5-coordinate: trigonal bipyramidal (p-block element, 1 lone pair)

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Se«V⁴C⁴O^IVE¹⁰B⁴Z⁰L⁰X⁴»

[MLXZ]𝘲 class:

[MX₄]

MLXZ class (ENC, equivalent neutral class):

MX₄

catena–1D-[Bi(Me)₂(SbF₆)]

Formula Unicode styled:

catena–1D-[Bi(Me)₂(SbF₆)]

Compound name(s):

catena-[dimethyl-(μ₂-hexafluoro-antimony)-bismuth]

Central atom:

Attached groups:

FSbF₅ (hexafluoroantimonato)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Bi«V³C⁴O^IIIE¹⁰B⁴Z⁰X²L²»^⊕

[MLXZ]𝘲 class:

[MX₂L₂]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₁

[Bi(Tol-p)₂(O₂PPh₂-κ²O)]

Formula Unicode styled:

[Bi(Tol-p)₂(O₂PPh₂-κ²O)]

Compound name(s):

catena-[bis(p-tolyl)-(μ-diphenylphosphinate)-bismuth]

Central atom:

O₂PPh₂ (diphenylphosphinate-κ²O)

Attached groups:

Tol-p (p-tolyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Bi«V³C⁴O^IIIE¹⁰B⁴Z⁰X³L¹»

[MLXZ]𝘲 class:

[MX₃L₁]

MLXZ class (ENC, equivalent neutral class):

MX₃L₁

[Bi(Me)₂(CNXy)(SbF₆)]

Formula Unicode styled:

[Bi(Me)₂(CNXy)(SbF₆)]

Compound name(s):

dimethyl-(2,6-dimethylphenyl-isocyanide)-(hexafluoroantimonate)-bismuth

Central atom:

Attached groups:

FSbF₅ (hexafluoroantimonato)

CNXy (xylyl isocyanide)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Bi«V³C⁴O^IIIE¹⁰B⁴Z⁰X²L²»^⊕

[MLXZ]𝘲 class:

[MX₂L₂]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₁

[Bi(C₆H₃Prⁱ₂)₂(OPPh₃)₂]⊕

Formula Unicode styled:

[Bi(C₆H₃Prⁱ₂)₂(OPPh₃)₂]⊕

Compound name(s):

bis(2,6-isopropyl)phenyl)-bis(triethylphosphine oxide)-bismuth(1+)

Central atom:

C₆H₃Prⁱ₂ (2,6-isopropylphenyl)

Attached groups:

OPPh₃ (triphenylphosphane oxide)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Bi«V³C⁴O^IIIE¹⁰B⁴Z⁰X²L²»^⊕

[MLXZ]𝘲 class:

[MX₂L₂]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₁

[Bi(Me)₂(Xy)₂]⊕

Formula Unicode styled:

[Bi(Me)₂(Xy)₂]⊕

Compound name(s):

dimethyl-bis(xylyl)-bismuth(1+)

Central atom:

Attached groups:

Xy (xylyl)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 5

Oxidation Number (ON) (Roman numerals):

ON: (V)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 8

Summary of calculated classifications:

Bi«V⁵C⁴O^VE⁸B⁴Z⁰L⁰X⁴»^⊕

[MLXZ]𝘲 class:

[MX₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃Z₁

[Bi(Me)₂(Py)₂]⊕

Formula Unicode styled:

[Bi(Me)₂(Py)₂]⊕

Compound name(s):

dimethyl-bis(pyridine)-bismuth(1+)

Central atom:

Attached groups:

Py (pyridine)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Bi«V³C⁴O^IIIE¹⁰B⁴Z⁰X²L²»^⊕

[MLXZ]𝘲 class:

[MX₂L₂]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₁

catena–1D-[Bi(Ph)₂(O₂PPh₂-κ²O)]

Formula Unicode styled:

catena–1D-[Bi(Ph)₂(O₂PPh₂-κ²O)]

Compound name(s):

catena-[diphenyl-(μ-diphenyl phosphinate)-bismuth]

Central atom:

O₂PPh₂ (diphenylphosphinate-κ²O)

Attached groups:

Ph (phenyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Bi«V³C⁴O^IIIE¹⁰B⁴Z⁰X³L¹»

[MLXZ]𝘲 class:

[MX₃L₁]

MLXZ class (ENC, equivalent neutral class):

MX₃L₁

catena–1D-[Bi(Me)(μ₂-SPh)₂]

Formula Unicode styled:

catena–1D-[Bi(Me)(μ₂-SPh)₂]

Compound name(s):

catena-[methyl-bis(μ₂-benzenethiolato)-bismuth]

Central atom:

Attached groups:

SPh (μ₂-phenylthio)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 12

Summary of calculated classifications:

Bi«V³C⁵O^IIIE¹²B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

catena–1D-[Bi(Bz)₂(μ₂-I)]

Formula Unicode styled:

catena–1D-[Bi(Bz)₂(μ₂-I)]

Compound name(s):

catena-[bis(benzyl)-(μ₂-iodo)-bismuth]

Central atom:

Attached groups:

Bz (phenylmethanido-κC)

I (μ₂-iodo)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Bi«V³C⁴O^IIIE¹⁰B⁴Z⁰X³L¹»

[MLXZ]𝘲 class:

[MX₃L₁]

MLXZ class (ENC, equivalent neutral class):

MX₃L₁

catena–1D-[Bi(Prⁱ)₂(μ₂-Br)]

Formula Unicode styled:

catena–1D-[Bi(Prⁱ)₂(μ₂-Br)]

Compound name(s):

catena-[bis(isopropyl)-(μ₂-bromo)-bismuth]

Central atom:

Attached groups:

Prⁱ (isopropyl)

