Chemicals

Central atom: Zirconium
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
catena–1D-[Zr(I)₂(μ₂-I)₂] Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 I (iodo), I (μ₂-iodo) Catena-1D 6-coordinate: octahedron (OC-6)

catena–1D-[Zr(I)₂(μ₂-I)₂]
[Zr(I)₂{η⁵-C₅H₃(Buᵗ)₂}₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 I (iodo), C₅H₃(Buᵗ)₂ (η⁵-bis(t-butyl)cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(I)₂{η⁵-C₅H₃(Buᵗ)₂}₂]
[Zr(I)₄(Diars-κ²As)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 I (iodo), Diars (1,2-bis-(dimethylarsino)benzene-κ²As) Molecular 8-coordinate: trigonal prism, square-face bicapped (TPRS-8)

[Zr(I)₄(Diars-κ²As)₂]
trans–[Zr(I)₄(PMe₂Ph)₂] Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 I (iodo), PMe₂Ph (dimethylphenylphosphane) Molecular 6-coordinate: octahedron (OC-6)

trans–[Zr(I)₄(PMe₂Ph)₂]
[Zr(I)₄(PMe₃)₃] Zirconium VN: 4 CN: 7 ON: (IV) EN: 14 I (iodo), PMe₃ (trimethylphosphane) Molecular 7-coordinate: octahedron, face monocapped (OCF-7)

[Zr(I)₄(PMe₃)₃]
[Zr(I)₆]²⊖ Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 I (iodo) Molecular 6-coordinate: octahedron (OC-6)

[Zr(I)₆]²⊖
[Zr(I){η⁵-C₅H₃(Buᵗ)₂}₂] Zirconium VN: 3 CN: 7 ON: (III) EN: 15 I (iodo), C₅H₃(Buᵗ)₂ (η⁵-bis(t-butyl)cyclopentadienyl) Molecular 7-coordinate: ③₂-●-1 bent metallocene

[Zr(I){η⁵-C₅H₃(Buᵗ)₂}₂]
[Zr(Me)(Cp*)₂]⊕ Zirconium VN: 4 CN: 7 ON: (IV) EN: 14 Me (methyl), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 7-coordinate: ③₂-●-1 bent metallocene

[Zr(Me)(Cp*)₂]⊕
[Zr(Me)(Cp₃)] Zirconium VN: 4 CN: 10 ON: (IV) EN: 18 Me (methyl), (Cp₃) (tris-(η⁵-cyclopentadienyl) Ⓢ) Molecular 10-coordinate: ③₃-●-1 bent metallocene

[Zr(Me)(Cp₃)]
[Zr(Me)(NCy₂)₃] Zirconium VN: 4 CN: 4 ON: (IV) EN: 14 Me (methyl), NCy₂ (dicyclohexylamino: planar) Molecular 4-coordinate: tetrahedron (T-4)

[Zr(Me)(NCy₂)₃]
[Zr(Me)(NEt₂)(Cp*)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 18 Me (methyl), NEt₂ (diethylamino: planar), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(Me)(NEt₂)(Cp*)₂]
[Zr(Me)(NPh₂)(Cp)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 18 Me (methyl), NPh₂ (diphenylamino: planar), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(Me)(NPh₂)(Cp)₂]
[Zr(Me)(OH)(Cp*)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 Me (methyl), OH (hydroxo), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(Me)(OH)(Cp*)₂]
[Zr(Me)(OMes)(Cp*)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 Me (methyl), OMes (mesityloxy), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(Me)(OMes)(Cp*)₂]
[Zr(Me)(Thf)(Cp)₂]⊕ Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 Me (methyl), Thf (tetrahydrofuran), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(Me)(Thf)(Cp)₂]⊕
[Zr(Me)(Tht)(Cp*)₂]⊕ Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 Me (methyl), Tht (tetrahydrothiophene), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(Me)(Tht)(Cp*)₂]⊕
[Zr(Me)(η⁵-C₅H₄Me)(η⁸-C₈Me₆)] Zirconium VN: 4 CN: 8 ON: (IV) EN: 18 Me (methyl), C₅H₄Me (η⁵-methylcyclopentadienyl), C₈Me₆ (η⁸-hexamethylpentalene) Molecular 8-coordinate (geometry not specified)

[Zr(Me)(η⁵-C₅H₄Me)(η⁸-C₈Me₆)]
[Zr(Me)₂(Cp)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 Me (methyl), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(Me)₂(Cp)₂]
cis–[Zr(Me)₂(Oep)] Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 Me (methyl), Oep (octaethylporphyrin) Molecular 6-coordinate: trigonal prism (TPR-6)

cis–[Zr(Me)₂(Oep)]
cis,cis,trans–[Zr(Me)₂(OSiPh₃)₂(Bpy)] Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 Me (methyl), OSiPh₃ (triphenylsiloxy), Bpy (bipyridine) Molecular 6-coordinate: octahedron (OC-6)

cis,cis,trans–[Zr(Me)₂(OSiPh₃)₂(Bpy)]