Chemicals

Central atom: Silver
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
[Ag(μ₂-Cl)(PPh₃)₂]₂ Silver VN: 1 CN: 4 ON: (I) EN: 18 Cl (μ₂-chloro), PPh₃ (triphenylphosphane) Oligomer 4-coordinate: tetrahedron (T-4)

[Ag(μ₂-Cl)(PPh₃)₂]₂

catena–1D-[Ag(μ₂-En)]⊕ Silver VN: 1 CN: 2 ON: (I) EN: 14 En (μ₂-ethylenediamine) Catena-1D 2-coordinate: linear (L-2)

catena–1D-[Ag(μ₂-En)]⊕

catena–3D-trans–[Ag(μ₂-F)(FBF₃)] Silver VN: 2 CN: 6 ON: (II) EN: 21 F (μ₂-fluoro), FBF₃ (tetrafluoroborate) Catena-3D 6-coordinate: octahedron (OC-6)

catena–3D-trans–[Ag(μ₂-F)(FBF₃)]

[Ag(μ₂-F)₂] Silver VN: 2 CN: 4 ON: (II) EN: 0 F (μ₂-fluoro) Lattice 4-coordinate: square plane (SP-4)

[Ag(μ₂-F)₂]

catena–2D-[Ag(μ₂-F)₂] Silver VN: 2 CN: 4 ON: (II) EN: 17 F (μ₂-fluoro) Catena-2D 4-coordinate: square plane (SP-4)

catena–2D-[Ag(μ₂-F)₂]

[Ag(μ₂-I)(AsPh₃)₂]₂ Silver VN: 1 CN: 4 ON: (I) EN: 18 I (μ₂-iodo), AsPh₃ (triphenylarsane) Oligomer 4-coordinate: tetrahedron (T-4)

[Ag(μ₂-I)(AsPh₃)₂]₂

[Ag(μ₂-I)(Py)(PPh₃)]₂ Silver VN: 1 CN: 4 ON: (I) EN: 18 I (μ₂-iodo), Py (pyridine), PPh₃ (triphenylphosphane) Oligomer 4-coordinate: tetrahedron (T-4)

[Ag(μ₂-I)(Py)(PPh₃)]₂

[Ag(μ₂-I)(SbPh₃)₂]₂ Silver VN: 1 CN: 4 ON: (I) EN: 18 I (μ₂-iodo), SbPh₃ (triphenylstibane) Oligomer 4-coordinate: tetrahedron (T-4)

[Ag(μ₂-I)(SbPh₃)₂]₂

catena–1D-[Ag(μ₂-I)₂]⊖ Silver VN: 1 CN: 4 ON: (I) EN: 18 I (μ₂-iodo) Catena-1D 4-coordinate: tetrahedron (T-4)

catena–1D-[Ag(μ₂-I)₂]⊖

[Ag(μ₂-N₃)(PPh₃)₂]₂ Silver VN: 1 CN: 4 ON: (I) EN: 18 N₃ (μ₂-azido), PPh₃ (triphenylphosphane) Oligomer 4-coordinate: tetrahedron (T-4)

[Ag(μ₂-N₃)(PPh₃)₂]₂

catena–1D-[Ag(μ₂-N₃)₂]⊖ Silver VN: 1 CN: 4 ON: (I) EN: 18 N₃ (μ₂-azido) Catena-1D 4-coordinate: tetrahedron (T-4)

catena–1D-[Ag(μ₂-N₃)₂]⊖

[Ag(μ₂-NCS-κN,κS)(PPh₃)₂]₂ Silver VN: 1 CN: 4 ON: (I) EN: 18 NCS (μ₂-thiocyanato-κN,κS), PPh₃ (triphenylphosphane) Oligomer 4-coordinate: tetrahedron (T-4)

[Ag(μ₂-NCS-κN,κS)(PPh₃)₂]₂

catena–2D-[Ag(μ₂-NCS-κN,κS)₂]⊖ Silver VN: 1 CN: 4 ON: (I) EN: 18 NCS (μ₂-thiocyanato-κN,κS) Catena-2D 4-coordinate: tetrahedron (T-4)

catena–2D-[Ag(μ₂-NCS-κN,κS)₂]⊖

[Ag(μ₂-O₂CCF₃)(PCy₃)]₂ Silver VN: 1 CN: 4 ON: (I) EN: 16 O₂CCF₃ (μ₂-trifluoroacetato), PCy₃ (tricyclohexylphosphane) Oligomer 4-coordinate (geometry not specified)

[Ag(μ₂-O₂CCF₃)(PCy₃)]₂

[Ag(μ₂-O₂NO)(AsCy₃)]₂ Silver VN: 1 CN: 3 ON: (I) EN: 16 NO₃ (μ₂-nitrato), AsCy₃ (tricyclohexylarsane) Oligomer 3-coordinate: trigonal plane (TP-3)

[Ag(μ₂-O₂NO)(AsCy₃)]₂

[Ag(μ₂-O₂NO)(AsPh₃)₂]₂ Silver VN: 1 CN: 4 ON: (I) EN: 18 NO₃ (μ₂-nitrato), AsPh₃ (triphenylarsane) Oligomer 5-coordinate (geometry not specified)

[Ag(μ₂-O₂NO)(AsPh₃)₂]₂

catena–2D-[Ag(μ₂-O₂NO)(C₈H₁₄)] Silver VN: 1 CN: 3 ON: (I) EN: 16 NO₃ (μ₂-nitrato), C₈H₁₄ (cyclooctene) Catena-2D 3-coordinate: trigonal plane (TP-3)

catena–2D-[Ag(μ₂-O₂NO)(C₈H₁₄)]

catena–1D-[Ag(μ₂-O₂NO)(CNBuᵗ)] Silver VN: 1 CN: 3 ON: (I) EN: 16 NO₃ (μ₂-nitrato), CNBuᵗ (t-butyl isocyanide) Catena-1D 3-coordinate: trigonal plane (TP-3)

catena–1D-[Ag(μ₂-O₂NO)(CNBuᵗ)]

catena–1D-[Ag(μ₂-O₂NO)(PPh₃)] Silver VN: 1 CN: 3 ON: (I) EN: 16 NO₃ (μ₂-nitrato), PPh₃ (triphenylphosphane) Catena-1D 3-coordinate: trigonal plane (TP-3)

catena–1D-[Ag(μ₂-O₂NO)(PPh₃)]

[Ag(μ₂-O₂NO){P(OMe)₃}₂]₂ Silver VN: 1 CN: 4 ON: (I) EN: 18 NO₃ (μ₂-nitrato), P(OMe)₃ (trimethylphosphite) Oligomer 4-coordinate: tetrahedron (T-4)

[Ag(μ₂-O₂NO){P(OMe)₃}₂]₂