Chemicals

Central atom: Tungsten
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
cis,trans–[W(Cl)₂(⭀NPh)(PMe₃)₂(PhC≡CPh)] Tungsten VN: 4 CN: 6 ON: (IV) EN: 18 Cl (chloro), ⭀NPh (phenylimino), PMe₃ (trimethylphosphane), PhC≡CPh (diphenylethyne) Molecular 6-coordinate: octahedron (OC-6)

cis,trans–[W(Cl)₂(⭀NPh)(PMe₃)₂(PhC≡CPh)]
mer,cis–[W(Cl)₂(⭀NPh)(PMe₃)₃] Tungsten VN: 4 CN: 6 ON: (IV) EN: 18 Cl (chloro), ⭀NPh (phenylimino), PMe₃ (trimethylphosphane) Molecular 6-coordinate: octahedron (OC-6)

mer,cis–[W(Cl)₂(⭀NPh)(PMe₃)₃]
[W(Cl)₃(CO)₂(Cp)] Tungsten VN: 4 CN: 8 ON: (IV) EN: 18 Cl (chloro), CO (carbonyl), Cp (η⁵-cyclopentadienyl) Molecular 8-coordinate (geometry not specified)

[W(Cl)₃(CO)₂(Cp)]
[W(Cl)₃(CO)₄]⊖ Tungsten VN: 2 CN: 7 ON: (II) EN: 18 Cl (chloro), CO (carbonyl) Molecular 7-coordinate (geometry not specified)

[W(Cl)₃(CO)₄]⊖
[W(Cl)₃(H)(PMe₂Ph)₃] Tungsten VN: 4 CN: 7 ON: (IV) EN: 16 Cl (chloro), H (hydrido), PMe₂Ph (dimethylphenylphosphane) Molecular 7-coordinate (geometry not specified)

[W(Cl)₃(H)(PMe₂Ph)₃]
fac–[W(Cl)₃(NEt₂)₃] Tungsten VN: 6 CN: 6 ON: (VI) EN: 18 Cl (chloro), NEt₂ (diethylamino: planar) Molecular 6-coordinate: octahedron (OC-6)

fac–[W(Cl)₃(NEt₂)₃]
[W(Cl)₃(NH₂Buᵗ)(⭀NBuᵗ)] Tungsten VN: 5 CN: 5 ON: (V) EN: 15 Cl (chloro), NH₂Buᵗ (t-butylamine), ⭀NBuᵗ (⭀N t-butylimino) Molecular 6-coordinate: octahedron (OC-6)

[W(Cl)₃(NH₂Buᵗ)(⭀NBuᵗ)]
[W(Cl)₃(O)(OMe₂)₂] Tungsten VN: 5 CN: 6 ON: (V) EN: 17 Cl (chloro), O (oxo ⭀O X₂L), OMe₂ (dimethylether) Molecular 6-coordinate: octahedron (OC-6)

[W(Cl)₃(O)(OMe₂)₂]
[W(Cl)₃(OPPh₃)₂(O)] Tungsten VN: 5 CN: 6 ON: (V) EN: 17 Cl (chloro), OPPh₃ (triphenylphosphane oxide), O (oxo ⭀O X₂L) Molecular 6-coordinate: octahedron (OC-6)

[W(Cl)₃(OPPh₃)₂(O)]
[W(Cl)₃(PMe₂Ph)₂(PhC≡CPh)] Tungsten VN: 3 CN: 6 ON: (III) EN: 15 Cl (chloro), PMe₂Ph (dimethylphenylphosphane), PhC≡CPh (diphenylethyne) Molecular 6-coordinate: octahedron (OC-6)

[W(Cl)₃(PMe₂Ph)₂(PhC≡CPh)]
mer–[W(Cl)₃(PMe₂Ph)₃] Tungsten VN: 3 CN: 6 ON: (III) EN: 15 Cl (chloro), PMe₂Ph (dimethylphenylphosphane) Molecular 6-coordinate: octahedron (OC-6)

mer–[W(Cl)₃(PMe₂Ph)₃]
mer–[W(Cl)₃(PMe₃)₃] Tungsten VN: 3 CN: 6 ON: (III) EN: 15 Cl (chloro), PMe₃ (trimethylphosphane) Molecular 6-coordinate: octahedron (OC-6)

mer–[W(Cl)₃(PMe₃)₃]
mer,cis–[W(Cl)₃(Py)(PMe₃)₃] Tungsten VN: 3 CN: 7 ON: (III) EN: 17 Cl (chloro), Py (pyridine), PMe₃ (trimethylphosphane) Molecular 6-coordinate: octahedron (OC-6)

mer,cis–[W(Cl)₃(Py)(PMe₃)₃]
mer–[W(Cl)₃(Thf)₃] Tungsten VN: 3 CN: 6 ON: (III) EN: 15 Cl (chloro), Thf (tetrahydrofuran) Molecular 6-coordinate: octahedron (OC-6)

mer–[W(Cl)₃(Thf)₃]
[W(Cl)₃(Tp-κ³N)]⊖ Tungsten VN: 3 CN: 6 ON: (III) EN: 15 Cl (chloro), Tp (hydrotris(pyrazolyl)borato-κ³N) Molecular 6-coordinate: ③-●-3 piano stool

[W(Cl)₃(Tp-κ³N)]⊖
[W(Cl)₃(μ₂-Cl)(=NEt)]₂ Tungsten VN: 6 CN: 6 ON: (VI) EN: 14 Cl (chloro), Cl (μ₂-chloro), =NEt (ethylimino) Oligomer 6-coordinate: octahedron (OC-6)

[W(Cl)₃(μ₂-Cl)(=NEt)]₂
[W(Cl)₃(μ₂-SPh)(SMe₂)]₂ Tungsten VN: 5 CN: 7 ON: (IV) EN: 15 Cl (chloro), SPh (μ₂-phenylthio), SMe₂ (dimethylthioether) Oligomer 7-coordinate: edge-capped octahedral

[W(Cl)₃(μ₂-SPh)(SMe₂)]₂
[W(Cl)₃(⭀NBuᵗ)(Cp*)] Tungsten VN: 6 CN: 7 ON: (VI) EN: 18 Cl (chloro), ⭀NBuᵗ (⭀N t-butylimino), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 7-coordinate: ③-●-4 piano stool

[W(Cl)₃(⭀NBuᵗ)(Cp*)]
mer,cis–[W(Cl)₃(⭀NPh)(PPh₃)₂] Tungsten VN: 5 CN: 6 ON: (V) EN: 17 Cl (chloro), ⭀NPh (phenylimino), PPh₃ (triphenylphosphane) Molecular 6-coordinate: octahedron (OC-6)

mer,cis–[W(Cl)₃(⭀NPh)(PPh₃)₂]
[W(Cl)₃{C(NEt₂)H}(Cp*)] Tungsten VN: 4 CN: 7 ON: (IV) EN: 16 Cl (chloro), C(NEt₂)H (diethylaminocarbene), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 7-coordinate: ③-●-4 piano stool

[W(Cl)₃{C(NEt₂)H}(Cp*)]