Chemicals

Central atom: Zirconium
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
[Zr(Cl)₄(μ₂-Cl)]₂²⊖ Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 Cl (chloro), Cl (μ₂-chloro) Oligomer 6-coordinate: octahedron (OC-6)

[Zr(Cl)₄(μ₂-Cl)]₂²⊖
[Zr(Cl)₄{S(Me)CH₂CH₂SMe}₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 Cl (chloro), S(Me)CH₂CH₂SMe (2,5-dithiahexane-κ²S) Molecular 8-coordinate: trigonal prism, square-face bicapped (TPRS-8)

[Zr(Cl)₄{S(Me)CH₂CH₂SMe}₂]
[Zr(Cl)₅(NCMe)]⊖ Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 Cl (chloro), NCMe (acetonitrile) Molecular 6-coordinate: octahedron (OC-6)

[Zr(Cl)₅(NCMe)]⊖
[Zr(Cl)₅(NEtH₂)]⊖ Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 Cl (chloro), NEtH₂ (ethylamine) Molecular 6-coordinate: octahedron (OC-6)

[Zr(Cl)₅(NEtH₂)]⊖
[Zr(Cl)₅(Py)]⊖ Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 Cl (chloro), Py (pyridine) Molecular 6-coordinate: octahedron (OC-6)

[Zr(Cl)₅(Py)]⊖
[Zr(Cl)₅(Thf)]⊖ Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 Cl (chloro), Thf (tetrahydrofuran) Molecular 6-coordinate: octahedron (OC-6)

[Zr(Cl)₅(Thf)]⊖
[Zr(Cl)₆]²⊖ Zirconium VN: 4 CN: 6 ON: (IV) EN: 12 Cl (chloro) Molecular 6-coordinate: octahedron (OC-6)

[Zr(Cl)₆]²⊖
[Zr(Cl){As(SiMe₃)₂}(Cp*)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 Cl (chloro), As(SiMe₃)₂ (bistrimethylsilylarsanyl), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(Cl){As(SiMe₃)₂}(Cp*)₂]
[Zr(Cl){CH(PPh₃)}(Cp)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 18 Cl (chloro), CH(PPh₃) (triphenylphosphinylidene-methyl), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(Cl){CH(PPh₃)}(Cp)₂]
[Zr(Cl){N(PPh₂)₂}(Cp)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 18 Cl (chloro), N(PPh₂)₂ (bis(diphenylphosphanyl)amino XL), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(Cl){N(PPh₂)₂}(Cp)₂]
[Zr(Cl){N(SiMe₃)₂}₃] Zirconium VN: 4 CN: 4 ON: (IV) EN: 14 Cl (chloro), N(SiMe₃)₂ (bis(trimethylsilyl)amino: planar) Molecular 4-coordinate: tetrahedron (T-4)

[Zr(Cl){N(SiMe₃)₂}₃]
[Zr(Cl){OC(Buᵗ)CHC(Buᵗ)O}₃] Zirconium VN: 4 CN: 7 ON: (IV) EN: 14 Cl (chloro), OC(Buᵗ)CHC(Buᵗ)O (tetramethylheptane-3,5-dionato) Molecular 7-coordinate: pentagonal bipyramid (PBPY-7)

[Zr(Cl){OC(Buᵗ)CHC(Buᵗ)O}₃]
[Zr(Cl){P(SiMe₃)₂}(Cp)₂] Zirconium VN: 4 CN: 8 ON: (IV) EN: 16 Cl (chloro), P(SiMe₃)₂ (bis(trimethylsilyl)phosphanyl), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate: ③₂-●-2 bent metallocene

[Zr(Cl){P(SiMe₃)₂}(Cp)₂]
[Zr(Cl){η⁵-C₅H₃(Buᵗ)₂}₂] Zirconium VN: 3 CN: 7 ON: (III) EN: 15 Cl (chloro), C₅H₃(Buᵗ)₂ (η⁵-bis(t-butyl)cyclopentadienyl) Molecular 7-coordinate: ③₂-●-1 bent metallocene

[Zr(Cl){η⁵-C₅H₃(Buᵗ)₂}₂]
[Zr(CNBuᵗ)(Cp)(η⁷-C₇H₇)] Zirconium VN: 4 CN: 8 ON: (IV) EN: 18 CNBuᵗ (t-butyl isocyanide), Cp (η⁵-cyclopentadienyl), C₇H₇ (η⁷-cycloheptatrienyl X₃L₂) Molecular 8-coordinate (geometry not specified)

[Zr(CNBuᵗ)(Cp)(η⁷-C₇H₇)]
[Zr(CNBuᵗ)(Cp₃)]⊕ Zirconium VN: 4 CN: 10 ON: (IV) EN: 18 CNBuᵗ (t-butyl isocyanide), (Cp₃) (tris-(η⁵-cyclopentadienyl) Ⓢ) Molecular 10-coordinate: ③₃-●-1 bent metallocene

[Zr(CNBuᵗ)(Cp₃)]⊕
[Zr(CNBuᵗ)(η⁴-Cot)(η⁸-Cot)] Zirconium VN: 2 CN: 7 ON: (II) EN: 18 CNBuᵗ (t-butyl isocyanide), Cot (η⁴-cyclooctatetraene), Cot (η⁸-cyclooctatetraene) Molecular 7-coordinate (geometry not specified)

[Zr(CNBuᵗ)(η⁴-Cot)(η⁸-Cot)]
[Zr(CNXy)(Cp)(η⁷-C₇H₇)] Zirconium VN: 4 CN: 8 ON: (IV) EN: 18 CNXy (xylyl isocyanide), Cp (η⁵-cyclopentadienyl), C₇H₇ (η⁷-cycloheptatrienyl X₃L₂) Molecular 8-coordinate (geometry not specified)

[Zr(CNXy)(Cp)(η⁷-C₇H₇)]
[Zr(CO)(Cp₃)]⊕ Zirconium VN: 4 CN: 10 ON: (IV) EN: 18 CO (carbonyl), (Cp₃) (tris-(η⁵-cyclopentadienyl) Ⓢ) Molecular 10-coordinate: ③₃-●-1 bent metallocene

[Zr(CO)(Cp₃)]⊕
[Zr(CO)(η⁵-C₅H₅Me₂)₂] Zirconium VN: 2 CN: 7 ON: (II) EN: 16 CO (carbonyl), C₅H₅Me₂ (η⁵-2,4-dimethylpentadienyl) Molecular 7-coordinate: ③₂-●-1 bent metallocene

[Zr(CO)(η⁵-C₅H₅Me₂)₂]