Chemicals

Central atom: Zirconium
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
[Zr(CO)₂(Cp)₂] Zirconium VN: 2 CN: 8 ON: (II) EN: 18 CO (carbonyl), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(CO)₂(Cp)₂]
[Zr(CO)₂(η⁵-C₅H₅Me₂)₂] Zirconium VN: 2 CN: 8 ON: (II) EN: 18 CO (carbonyl), C₅H₅Me₂ (η⁵-2,4-dimethylpentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(CO)₂(η⁵-C₅H₅Me₂)₂]
[Zr(CO)₂{η⁵-C₅H₃(Buᵗ)₂}₂] Zirconium VN: 2 CN: 8 ON: (II) EN: 18 CO (carbonyl), C₅H₃(Buᵗ)₂ (η⁵-bis(t-butyl)cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(CO)₂{η⁵-C₅H₃(Buᵗ)₂}₂]
[Zr(CO)₄(Tripod)] Zirconium VN: 0 CN: 7 ON: (O) EN: 18 CO (carbonyl), Tripod (1,1,1-tris-(dimethylphosphino)-methyl)-ethane) Molecular 7-coordinate: ③-●-4 piano stool

[Zr(CO)₄(Tripod)]
[Zr(CO)₆]²⊖ Zirconium VN: 2 CN: 6 ON: (-II) EN: 18 CO (carbonyl) Molecular 6-coordinate: octahedron (OC-6)

[Zr(CO)₆]²⊖
[Zr(CO){P(OMe)₃}(Cp)₂] Zirconium VN: 2 CN: 8 ON: (II) EN: 18 CO (carbonyl), P(OMe)₃ (trimethylphosphite), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(CO){P(OMe)₃}(Cp)₂]
[Zr(Cp)(Tpp)] Zirconium VN: 3 CN: 7 ON: (III) EN: 15 Cp (η⁵-cyclopentadienyl), Tpp (tetraphenylporphyrin) Molecular 7-coordinate: ③-●-4 piano stool

[Zr(Cp)(Tpp)]
[Zr(Cp)(η⁷-C₇H₇)] Zirconium VN: 4 CN: 7 ON: (IV) EN: 16 Cp (η⁵-cyclopentadienyl), C₇H₇ (η⁷-cycloheptatrienyl X₃L₂) Molecular 7-coordinate: ③-●-4 piano stool

[Zr(Cp)(η⁷-C₇H₇)]
[Zr(Cp*)(η⁷-C₇H₇)] Zirconium VN: 4 CN: 7 ON: (IV) EN: 16 Cp* (η⁵-pentamethylcyclopentadienyl), C₇H₇ (η⁷-cycloheptatrienyl X₃L₂) Molecular 7-coordinate: ③-●-4 piano stool

[Zr(Cp*)(η⁷-C₇H₇)]
[Zr(Cp*)(η⁸-Cot)] Zirconium VN: 3 CN: 7 ON: (III) EN: 17 Cp* (η⁵-pentamethylcyclopentadienyl), Cot (η⁸-cyclooctatetraene) Molecular 7-coordinate: ③-●-4 piano stool

[Zr(Cp*)(η⁸-Cot)]
[Zr(Cp-κC)(Cp)(η⁸-C₈Me₆)] Zirconium VN: 4 CN: 8 ON: (IV) EN: 18 Cp (cyclopentadienyl-κC), Cp (η⁵-cyclopentadienyl), C₈Me₆ (η⁸-hexamethylpentalene) Molecular 8-coordinate (geometry not specified)

[Zr(Cp-κC)(Cp)(η⁸-C₈Me₆)]
[Zr(Cp₃)] Zirconium VN: 3 CN: 9 ON: (III) EN: 17 (Cp₃) (tris-(η⁵-cyclopentadienyl) Ⓢ) Molecular 9-coordinate: ③₃-●-metallocene

[Zr(Cp₃)]
[Zr(C≡CMe)₂(Cp)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 C≡CMe (propynyl), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(C≡CMe)₂(Cp)₂]
[Zr(C≡CPh)₂(Cp)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 C≡CPh (phenylethynyl), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(C≡CPh)₂(Cp)₂]
[Zr(C≡CPh)₂(Cp*)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 C≡CPh (phenylethynyl), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(C≡CPh)₂(Cp*)₂]
[Zr(Dedtc)₃(Cp)] Zirconium VN: 4 CN: 9 ON: (IV) EN: 18 Dedtc (diethyldithiocarbamato-κ²S), Cp (η⁵-cyclopentadienyl) Molecular

[Zr(Dedtc)₃(Cp)]
[Zr(Dmso-κO)₈]⁴⊕ Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 Dmso (dimethylsulfoxide-κO) Molecular 8-coordinate: trigonal prism, square-face bicapped (TPRS-8)

[Zr(Dmso-κO)₈]⁴⊕
[Zr(F)(C₆F₅)(Cp)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 F (fluoro), C₆F₅ (pentafluorophenyl), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(F)(C₆F₅)(Cp)₂]
[Zr(F)(C₆F₅)(Cp*)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 F (fluoro), C₆F₅ (pentafluorophenyl), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(F)(C₆F₅)(Cp*)₂]
[Zr(F)(H)(Cp*)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 F (fluoro), H (hydrido), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(F)(H)(Cp*)₂]