8-coordinate: ③-●-4-1 half-sandwich

[V(μ₂-H)(μ₂-Dmpe)(Cp)]

Formula Unicode styled: 
[V(μ₂-H)(μ₂-Dmpe)(Cp)]
Compound name(s): 
bis-[(μ₂-hydrido)-(dimethylphosphinoethane)-(η⁵-cyclopentadienyl)-vanadium(V—V)]
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
V«V3C8OIIE18B8Z0X3L5»
[MLXZ]𝘲 class: 
[MX3L5]
MLXZ class (ENC, equivalent neutral class): 
MX3L5

[Ta(Br)₂(μ₂-H)(Cp*)]₂

Formula Unicode styled: 
[Ta(Br)₂(μ₂-H)(Cp*)]₂
Compound name(s): 
bis-[dibromo-(μ₂-hydrido)-(η⁵-pentamethylcyclopentadienyl)-tantalum] (Ta—Ta)
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Ta«V5C8OIVE16B8Z0X5L3»
[MLXZ]𝘲 class: 
[MX5L3]
MLXZ class (ENC, equivalent neutral class): 
MX5L3

[Ta(Cl)₂(μ₂-H)(Cp*)]₂

Formula Unicode styled: 
[Ta(Cl)₂(μ₂-H)(Cp*)]₂
Compound name(s): 
bis-[dichloro-(μ₂-hydrido)-(η⁵-pentamethylcyclopentadienyl)-tantalum] (Ta—Ta)
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Ta«V5C8OIVE16B8Z0X5L3»
[MLXZ]𝘲 class: 
[MX5L3]
MLXZ class (ENC, equivalent neutral class): 
MX5L3

[Ta(Cl)₂(μ₂-H){η⁵-C₅H₄(SiMe₃)}]₂

Formula Unicode styled: 
[Ta(Cl)₂(μ₂-H){η⁵-C₅H₄(SiMe₃)}]₂
Compound name(s): 
bis-[dichloro-(μ₂-hydrido)-bis(η⁵-trimethylsilyl-cyclopentadienyl)-tantalum] (Ta—Ta)
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Ta«V5C8OIVE16B8Z0X5L3»
[MLXZ]𝘲 class: 
[MX5L3]
MLXZ class (ENC, equivalent neutral class): 
MX5L3

[Ta(Br)₂(μ₂-H){η⁵-C₅H₄(SiMe₃)}]₂

Formula Unicode styled: 
[Ta(Br)₂(μ₂-H){η⁵-C₅H₄(SiMe₃)}]₂
Compound name(s): 
bis-[dibromo-(μ₂-hydrido)-bis(η⁵-trimethylsilyl-cyclopentadienyl)-tantalum] (Ta—Ta)
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Ta«V5C8OIVE16B8Z0X5L3»
[MLXZ]𝘲 class: 
[MX5L3]
MLXZ class (ENC, equivalent neutral class): 
MX5L3

cis–[Nb(μ₂-I)₂(CO)₂(η⁶-C₆H₃Me₃){Re(CO)₃}]

Formula Unicode styled: 
cis–[Nb(μ₂-I)₂(CO)₂(η⁶-C₆H₃Me₃){Re(CO)₃}]
Compound name(s): 
(η⁶-mesitylene)-bis(μ₂-iodo)-dicarbonyl-(rhenium-tricarbonyl)-niobium (Nb—Re)
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Nb«V3C8OIIIE18B8Z0X3L5»
[MLXZ]𝘲 class: 
[MX3L5]
MLXZ class (ENC, equivalent neutral class): 
MX3L5

[Ho(Cl)₂(Thf)₃(Ind)]

Formula Unicode styled: 
[Ho(Cl)₂(Thf)₃(Ind)]
Compound name(s): 
Dichloro-(η⁵-indenyl)-tris(tetrahydrofuran)-holmium
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Ho«V3C8OIIIE26B8Z0X3L5»
[MLXZ]𝘲 class: 
[MX3L5]
MLXZ class (ENC, equivalent neutral class): 
MX3L5

[Er(OC₆F₅)₂(OEt₂)(Dme)(Cp)]

Formula Unicode styled: 
[Er(OC₆F₅)₂(OEt₂)(Dme)(Cp)]
Compound name(s): 
cyclopentadienyl-(diethyl ether)-bis(pentafluorophenolato)-(1,2-dimethoxyethane)-erbium
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Er«V3C8OIIIE27B8Z0X3L5»
[MLXZ]𝘲 class: 
[MX3L5]
MLXZ class (ENC, equivalent neutral class): 
MX3L5

[Er(Cl)(Thf)(Tp*-κ³N)(Cp)]

Formula Unicode styled: 
[Er(Cl)(Thf)(Tp*-κ³N)(Cp)]
Compound name(s): 
Chloro-(η⁵-cyclopentadienyl)-(hydrogen tris(3,5-dimethylpyrazolyl)borate-N,N',N'')-tetrahydrofuran-erbium
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Er«V3C8OIIIE27B8Z0X3L5»
[MLXZ]𝘲 class: 
[MX3L5]
MLXZ class (ENC, equivalent neutral class): 
MX3L5

[Re(Cl)₂(μ₂-Cl)(η⁵-C₅EtMe₄)]₂

Formula Unicode styled: 
[Re(Cl)₂(μ₂-Cl)(η⁵-C₅EtMe₄)]₂
Compound name(s): 
bis-[(μ₂-Chloro)-dichloro-(η⁵-ethyltetramethyl-cyclopentadienyl)-rhenium(Re—Re)]
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Re«V5C8OIVE18B8Z0X5L3»
[MLXZ]𝘲 class: 
[MX5L3]
MLXZ class (ENC, equivalent neutral class): 
MX5L3

