I)(NEt₂)₂]₂ Zirconium VN: 4 CN: 5 ON: (IV) EN: 14 I (iodo), I (μ₂-iodo), NEt₂ (diethylamino: planar) Oligomer 5-coordinate: trigonal bipyramid (TBPY-5)

[Zr(I)(μ₂-I)(NEt₂)₂]₂
[Zr(I)₂(Cp)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 I (iodo), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(I)₂(Cp)₂]
[Zr(I)₂(Cp*)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 I (iodo), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(I)₂(Cp*)₂]
[Zr(I)₂(μ₂-I)(PMe₂Ph)₂]₂ Zirconium VN: 4 CN: 7 ON: (III) EN: 14 I (iodo), I (μ₂-iodo), PMe₂Ph (dimethylphenylphosphane) Oligomer 7-coordinate: edge-capped octahedral

[Zr(I)₂(μ₂-I)(PMe₂Ph)₂]₂
[Zr(I)₂(μ₂-I)(PMe₃)₂]₂ Zirconium VN: 4 CN: 7 ON: (III) EN: 14 I (iodo), I (μ₂-iodo), PMe₃ (trimethylphosphane) Oligomer 7-coordinate: edge-capped octahedral

[Zr(I)₂(μ₂-I)(PMe₃)₂]₂
catena–1D-[Zr(I)₂(μ₂-I)₂] Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 I (iodo), I (μ₂-iodo) Catena-1D 6-coordinate: octahedron (OC-6)

catena–1D-[Zr(I)₂(μ₂-I)₂]
[Zr(I)₂{η⁵-C₅H₃(Buᵗ)₂}₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 I (iodo), C₅H₃(Buᵗ)₂ (η⁵-bis(t-butyl)cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(I)₂{η⁵-C₅H₃(Buᵗ)₂}₂]
[Zr(I)₄(Diars-κ²As)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 I (iodo), Diars (1,2-bis-(dimethylarsino)benzene-κ²As) Molecular 8-coordinate: trigonal prism, square-face bicapped (TPRS-8)

[Zr(I)₄(Diars-κ²As)₂]
trans–[Zr(I)₄(PMe₂Ph)₂] Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 I (iodo), PMe₂Ph (dimethylphenylphosphane) Molecular 6-coordinate: octahedron (OC-6)

trans–[Zr(I)₄(PMe₂Ph)₂]
[Zr(I)₄(PMe₃)₃] Zirconium VN: 4 CN: 7 ON: (IV) EN: 14 I (iodo), PMe₃ (trimethylphosphane) Molecular 7-coordinate: octahedron, face monocapped (OCF-7)

[Zr(I)₄(PMe₃)₃]
[Zr(I)₆]²⊖ Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 I (iodo) Molecular 6-coordinate: octahedron (OC-6)

[Zr(I)₆]²⊖