Chemicals

Central atom: Aluminium
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
[Al(Buᵗ)₂(μ₂-OSiMe₃)]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), OSiMe₃ (μ₂-trimethylsiloxy) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₂(μ₂-OSiMe₃)]₂
[Al(Buᵗ)₂(μ₂-Pz)]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), Pz (μ₂-pyrazolyl) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₂(μ₂-Pz)]₂
[Al(Buᵗ)₂(μ₂-SC₆H₂Prⁱ₃-2,4,6)]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), SC₆H₂Prⁱ₃-2,4,6 (μ₂-tri-i-propylphenylthio) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₂(μ₂-SC₆H₂Prⁱ₃-2,4,6)]₂
[Al(Buᵗ)₂(μ₂-TeBuᵗ)]₂ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), TeBuᵗ (μ₂-t-butyltellanyl) Oligomer 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₂(μ₂-TeBuᵗ)]₂
[Al(Buᵗ)₂{N(SiPh₃)₂}] Aluminium VN: 3 CN: 3 ON: (III) EN: 6 Buᵗ (t-butyl), N(SiPh₃)₂ (bis(triphenylsilyl)amino) Molecular 3-coordinate: trigonal planar (p-block element, 0 lone pairs)

[Al(Buᵗ)₂{N(SiPh₃)₂}]
[Al(Buᵗ)₃(AlCp*)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), AlCp* (pentamethylcyclopentadienylaluminium) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₃(AlCp*)]
[Al(Buᵗ)₃(AsPrⁱ₃)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), AsPrⁱ₃ (triisopropyl-arsane) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₃(AsPrⁱ₃)]
[Al(Buᵗ)₃(BiEt₃)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), BiEt₃ (triethylbismuthane) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₃(BiEt₃)]
[Al(Buᵗ)₃(Cl)]⊖ Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), Cl (chloro) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₃(Cl)]⊖
[Al(Buᵗ)₃(CNBuᵗ)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), CNBuᵗ (t-butyl isocyanide) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₃(CNBuᵗ)]
[Al(Buᵗ)₃(CNXy)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), CNXy (xylyl isocyanide) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₃(CNXy)]
[Al(Buᵗ)₃(GaCp*)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), GaCp* (pentamethylcyclopentadienylgallium) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₃(GaCp*)]
[Al(Buᵗ)₃(InCp*)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), InCp* (pentamethylcyclopentadienylindium) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₃(InCp*)]
[Al(Buᵗ)₃(NC₅H₄NMe₂)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), NC₅H₄NMe₂ (4-dimethylaminopyridine) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₃(NC₅H₄NMe₂)]
[Al(Buᵗ)₃(NEt₂H)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), NEt₂H (diethylamine) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₃(NEt₂H)]
[Al(Buᵗ)₃(PPrⁱ₃)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), PPrⁱ₃ (triisopropylphosphane) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₃(PPrⁱ₃)]
[Al(Buᵗ)₃(PPrⁿ₃)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), PPrⁿ₃ (tri-n-propylphosphane) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₃(PPrⁿ₃)]
[Al(Buᵗ)₃(SbEt₃)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), SbEt₃ (triethylstibane) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₃(SbEt₃)]
[Al(Buᵗ)₃(SbMe₃)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), SbMe₃ (trimethylstibane) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₃(SbMe₃)]
[Al(Buᵗ)₃(SbPrⁱ₃)] Aluminium VN: 3 CN: 4 ON: (III) EN: 8 Buᵗ (t-butyl), SbPrⁱ₃ (triisopropylstibane) Molecular 4-coordinate: tetrahedral (p-block element, 0 lone pairs)

[Al(Buᵗ)₃(SbPrⁱ₃)]