Chemicals

Central atom: Tungsten
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
mer–[W(Cl)(OBuᵗ)₃(⭀NBuᵗ)(NH₂Buᵗ)] Tungsten VN: 6 CN: 6 ON: (VI) EN: 16 Cl (chloro), OBuᵗ (t-butyloxy), ⭀NBuᵗ (⭀N t-butylimino), NH₂Buᵗ (t-butylamine) Molecular 6-coordinate: octahedron (OC-6)

mer–[W(Cl)(OBuᵗ)₃(⭀NBuᵗ)(NH₂Buᵗ)]

[W(Cl)(OXylyl)₄] Tungsten VN: 5 CN: 5 ON: (V) EN: 11 Cl (chloro), OXylyl (xylyloxy) Molecular 5-coordinate: square-based pyramid (SPY-5)

[W(Cl)(OXylyl)₄]

[W(Cl)(PMe₃)₄(≡CH)] Tungsten VN: 4 CN: 6 ON: (IV) EN: 18 Cl (chloro), PMe₃ (trimethylphosphane), ≡CH (methylidyne) Molecular 6-coordinate: octahedron (OC-6)

[W(Cl)(PMe₃)₄(≡CH)]

[W(Cl)(PMe₃)₄(≡CMe)] Tungsten VN: 4 CN: 6 ON: (IV) EN: 18 Cl (chloro), PMe₃ (trimethylphosphane), ≡CMe (ethylidyne) Molecular 6-coordinate: octahedron (OC-6)

[W(Cl)(PMe₃)₄(≡CMe)]

[W(Cl)(S)₂(Cp*)] Tungsten VN: 6 CN: 6 ON: (VI) EN: 16 Cl (chloro), S (thio), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 6-coordinate: ③-●-3 piano stool

[W(Cl)(S)₂(Cp*)]

[W(Cl)(SPh)₃(NO)]⊖ Tungsten VN: 6 CN: 5 ON: (II) EN: 14 Cl (chloro), SPh (phenylthio), NO (nitrosyl, linear) Molecular 5-coordinate: trigonal bipyramid (TBPY-5)

[W(Cl)(SPh)₃(NO)]⊖

[W(Cl)(μ₂-Cl)(CO)(η⁵-C₅H₄Me)]₂ Tungsten VN: 4 CN: 8 ON: (III) EN: 18 Cl (chloro), Cl (μ₂-chloro), CO (carbonyl), C₅H₄Me (η⁵-methylcyclopentadienyl) Oligomer 8-coordinate: ③-●-4-1 half-sandwich

[W(Cl)(μ₂-Cl)(CO)(η⁵-C₅H₄Me)]₂

[W(Cl)(μ₂-Cl)(⭀NPh)(CO)₂]₂ Tungsten VN: 4 CN: 6 ON: (IV) EN: 18 Cl (chloro), Cl (μ₂-chloro), ⭀NPh (phenylimino), CO (carbonyl) Oligomer 6-coordinate: octahedron (OC-6)

[W(Cl)(μ₂-Cl)(⭀NPh)(CO)₂]₂

[W(Cl)(μ₂-H)(μ₂-O₂CPh)(PPh₃)]₂ Tungsten VN: 6 CN: 7 ON: (III) EN: 18 Cl (chloro), H (μ₂-hydrido), O₂CPh (μ₂-benzoato), PPh₃ (triphenylphosphane) Oligomer 7-coordinate: edge-capped octahedral

[W(Cl)(μ₂-H)(μ₂-O₂CPh)(PPh₃)]₂

[W(Cl)(≡CPh)(Dmpe)₂] Tungsten VN: 4 CN: 6 ON: (IV) EN: 18 Cl (chloro), ≡CPh (phenylmethylidyne, benzylidyne), Dmpe (1,2-bis-(dimethylphosphino)ethane) Molecular 6-coordinate: octahedron (OC-6)

[W(Cl)(≡CPh)(Dmpe)₂]

[W(Cl)₂(=CHBuᵗ)(O)(PEt₃)] Tungsten VN: 6 CN: 5 ON: (VI) EN: 16 Cl (chloro), =CHBuᵗ (t-butylmethylidene), O (oxo ⭀O X₂L), PEt₃ (triethylphosphane) Molecular 5-coordinate: trigonal bipyramid (TBPY-5)