[W(Cl)(μ₂-Cl)(CO)(η⁵-C₅H₄Me)]₂

Formula Unicode styled: 
[W(Cl)(μ₂-Cl)(CO)(η⁵-C₅H₄Me)]₂
Compound name(s): 
bis-[(μ₂-Chloro)-carbonyl-chloro-(η⁵-methylcyclopentadienyl)-tungsten(W—W)]
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
W«V4C8OIIIE18B8Z0X4L4»
[MLXZ]𝘲 class: 
[MX4L4]
MLXZ class (ENC, equivalent neutral class): 
MX4L4

[V(μ₄-S₂C₆H₄)(Cp)]₂

Formula Unicode styled: 
[V(μ₄-S₂C₆H₄)(Cp)]₂
Compound name(s): 
bis-[μ₂-1,2-Benzenedithiolato-S,S'-η⁵-cyclopentadienyl)-vanadium(V—V)]
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
V«V4C8OIIIE17B8Z0X4L4»
[MLXZ]𝘲 class: 
[MX4L4]
MLXZ class (ENC, equivalent neutral class): 
MX4L4

[V(μ₂-Br)₂(η⁵-C₅EtMe₄)]₂

Formula Unicode styled: 
[V(μ₂-Br)₂(η⁵-C₅EtMe₄)]₂
Compound name(s): 
bis-[bis-(μ₂-Bromo)-(η⁵-ethyltetramethyl-cyclopentadienyl)-vanadium(V—V)]
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
V«V4C8OIIIE17B8Z0X4L4»
[MLXZ]𝘲 class: 
[MX4L4]
MLXZ class (ENC, equivalent neutral class): 
MX4L4

[Ta(N₃)₃(μ₂-N₃)(Cp*)]₂

Formula Unicode styled: 
[Ta(N₃)₃(μ₂-N₃)(Cp*)]₂
Compound name(s): 
bis-[(μ₂-Azido)-tris(azido)-(η⁵-pentamethylcyclopentadienyl)-tantalum]
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Ta«V5C8OVE16B8Z0X5L3»
[MLXZ]𝘲 class: 
[MX5L3]
MLXZ class (ENC, equivalent neutral class): 
MX5L3

[Ta(F)₃(μ₂-F)(Cp*)]₂

Formula Unicode styled: 
[Ta(F)₃(μ₂-F)(Cp*)]₂
Compound name(s): 
bis-[(μ₂-Fluoro)-trifluoro-(η⁵-pentamethyl-cyclopentadienyl)-tantalum]
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Ta«V5C8OVE16B8Z0X5L3»
[MLXZ]𝘲 class: 
[MX5L3]
MLXZ class (ENC, equivalent neutral class): 
MX5L3

[Ta(Cl)₄{CH₂(PMe₂Ph)}(Cp*)]

Formula Unicode styled: 
[Ta(Cl)₄{CH₂(PMe₂Ph)}(Cp*)]
Compound name(s): 
Tetrachloro-(eta-pentamethyl-cyclopentadienyl)-(diphenylmethylphosphino-methyl)-tantalum
Central atom: 
Charge on central atom: 
-1
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Ta«V5C8OVE16B8Z0X6L2»
[MLXZ]𝘲 class: 
[MX6L2]-
MLXZ class (ENC, equivalent neutral class): 
MX5L3

[Nb(μ₂-Cl)(CO)₂(η⁵-C₅H₄Me)]₂

Formula Unicode styled: 
[Nb(μ₂-Cl)(CO)₂(η⁵-C₅H₄Me)]₂
Compound name(s): 
bis-[(μ₂-Chloro)-dicarbonyl-(η⁵-methylcyclopentadienyl)-niobium(Nb—Nb)]
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Nb«V3C8OIIE18B8Z0X3L5»
[MLXZ]𝘲 class: 
[MX3L5]
MLXZ class (ENC, equivalent neutral class): 
MX3L5

[Nb(μ₂-Br)₂(η⁶-C₆Me₆)]₂

Formula Unicode styled: 
[Nb(μ₂-Br)₂(η⁶-C₆Me₆)]₂
Compound name(s): 
bis-[di(μ₂-Bromo)-(η⁶-hexamethylbenzene)-niobium(Nb—Nb)]
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Nb«V3C8OIIE18B8Z0X3L5»
[MLXZ]𝘲 class: 
[MX3L5]
MLXZ class (ENC, equivalent neutral class): 
MX3L5

catena–1D-[Zr(Cl)(μ₂-Cl)₂(Cp)]

Formula Unicode styled: 
catena–1D-[Zr(Cl)(μ₂-Cl)₂(Cp)]
Compound name(s): 
catena-[bis(μ₂-Chloro)-chloro-(η⁵-cvclopentadienyl)-zirconium]
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Zr«V4C8OIVE16B8Z0X4L4»
[MLXZ]𝘲 class: 
[MX4L4]
MLXZ class (ENC, equivalent neutral class): 
MX4L4

[Tb(Cl)₂(Thf)₃(Cp)]

Formula Unicode styled: 
[Tb(Cl)₂(Thf)₃(Cp)]
Compound name(s): 
(Cyclopentadienyl)-dichloro-tris(tetrahydrofuran)-terbium
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Tb«V3C8OIIIE24B8Z0X3L5»
[MLXZ]𝘲 class: 
[MX3L5]
MLXZ class (ENC, equivalent neutral class): 
MX3L5