Chemicals

Central atom: Aluminium
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
[Al(C₃H₅-κC)₄]⊖ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 C₃H₅ (allyl-κC) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(C₃H₅-κC)₄]⊖
[Al(C₆F₅)(Me)(μ₂-Me)]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 C₆F₅ (pentafluorophenyl), Me (methyl), Me (μ₂-methyl) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(C₆F₅)(Me)(μ₂-Me)]₂
[Al(C₆F₅)₂(η³-Cp*)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 C₆F₅ (pentafluorophenyl), Cp*-η³ (η³-pentamethylcyclopentadienyl) Molecular 4-coordinate (geometry not specified)

[Al(C₆F₅)₂(η³-Cp*)]
[Al(C₆F₅)₂(μ₂-Cl)]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 C₆F₅ (pentafluorophenyl), Cl (μ₂-chloro) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(C₆F₅)₂(μ₂-Cl)]₂
[Al(C₆F₅)₂(μ₂-O₂CC₆F₅)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 C₆F₅ (pentafluorophenyl), O₂CC₆F₅ (μ₂-pentafluorobenzoato-κ²O) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(C₆F₅)₂(μ₂-O₂CC₆F₅)]
[Al(C₆F₅)₃(AlCp*)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 C₆F₅ (pentafluorophenyl), AlCp* (pentamethylcyclopentadienylaluminium) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(C₆F₅)₃(AlCp*)]
[Al(C₆F₅)₃(Cl)]⊖ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 C₆F₅ (pentafluorophenyl), Cl (chloro) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(C₆F₅)₃(Cl)]⊖
[Al(C₆F₅)₃(C≡CBuᵗ)]⊖ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 C₆F₅ (pentafluorophenyl), C≡CBuᵗ (t-butyl-ethynyl) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(C₆F₅)₃(C≡CBuᵗ)]⊖
[Al(C₆F₅)₃(Et)]⊖ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 C₆F₅ (pentafluorophenyl), Et (ethyl) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(C₆F₅)₃(Et)]⊖
[Al(C₆F₅)₃(H)]⊖ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 C₆F₅ (pentafluorophenyl), H (hydrido) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(C₆F₅)₃(H)]⊖
[Al(C₆F₅)₃(NH₂Buᵗ)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 C₆F₅ (pentafluorophenyl), NH₂Buᵗ (t-butylamine) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(C₆F₅)₃(NH₂Buᵗ)]
[Al(C₆F₅)₃(NH₂Bz)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 C₆F₅ (pentafluorophenyl), NH₂Bz (benzylamine) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(C₆F₅)₃(NH₂Bz)]
[Al(C₆F₅)₃(NHMe₂)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 C₆F₅ (pentafluorophenyl), NHMe₂ (dimethylamine) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(C₆F₅)₃(NHMe₂)]
[Al(C₆F₅)₃(OH₂)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 C₆F₅ (pentafluorophenyl), OH₂ (aqua) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(C₆F₅)₃(OH₂)]
[Al(C₆F₅)₃(OHMe)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 C₆F₅ (pentafluorophenyl), OHMe (methanol) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(C₆F₅)₃(OHMe)]
[Al(C₆F₅)₃(Pip)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 C₆F₅ (pentafluorophenyl), Pip (piperidine) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(C₆F₅)₃(Pip)]
[Al(C₆F₅)₃(Pip)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 C₆F₅ (pentafluorophenyl), Pip (piperidine) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(C₆F₅)₃(Pip)]
[Al(C₆F₅)₃(Thf)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 C₆F₅ (pentafluorophenyl), Thf (tetrahydrofuran) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(C₆F₅)₃(Thf)]
[Al(C₆H₂Buᵗ₃)(μ₂-S)(Dmso-κO)]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 C₆H₂Buᵗ₃ (2,4,6-tri-t-butylphenyl), S (μ₂-thio X–X), Dmso (dimethylsulfoxide-κO) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(C₆H₂Buᵗ₃)(μ₂-S)(Dmso-κO)]₂
[Al(C₆H₂Buᵗ₃)(μ₂-S)]₂ Aluminium VN: 3 CN: 3 ON: (III) EN: 6 C₆H₂Buᵗ₃ (2,4,6-tri-t-butylphenyl), S (μ₂-thio X–X) Oligomer 3-coordinate: trigonal planar (p-block element, 0 lone pairs)

[Al(C₆H₂Buᵗ₃)(μ₂-S)]₂