[W(Cl)₂(=CHBuᵗ)(O)(PEt₃)]

[W(Cl)₂(=CHBuᵗ)(O)(PMe₃)₂] Tungsten VN: 6 CN: 6 ON: (VI) EN: 18 Cl (chloro), =CHBuᵗ (t-butylmethylidene), O (oxo ⭀O X₂L), PMe₃ (trimethylphosphane) Molecular 6-coordinate: octahedron (OC-6)

[W(Cl)₂(=CHBuᵗ)(O)(PMe₃)₂]

[W(Cl)₂(=CHPh)(CO)(PMe₃)] Tungsten VN: 4 CN: 5 ON: (IV) EN: 14 Cl (chloro), =CHPh (benzylidene), CO (carbonyl), PMe₃ (trimethylphosphane) Molecular 6-coordinate: octahedron (OC-6)

[W(Cl)₂(=CHPh)(CO)(PMe₃)]

[W(Cl)₂(=CHPh)(PhC≡CPh)(PMe₃)₂] Tungsten VN: 4 CN: 6 ON: (IV) EN: 16 Cl (chloro), =CHPh (benzylidene), PhC≡CPh (diphenylethyne), PMe₃ (trimethylphosphane) Molecular 6-coordinate: octahedron (OC-6)

[W(Cl)₂(=CHPh)(PhC≡CPh)(PMe₃)₂]

[W(Cl)₂(=NSiMe₃)₂(PMePh₂)] Tungsten VN: 6 CN: 5 ON: (VI) EN: 14 Cl (chloro), =NSiMe₃ (trimethylsilylimino), PMePh₂ (methyldiphenylphosphane) Molecular 5-coordinate: trigonal bipyramid (TBPY-5)

[W(Cl)₂(=NSiMe₃)₂(PMePh₂)]

cis,trans–[W(Cl)₂(=NTol)(CO)(PMe₂Ph)₂] Tungsten VN: 4 CN: 6 ON: (IV) EN: 16 Cl (chloro), =NTol (tolylimino), CO (carbonyl), PMe₂Ph (dimethylphenylphosphane) Molecular 6-coordinate: octahedron (OC-6)

cis,trans–[W(Cl)₂(=NTol)(CO)(PMe₂Ph)₂]

[W(Cl)₂(C₂H₄)(O)(PMePh₂)₂] Tungsten VN: 4 CN: 6 ON: (IV) EN: 18 Cl (chloro), C₂H₄ (ethene), O (oxo ⭀O X₂L), PMePh₂ (methyldiphenylphosphane) Molecular 6-coordinate: octahedron (OC-6)

[W(Cl)₂(C₂H₄)(O)(PMePh₂)₂]

[W(Cl)₂(C₂H₄)(PhC≡CPh)(PMe₃)₂] Tungsten VN: 2 CN: 6 ON: (II) EN: 16 Cl (chloro), C₂H₄ (ethene), PhC≡CPh (diphenylethyne), PMe₃ (trimethylphosphane) Molecular 6-coordinate: octahedron (OC-6)

[W(Cl)₂(C₂H₄)(PhC≡CPh)(PMe₃)₂]

cis,trans–[W(Cl)₂(CH₂Buᵗ)(PHPh)(PEt₃)₂] Tungsten VN: 4 CN: 6 ON: (IV) EN: 14 Cl (chloro), CH₂Buᵗ (t-butylmethyl), PHPh (phenylphosphanyl), PEt₃ (triethylphosphane) Molecular 6-coordinate: octahedron (OC-6)

cis,trans–[W(Cl)₂(CH₂Buᵗ)(PHPh)(PEt₃)₂]

[W(Cl)₂(CO)(O)(PMePh₂)] Tungsten VN: 4 CN: 5 ON: (IV) EN: 16 Cl (chloro), CO (carbonyl), O (oxo ⭀O X₂L), PMePh₂ (methyldiphenylphosphane) Molecular 6-coordinate: octahedron (OC-6)

[W(Cl)₂(CO)(O)(PMePh₂)]