Chemicals

Central atom: Zirconium
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
[Zr(F)(Ph)(Cp*)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 F (fluoro), Ph (phenyl), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(F)(Ph)(Cp*)₂]
[Zr(F)₂(Cp)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 F (fluoro), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(F)₂(Cp)₂]
[Zr(F)₂(Cp*)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 F (fluoro), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(F)₂(Cp*)₂]
[Zr(F)₂(Cp*){η⁵-C₅H₄(SiMe₃)}] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 F (fluoro), Cp* (η⁵-pentamethylcyclopentadienyl), C₅H₄(SiMe₃) (η⁵-(trimethylsilyl)cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(F)₂(Cp*){η⁵-C₅H₄(SiMe₃)}]
[Zr(F)₂{η⁵-C₅H₃(SiMe₃)₂}₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 F (fluoro), C₅H₃(SiMe₃)₂ (η⁵-bis(trimethylsilyl)cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(F)₂{η⁵-C₅H₃(SiMe₃)₂}₂]
[Zr(F)₃(μ₂-F)(Dmso-κO)₂]₂ Zirconium VN: 4 CN: 7 ON: (IV) EN: 14 F (fluoro), F (μ₂-fluoro), Dmso (dimethylsulfoxide-κO) Oligomer 7-coordinate: pentagonal bipyramid (PBPY-7)

[Zr(F)₃(μ₂-F)(Dmso-κO)₂]₂
[Zr(F)₃(μ₂-F){O=CH(NMe₂)-κO}₂]₂ Zirconium VN: 4 CN: 7 ON: (IV) EN: 14 F (fluoro), F (μ₂-fluoro), O=CH(NMe₂) (dimethylformamido-κO) Oligomer 7-coordinate: pentagonal bipyramid (PBPY-7)

[Zr(F)₃(μ₂-F){O=CH(NMe₂)-κO}₂]₂
[Zr(F)₄(Bpy)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 F (fluoro), Bpy (bipyridine) Molecular 8-coordinate: trigonal prism, square-face bicapped (TPRS-8)

[Zr(F)₄(Bpy)₂]
[Zr(F)₄(Dmso-κO)(OH₂)₂] Zirconium VN: 4 CN: 7 ON: (IV) EN: 14 F (fluoro), Dmso (dimethylsulfoxide-κO), OH₂ (aqua) Molecular 7-coordinate: pentagonal bipyramid (PBPY-7)

[Zr(F)₄(Dmso-κO)(OH₂)₂]
cis–[Zr(F)₄(OAsPh₃)₂] Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 F (fluoro), OAsPh₃ (triphenylarsane oxide) Molecular 6-coordinate: octahedron (OC-6)

cis–[Zr(F)₄(OAsPh₃)₂]
trans–[Zr(F)₄(OAsPh₃)₂] Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 F (fluoro), OAsPh₃ (triphenylarsane oxide) Molecular 6-coordinate: octahedron (OC-6)

trans–[Zr(F)₄(OAsPh₃)₂]
trans–[Zr(F)₄(OPPh₃)₂] Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 F (fluoro), OPPh₃ (triphenylphosphane oxide) Molecular 6-coordinate: octahedron (OC-6)

trans–[Zr(F)₄(OPPh₃)₂]
[Zr(F)₅(μ₂-F)]₂⁴⊖ Zirconium VN: 4 CN: 7 ON: (IV) EN: 14 F (fluoro), F (μ₂-fluoro) Oligomer 7-coordinate: pentagonal bipyramid (PBPY-7)

[Zr(F)₅(μ₂-F)]₂⁴⊖
[Zr(F)₆(μ₂-F)]₂⁶⊖ Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 F (fluoro), F (μ₂-fluoro) Oligomer 8-coordinate: square antiprism (SAPR-8)

[Zr(F)₆(μ₂-F)]₂⁶⊖
[Zr(F)₆]²⊖ Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 F (fluoro) Molecular 6-coordinate: octahedron (OC-6)

[Zr(F)₆]²⊖
[Zr(F)₇]³⊖ Zirconium VN: 4 CN: 7 ON: (IV) EN: 14 F (fluoro) Molecular 7-coordinate: trigonal prism, square-face monocapped (TPRS-7)

[Zr(F)₇]³⊖
[Zr(F)₈]⁴⊖ Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 F (fluoro) Molecular 8-coordinate: trigonal prism, square-face bicapped (TPRS-8)

[Zr(F)₈]⁴⊖
[Zr(H)(Cp*)(η⁸-Cot)] Zirconium VN: 4 CN: 8 ON: (IV) EN: 18 H (hydrido), Cp* (η⁵-pentamethylcyclopentadienyl), Cot (η⁸-cyclooctatetraene) Molecular 8-coordinate (geometry not specified)

[Zr(H)(Cp*)(η⁸-Cot)]
[Zr(H)(Cp*)₂]⊕ Zirconium VN: 4 CN: 7 ON: (IV) EN: 14 H (hydrido), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 7-coordinate: ③₂-●-1 bent metallocene

[Zr(H)(Cp*)₂]⊕
[Zr(H)(Cp₃)] Zirconium VN: 4 CN: 10 ON: (IV) EN: 18 H (hydrido), (Cp₃) (tris-(η⁵-cyclopentadienyl) Ⓢ) Molecular 10-coordinate: ③₃-●-1 bent metallocene

[Zr(H)(Cp₃)]