Chemicals

Central atom: Aluminium
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
[Al(Buᵗ)₃(SbPrⁱ₃)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), SbPrⁱ₃ (triisopropylstibane) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₃(SbPrⁱ₃)]
[(AlBuᵗ₃)(SbMe₂)]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), SbR₃ (stibane) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[(AlBuᵗ₃)(SbMe₂)]₂
[Al(Buᵗ)₃] Aluminium VN: 3 CN: 3 ON: (III) EN: 6 Buᵗ (t-butyl) Molecular 3-coordinate: trigonal planar (p-block element, 0 lone pairs)

[Al(Buᵗ)₃]
[Al(Buⁱ)(Cp*-κC)(μ₂-Cl)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buⁱ (isobutyl), Cp* (pentamethylcyclopentadienyl-κC), Cl (μ₂-chloro) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buⁱ)(Cp*-κC)(μ₂-Cl)]
[Al(Buⁱ)(OC₆H₃Buᵗ₂-2,6)₂] Aluminium VN: 3 CN: 3 ON: (III) EN: 6 Buⁱ (isobutyl), OC₆H₃Buᵗ₂-2,6 (di-t-butylphenoxy-2,6) Molecular 3-coordinate: trigonal planar (p-block element, 0 lone pairs)

[Al(Buⁱ)(OC₆H₃Buᵗ₂-2,6)₂]
[Al(Buⁱ)₂(F)₂]⊖ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buⁱ (isobutyl), F (fluoro) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buⁱ)₂(F)₂]⊖
[Al(Buⁱ)₂(μ₂-NEt₂)]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buⁱ (isobutyl), NEt₂ (μ₂-diethylamino) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buⁱ)₂(μ₂-NEt₂)]₂
[Al(Buⁱ)₂(μ₂-NHPh)]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buⁱ (isobutyl), NHPh (μ₂-phenylamino) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buⁱ)₂(μ₂-NHPh)]₂
[Al(Buⁱ)₂(μ₂-NMe₂)]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buⁱ (isobutyl), NMe₂ (μ₂-dimethylamino) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buⁱ)₂(μ₂-NMe₂)]₂
[Al(Buⁱ)₂(μ₂-OC₆H₃Me₂-2,6)]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buⁱ (isobutyl), OC₆H₃Me₂-2,6 (μ₂-dimethylphenoxy-2,6) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buⁱ)₂(μ₂-OC₆H₃Me₂-2,6)]₂
[Al(Buⁱ)₂(μ₂-OSiMe₃)]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buⁱ (isobutyl), OSiMe₃ (μ₂-trimethylsiloxy) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buⁱ)₂(μ₂-OSiMe₃)]₂
[Al(Buⁱ)₂(μ₂-SC₆H₂Prⁱ₃-2,4,6)]₃ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buⁱ (isobutyl), SC₆H₂Prⁱ₃-2,4,6 (μ₂-tri-i-propylphenylthio) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buⁱ)₂(μ₂-SC₆H₂Prⁱ₃-2,4,6)]₃
[Al(Buⁱ)₂{μ₂-P(SiMe₃)₂}]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buⁱ (isobutyl), P(SiMe₃)₂ (μ₂-bis(trimethylsilyl)phosphanyl) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buⁱ)₂{μ₂-P(SiMe₃)₂}]₂
[Al(Buⁿ)₂(μ₂-NBz₂)]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buⁿ (butyl), NBz₂ (μ₂-dibenzylamino) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buⁿ)₂(μ₂-NBz₂)]₂
[Al(Buⁿ)₄]⊖ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buⁿ (butyl) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buⁿ)₄]⊖
[Al(Bz)₃(OEt₂)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Bz (phenylmethanido-κC), OEt₂ (diethylether) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Bz)₃(OEt₂)]
[Al(Bz)₃] Aluminium VN: 3 CN: 3 ON: (III) EN: 6 Bz (phenylmethanido-κC) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Bz)₃]
[Al(C₃H₅)₂(μ₂-C₃H₅)]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 C₃H₅ (cyclopropyl), C₃H₅ (μ₂-cyclopropyl) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(C₃H₅)₂(μ₂-C₃H₅)]₂
[Al(C₃H₅-κC)₂(Thf)₃]⊕ Aluminium VN: 3 CN: 5 ON: (III) EN: 10 C₃H₅ (allyl-κC), Thf (tetrahydrofuran) Molecular 5-coordinate: trigonal bipyramidal (p-block element, 1 lone pair)

[Al(C₃H₅-κC)₂(Thf)₃]⊕
[Al(C₃H₅-κC)₃(OPPh₃)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 C₃H₅ (allyl-κC), OPPh₃ (triphenylphosphane oxide) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(C₃H₅-κC)₃(OPPh₃)]