Chemicals

Central atom: Aluminium
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
[Al(Br)₃(PBuᵗ₂H)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Br (bromo), PBuᵗ₂H (di-t-butylphosphane) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Br)₃(PBuᵗ₂H)]
[Al(Br)₃(PMes₃)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Br (bromo), PMes₃ (trimesitylphosphane) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Br)₃(PMes₃)]
[Al(Br)₃(Py)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Br (bromo), Py (pyridine) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Br)₃(Py)]
[Al(Br)₃(TeMe₂)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Br (bromo), TeMe₂ (dimethyltellurane) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Br)₃(TeMe₂)]
[Al(Br)₃(Thf)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Br (bromo), Thf (tetrahydrofuran) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Br)₃(Thf)]
catena–1D-[Al(Br)₃(μ₂-Diox)] Aluminium VN: 3 CN: 5 ON: (III) EN: 10 Br (bromo), Diox (μ₂-dioxane) Catena-1D 5-coordinate: trigonal bipyramidal (p-block element, 0 lone pairs)

catena–1D-[Al(Br)₃(μ₂-Diox)]
[Al(Br)₃{C(PPh₃)₂}] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Br (bromo), C(PPh₃)₂ (carbodiphosphorane) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Br)₃{C(PPh₃)₂}]
[Al(Br)₃{NH(CMe₂CH₂CH₂CH₂CMe₂)}] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Br (bromo), NH(CMe₂CH₂CH₂CH₂CMe₂) (2,2,6,6,tetramethyl-piperidine) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Br)₃{NH(CMe₂CH₂CH₂CH₂CMe₂)}]
[Al(Br)₃{P(SiMe₃)₃}] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Br (bromo), P(SiMe₃)₃ (tris-(trimethylsilyl)-phosphane) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Br)₃{P(SiMe₃)₃}]
[Al(Br)₄]⊖ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Br (bromo) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Br)₄]⊖
[Al(Br){N(CMe₂CH₂CH₂CH₂CMe₂)}₂(Py)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Br (bromo), N(CMe₂CH₂CH₂CH₂CMe₂) (2,2,6,6,tetramethyl-piperidinato), Py (pyridine) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Br){N(CMe₂CH₂CH₂CH₂CMe₂)}₂(Py)]
[Al(Br){N(CMe₂CH₂CH₂CH₂CMe₂)}₂(Thf)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Br (bromo), N(CMe₂CH₂CH₂CH₂CMe₂) (2,2,6,6,tetramethyl-piperidinato), Thf (tetrahydrofuran) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Br){N(CMe₂CH₂CH₂CH₂CMe₂)}₂(Thf)]
[Al(Br){N(CMe₂CH₂CH₂CH₂CMe₂)}₂] Aluminium VN: 3 CN: 3 ON: (III) EN: 6 Br (bromo), N(CMe₂CH₂CH₂CH₂CMe₂) (2,2,6,6,tetramethyl-piperidinato) Molecular 3-coordinate: trigonal planar (p-block element, 0 lone pairs)

[Al(Br){N(CMe₂CH₂CH₂CH₂CMe₂)}₂]
[Al(Br){Si(SiMe₃)₃}(Thf)]₂ Aluminium VN: 3 CN: 4 ON: (II) EN: 8 Br (bromo), Si(SiMe₃)₃ (tris-trimethylsilyl-silyl), Thf (tetrahydrofuran) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Br){Si(SiMe₃)₃}(Thf)]₂
[Al(Buᵗ)(SC₆H₂Mes₃-2,4,6)₂] Aluminium VN: 3 CN: 3 ON: (III) EN: 6 Buᵗ (t-butyl), SC₆H₂Mes₃-2,4,6 (tri-mesitylphenylthio) Molecular 3-coordinate: trigonal planar (p-block element, 0 lone pairs)

[Al(Buᵗ)(SC₆H₂Mes₃-2,4,6)₂]
[Al(Buᵗ)(μ₂-NSiMe₃)(Thf)]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), NSiMe₃ (μ₂-trimethylsilylimino X₂), Thf (tetrahydrofuran) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)(μ₂-NSiMe₃)(Thf)]₂
[Al(Buᵗ)(μ₃-Acac)]₂ Aluminium VN: 3 CN: 4 ON: (II) EN: 8 Buᵗ (t-butyl), Acac (μ₃-acetylacetonato) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)(μ₃-Acac)]₂
[Al(Buᵗ)(μ₃–O)]₆ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), O (μ₃–oxo X₂L) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)(μ₃–O)]₆
[Al(Buᵗ)(μ₃–O)]₈ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), O (μ₃–oxo X₂L) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)(μ₃–O)]₈
[Al(Buᵗ)₂(C₆H₂Buᵗ₃)] Aluminium VN: 3 CN: 3 ON: (III) EN: 6 Buᵗ (t-butyl), C₆H₂Buᵗ₃ (2,4,6-tri-t-butylphenyl) Molecular 3-coordinate: trigonal planar (p-block element, 0 lone pairs)

[Al(Buᵗ)₂(C₆H₂Buᵗ₃)]