Chemicals

Central atom: Silver
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
[Ag(μ₂-O₂NO){P(OPh)₃}₂]₂ Silver VN: 1 CN: 4 ON: (I) EN: 18 NO₃ (μ₂-nitrato), P(OPh)₃ (triphenylphosphite) Oligomer 4-coordinate: tetrahedron (T-4)

[Ag(μ₂-O₂NO){P(OPh)₃}₂]₂

catena–1D-[Ag(μ₂-SO₃CF₃)₂] Silver VN: 2 CN: 4 ON: (II) EN: 17 OSO₂CF₃ (μ₂-trifluoromethanesulfonato-κ²O) Catena-1D 4-coordinate: square plane (SP-4)

catena–1D-[Ag(μ₂-SO₃CF₃)₂]

catena–2D-[Ag(μ₂-SO₃CF₃){μ₂-S(CH₂)₄O-κO,κS}] Silver VN: 1 CN: 4 ON: (I) EN: 18 OSO₂CF₃ (μ₂-trifluoromethanesulfonato-κ²O), S(CH₂)₄O (μ₂-thioxane-κO,κS) Catena-2D 4-coordinate: tetrahedron (T-4)

catena–2D-[Ag(μ₂-SO₃CF₃){μ₂-S(CH₂)₄O-κO,κS}]

[Ag(μ₃-Hfa)(η⁴-Cod)]₂ Silver VN: 1 CN: 5 ON: (I) EN: 20 Hfa (μ₃-hexafluoroacetylacetonato), Cod (η²,η²-cycloocta-1,5-diene) Oligomer 6-coordinate (geometry not specified)

[Ag(μ₃-Hfa)(η⁴-Cod)]₂

[Ag(μ₃-I)(NEt₃)]₄ Silver VN: 1 CN: 4 ON: (I) EN: 18 I (μ₃-iodo), NEt₃ (triethylamine) Oligomer 4-coordinate: tetrahedron (T-4)

[Ag(μ₃-I)(NEt₃)]₄

[Ag(μ₃-I)(Pip)]₄ Silver VN: 1 CN: 4 ON: (I) EN: 18 I (μ₃-iodo), Pip (piperidine) Oligomer 4-coordinate: tetrahedron (T-4)

[Ag(μ₃-I)(Pip)]₄

catena–1D-[Ag(μ₃-O₂N)(PPh₃)] Silver VN: 1 CN: 3 ON: (I) EN: 18 NO₂ (μ₃-nitrito-κ²OκN), PPh₃ (triphenylphosphane) Catena-1D 4-coordinate: tetrahedron (T-4)

catena–1D-[Ag(μ₃-O₂N)(PPh₃)]

catena–1D-[Ag(μ₃-O₂N)(SbPh₃)] Silver VN: 1 CN: 3 ON: (I) EN: 18 NO₂ (μ₃-nitrito-κ²OκN), SbPh₃ (triphenylstibane) Catena-1D 4-coordinate: tetrahedron (T-4)

catena–1D-[Ag(μ₃-O₂N)(SbPh₃)]

network–[Ag(μ₄-I)] Silver VN: 1 CN: 4 ON: (I) EN: 18 I (μ₄-iodo) Network 4-coordinate: tetrahedron (T-4)

network–[Ag(μ₄-I)]

catena–3D-[Ag(μ₄-SO₄)] Silver VN: 2 CN: 4 ON: (II) EN: 17 SO₄ (μ₄-sulphato) Catena-3D 4-coordinate: square plane (SP-4)

catena–3D-[Ag(μ₄-SO₄)]

[Ag₂(O)] Silver VN: 1 CN: 2 ON: (I) EN: 0 O (oxo X₂) Lattice 14-coordinate (geometry not specified)

[Ag₂(O)]

[Ag{(OCNH₂CH₂)N}₂]⊕ Silver VN: 1 CN: 2 ON: (I) EN: 14 (OCNH₂CH₂)N (nitrilotriacetamide-κN,κ³O) Molecular 2-coordinate: linear (L-2)

[Ag{(OCNH₂CH₂)N}₂]⊕

[Ag{C(PPh₃)₂}₂]⊕ Silver VN: 1 CN: 2 ON: (I) EN: 14 C(PPh₃)₂ (carbodiphosphorane) Molecular 2-coordinate: linear (L-2)

[Ag{C(PPh₃)₂}₂]⊕

[Ag{C(SiMe₃)₃}₂]⊖ Silver VN: 1 CN: 2 ON: (I) EN: 14 C(SiMe₃)₃ (tristrimethylsilylmethyl) Molecular 2-coordinate: linear (L-2)

[Ag{C(SiMe₃)₃}₂]⊖

[Ag{CH(PPh₃)₂}₂]³⊕ Silver VN: 1 CN: 2 ON: (I) EN: 14 CH(PPh₃)₂ (bis-(triphenylphosphonio)methyl) Molecular 2-coordinate: linear (L-2)

[Ag{CH(PPh₃)₂}₂]³⊕

[Ag{CH₂(PPh₃)}(C₆F₅)] Silver VN: 1 CN: 2 ON: (I) EN: 14 CH₂(PPh₃) (triphenylphosphonium-ylide), C₆F₅ (pentafluorophenyl) Molecular 2-coordinate: linear (L-2)

[Ag{CH₂(PPh₃)}(C₆F₅)]

[Ag{CO₂(OH)-κO}(PPh₃)₂] Silver VN: 1 CN: 3 ON: (I) EN: 16 CO₂(OH) (hydrogencarbonato-κO), PPh₃ (triphenylphosphane) Molecular 3-coordinate: trigonal plane (TP-3)

[Ag{CO₂(OH)-κO}(PPh₃)₂]

[Ag{N(CH)₄NO}₂]⊕ Silver VN: 1 CN: 2 ON: (I) EN: 14 N(CH)₄NO (pyrazine-N-oxide) Molecular 2-coordinate: linear (L-2)

[Ag{N(CH)₄NO}₂]⊕

[Ag{SC(NH₂)₂}₂{μ₂-SC(NH₂)₂}]₂²⊕ Silver VN: 1 CN: 4 ON: (I) EN: 18 SC(NH₂)₂ (thiourea), SC(NH₂)₂ (μ₂-thiourea) Oligomer 4-coordinate: tetrahedron (T-4)

[Ag{SC(NH₂)₂}₂{μ₂-SC(NH₂)₂}]₂²⊕

[Ag{SC(NHEt)₂}₂]₂²⊕ Silver VN: 1 CN: 2 ON: (I) EN: 14 SC(NHEt)₂ (ethylthiourea) Molecular 3-coordinate: trigonal plane (TP-3)

[Ag{SC(NHEt)₂}₂]₂²⊕