Chemicals

Central atom: Aluminium
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
[Al(Buᵗ)₂(NMes₂)] Aluminium VN: 3 CN: 3 ON: (III) EN: 6 Buᵗ (t-butyl), NMes₂ (dimesitylamino) Molecular 3-coordinate: trigonal planar (p-block element, 0 lone pairs)

[Al(Buᵗ)₂(NMes₂)]
[Al(Buᵗ)₂(O₂CBz)]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), O₂CBz (benzyloato-κ²O) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₂(O₂CBz)]₂
[Al(Buᵗ)₂(O₂CPh-κ²O)]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), O₂CPh (benzoato-κ²O) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₂(O₂CPh-κ²O)]₂
[Al(Buᵗ)₂(OC₆H₂Buᵗ₂-2,6-Me-4)] Aluminium VN: 3 CN: 3 ON: (III) EN: 6 Buᵗ (t-butyl), OC₆H₂Buᵗ₂-2,6-Me-4 (di-t-butylmethylphenoxy) Molecular 3-coordinate: trigonal planar (p-block element, 0 lone pairs)

[Al(Buᵗ)₂(OC₆H₂Buᵗ₂-2,6-Me-4)]
[Al(Buᵗ)₂(OC₆H₂Buᵗ₃-2,4,6)] Aluminium VN: 3 CN: 3 ON: (III) EN: 6 Buᵗ (t-butyl), OC₆H₂Buᵗ₃-2,4,6 (tri-t-butylphenoxy-2,4,6) Molecular 3-coordinate: trigonal planar (p-block element, 0 lone pairs)

[Al(Buᵗ)₂(OC₆H₂Buᵗ₃-2,4,6)]
[Al(Buᵗ)₂(OTol)]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), OTol (tolyloxy) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₂(OTol)]₂
[Al(Buᵗ)₂(Ph)(Thf)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), Ph (phenyl), Thf (tetrahydrofuran) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₂(Ph)(Thf)]
[Al(Buᵗ)₂(TMEDA-κ²N)]⊕ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), TMEDA (tetramethylethylenediamine-κ²N) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₂(TMEDA-κ²N)]⊕
[Al(Buᵗ)₂(μ₂-Br)]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), Br (μ₂-bromo) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₂(μ₂-Br)]₂
[Al(Buᵗ)₂(μ₂-Cl)]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), Cl (μ₂-chloro) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₂(μ₂-Cl)]₂
[Al(Buᵗ)₂(μ₂-CN)]₄ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), CN (μ₂-cyano-κC,κN) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₂(μ₂-CN)]₄
[Al(Buᵗ)₂(μ₂-C≡CBuᵗ)]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), C≡CBuᵗ (μ₂-t-butyl-ethynyl) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₂(μ₂-C≡CBuᵗ)]₂
[Al(Buᵗ)₂(μ₂-I)]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), I (μ₂-iodo) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₂(μ₂-I)]₂
[Al(Buᵗ)₂(μ₂-NH₂)]₃ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), NH₂ (μ₂-amino) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₂(μ₂-NH₂)]₃
[Al(Buᵗ)₂(μ₂-NHBuᵗ)]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), NHBuᵗ (μ₂-t-butylamino) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₂(μ₂-NHBuᵗ)]₂
[Al(Buᵗ)₂(μ₂-O₂CBuᵗ-κ²O)]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), O₂CBuᵗ (μ₂-pivalato) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₂(μ₂-O₂CBuᵗ-κ²O)]₂
[Al(Buᵗ)₂(μ₂-OBuᵗ)]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), OBuᵗ (μ₂-t-butyloxy) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₂(μ₂-OBuᵗ)]₂
[Al(Buᵗ)₂(μ₂-OH)]₃ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), OH (μ₂-hydroxy) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₂(μ₂-OH)]₃
[Al(Buᵗ)₂(μ₂-OPh)]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), OPh (μ₂-phenoxy) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₂(μ₂-OPh)]₂
[Al(Buᵗ)₂(μ₂-OPrⁿ)]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), OPrⁿ (μ₂-n-propoxy) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₂(μ₂-OPrⁿ)]₂