Br (μ₂-bromo)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Bi«V³C⁴O^IIIE¹⁰B⁴Z⁰X³L¹»

[MLXZ]𝘲 class:

[MX₃L₁]

MLXZ class (ENC, equivalent neutral class):

MX₃L₁

catena–1D-[Bi(Buᵗ)₂(μ₂-CN)]

Formula Unicode styled:

catena–1D-[Bi(Buᵗ)₂(μ₂-CN)]

Compound name(s):

catena-[bis(t-butyl)-(μ₂-cyano-κC,κN)-bismuth]

Central atom:

Attached groups:

Buᵗ (t-butyl)

CN (μ₂-cyano-κC,κN)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Bi«V³C⁴O^IIIE¹⁰B⁴Z⁰X³L¹»

[MLXZ]𝘲 class:

[MX₃L₁]

MLXZ class (ENC, equivalent neutral class):

MX₃L₁

catena–1D-[Bi(Buᵗ)₂(μ₂-N₃)]

Formula Unicode styled:

catena–1D-[Bi(Buᵗ)₂(μ₂-N₃)]

Compound name(s):

catena-[bis(t-butyl)-(μ₂-azido)-bismuth]

Central atom:

Attached groups:

Buᵗ (t-butyl)

N₃ (μ₂-azido)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Bi«V³C⁴O^IIIE¹⁰B⁴Z⁰X³L¹»

[MLXZ]𝘲 class:

[MX₃L₁]

MLXZ class (ENC, equivalent neutral class):

MX₃L₁

catena–1D-[Bi(Buᵗ)₂(μ₂-Cl)]

Formula Unicode styled:

catena–1D-[Bi(Buᵗ)₂(μ₂-Cl)]

Compound name(s):

catena-[bis(t-butyl)-(μ₂-chloro)-bismuth]

Central atom:

Attached groups:

Buᵗ (t-butyl)

Cl (μ₂-chloro)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Bi«V³C⁴O^IIIE¹⁰B⁴Z⁰X³L¹»

[MLXZ]𝘲 class:

[MX₃L₁]

MLXZ class (ENC, equivalent neutral class):

MX₃L₁

catena–1D-[Bi(C₂F₅)₂(μ₂-Cl)]

Formula Unicode styled:

catena–1D-[Bi(C₂F₅)₂(μ₂-Cl)]

Compound name(s):

catena-[(μ₂-chloro)-bis(pentafluoroethyl)-bismuth]

Central atom:

Attached groups:

C₂F₅ (perfluoroethyl)

Cl (μ₂-chloro)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Bi«V³C⁴O^IIIE¹⁰B⁴Z⁰X³L¹»

[MLXZ]𝘲 class:

[MX₃L₁]

MLXZ class (ENC, equivalent neutral class):

MX₃L₁

catena–1D-[Bi(C₂F₅)₂(μ₂-Br)]

Formula Unicode styled:

catena–1D-[Bi(C₂F₅)₂(μ₂-Br)]

Compound name(s):

catena-[(μ₂-bromo)-bis(pentafluoroethyl)-bismuth]

Central atom:

Attached groups:

C₂F₅ (perfluoroethyl)

Br (μ₂-bromo)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Bi«V³C⁴O^IIIE¹⁰B⁴Z⁰X³L¹»

[MLXZ]𝘲 class:

[MX₃L₁]

MLXZ class (ENC, equivalent neutral class):

MX₃L₁

catena–3D-[Bi₂(Et)₄(μ₄-Te)]

Formula Unicode styled:

catena–3D-[Bi₂(Et)₄(μ₄-Te)]

Compound name(s):

catena-[tetraethyl-(μ₄-tellurido)-di-bismuth]

Central atom:

Attached groups:

Et (ethyl)

Te (μ₄-telluro X₂L₂)

Charge on central atom:

0

Compound type:

Catena-3D

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Bi«V³C⁴O^IIIE¹⁰B⁴Z⁰X³L¹»

[MLXZ]𝘲 class:

[MX₃L₁]

MLXZ class (ENC, equivalent neutral class):

MX₃L₁

[Bi(C₃H₅-κC)₂(Thf)₂]⊕

Formula Unicode styled:

[Bi(C₃H₅-κC)₂(Thf)₂]⊕

Compound name(s):

diallyl-bis(tetrahydrofuran)-bismuth(1+)

Central atom:

Attached groups:

C₃H₅ (allyl-κC)

Thf (tetrahydrofuran)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Bi«V³C⁴O^IIIE¹⁰B⁴Z⁰X²L²»^⊕

[MLXZ]𝘲 class:

[MX₂L₂]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₁

catena–1D-[Bi(Ph)₂(μ₂-SO₃CF₃)]

Formula Unicode styled:

catena–1D-[Bi(Ph)₂(μ₂-SO₃CF₃)]

Compound name(s):

catena-[diphenyl-(μ₂-trifluoromethanesulfonato-O,O')-bismuth]

Central atom:

OSO₂CF₃ (μ₂-trifluoromethanesulfonato-κ²O)

Attached groups:

Ph (phenyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Bi«V³C⁴O^IIIE¹⁰B⁴Z⁰X³L¹»

[MLXZ]𝘲 class:

[MX₃L₁]

MLXZ class (ENC, equivalent neutral class):

MX₃L₁

catena–1D-[Bi(Ph)₂(μ₂-O₂CCF₃)]

Formula Unicode styled:

catena–1D-[Bi(Ph)₂(μ₂-O₂CCF₃)]

Compound name(s):

catena-[diphenyl-(μ₂-trifluoroacetato)-bismuth]

Central atom:

O₂CCF₃ (μ₂-trifluoroacetato)

Attached groups:

Ph (phenyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: