Chemicals

Central atom: Tungsten
Title Central atom Valence Number (VN) = 𝘹 + 2𝘻 Coordination number Oxidation number Electron number Attached ligand taxonomy Compound type Geometry Formula Unicode
cis,cis,cis–[W(Cl)₂(O)₂(TMEDA-κ²N)] Tungsten VN: 6 CN: 6 ON: (VI) EN: 18 Cl (chloro), (O)₂ (dioxo-cis X₄L Ⓢ), TMEDA (tetramethylethylenediamine-κ²N) Molecular 6-coordinate: octahedron (OC-6)

cis,cis,cis–[W(Cl)₂(O)₂(TMEDA-κ²N)]

[W(Cl)₂(OEt)(μ₂-OEt)(OHEt)]₂ Tungsten VN: 6 CN: 7 ON: (IV) EN: 16 Cl (chloro), OEt (ethoxy), OEt (μ₂-ethoxy), OHEt (ethanol) Oligomer 7-coordinate: edge-capped octahedral

[W(Cl)₂(OEt)(μ₂-OEt)(OHEt)]₂

[W(Cl)₂(OMe)(μ₂-OMe)(OHMe)]₂ Tungsten VN: 6 CN: 7 ON: (IV) EN: 16 Cl (chloro), OMe (methoxy), OMe (μ₂-methoxy), OHMe (methanol) Oligomer 7-coordinate: edge-capped octahedral

[W(Cl)₂(OMe)(μ₂-OMe)(OHMe)]₂

trans,trans–[W(Cl)₂(OSiPh₃)₂(⭀NPh)(OEt₂)] Tungsten VN: 6 CN: 6 ON: (VI) EN: 16 Cl (chloro), OSiPh₃ (triphenylsiloxy), ⭀NPh (phenylimino), OEt₂ (diethylether) Molecular 6-coordinate: octahedron (OC-6)

trans,trans–[W(Cl)₂(OSiPh₃)₂(⭀NPh)(OEt₂)]

[W(Cl)₂(PhC≡CPh)(PMe₃)₃] Tungsten VN: 2 CN: 6 ON: (II) EN: 16 Cl (chloro), PhC≡CPh (diphenylethyne), PMe₃ (trimethylphosphane) Molecular 6-coordinate: octahedron (OC-6)

[W(Cl)₂(PhC≡CPh)(PMe₃)₃]

[W(Cl)₂(PhC≡CPh)₂(PMe₃)₂] Tungsten VN: 2 CN: 6 ON: (II) EN: 16 Cl (chloro), PhC≡CPh (diphenylethyne), PMe₃ (trimethylphosphane) Molecular 6-coordinate: octahedron (OC-6)

[W(Cl)₂(PhC≡CPh)₂(PMe₃)₂]

cis–[W(Cl)₂(Phen)₂] Tungsten VN: 2 CN: 6 ON: (II) EN: 16 Cl (chloro), Phen (phenanthroline) Molecular 6-coordinate: octahedron (OC-6)

cis–[W(Cl)₂(Phen)₂]

[W(Cl)₂(PMe₃)₂]₂ Tungsten VN: 6 CN: 5 ON: (II) EN: 16 Cl (chloro), PMe₃ (trimethylphosphane) Oligomer 5-coordinate: square-based pyramid (SPY-5)

[W(Cl)₂(PMe₃)₂]₂

trans–[W(Cl)₂(PMe₃)₄] Tungsten VN: 2 CN: 6 ON: (II) EN: 16 Cl (chloro), PMe₃ (trimethylphosphane) Molecular 6-coordinate: octahedron (OC-6)

trans–[W(Cl)₂(PMe₃)₄]

trans–[W(Cl)₂(PMePh₂)₄] Tungsten VN: 2 CN: 6 ON: (II) EN: 16 Cl (chloro), PMePh₂ (methyldiphenylphosphane) Molecular 6-coordinate: octahedron (OC-6)

trans–[W(Cl)₂(PMePh₂)₄]

[W(Cl)₂(S)(Dmdtc)₂] Tungsten VN: 6 CN: 7 ON: (VI) EN: 18 Cl (chloro), S (thio; ⭀S), Dmdtc (dimethyldithiocarbamato-κ²S) Molecular 7-coordinate: pentagonal bipyramid (PBPY-7)

[W(Cl)₂(S)(Dmdtc)₂]

cis–[W(Cl)₂(μ₂-Cl)(NO)₂]₂²⊖ Tungsten VN: 6 CN: 6 ON: (O) EN: 18 Cl (chloro), Cl (μ₂-chloro), (NO)₂ (dinitrosyl, (N≡O)₂ cis-octahedral Ⓢ) Oligomer 6-coordinate: octahedron (OC-6)

cis–[W(Cl)₂(μ₂-Cl)(NO)₂]₂²⊖

[W(Cl)₂(μ₂-Cl)(PEt₃)₂]₂ Tungsten VN: 4 CN: 7 ON: (III) EN: 16 Cl (chloro), Cl (μ₂-chloro), PEt₃ (triethylphosphane) Oligomer 7-coordinate: edge-capped octahedral

[W(Cl)₂(μ₂-Cl)(PEt₃)₂]₂

[W(Cl)₂(μ₂-Cl)(PMe₃)₂]₂ Tungsten VN: 4 CN: 7 ON: (III) EN: 16 Cl (chloro), Cl (μ₂-chloro), PMe₃ (trimethylphosphane) Oligomer 7-coordinate: edge-capped octahedral

[W(Cl)₂(μ₂-Cl)(PMe₃)₂]₂

catena–1D-[W(Cl)₂(μ₂-Cl)(μ₂–O)] Tungsten VN: 6 CN: 7 ON: (V) EN: 16 Cl (chloro), Cl (μ₂-chloro), O (μ₂–oxo X₂L) Catena-1D 7-coordinate: edge-capped octahedral

catena–1D-[W(Cl)₂(μ₂-Cl)(μ₂–O)]

catena–1D-[W(Cl)₂(μ₂-Cl)₂] Tungsten VN: 6 CN: 7 ON: (IV) EN: 16 Cl (chloro), Cl (μ₂-chloro) Catena-1D 7-coordinate: edge-capped octahedral

catena–1D-[W(Cl)₂(μ₂-Cl)₂]

[W(Cl)₂(⭀NBuᵗ)(Cp*)] Tungsten VN: 5 CN: 6 ON: (V) EN: 17 Cl (chloro), ⭀NBuᵗ (⭀N t-butylimino), Cp* (η⁵-pentamethylcyclopentadienyl) Molecular 6-coordinate: ③-●-3 piano stool

[W(Cl)₂(⭀NBuᵗ)(Cp*)]

cis,trans–[W(Cl)₂(⭀NBuᵗ)(PMe₃)₂(PhC≡CPh)] Tungsten VN: 4 CN: 6 ON: (IV) EN: 18 Cl (chloro), ⭀NBuᵗ (⭀N t-butylimino), PMe₃ (trimethylphosphane), PhC≡CPh (diphenylethyne) Molecular 6-coordinate: octahedron (OC-6)

cis,trans–[W(Cl)₂(⭀NBuᵗ)(PMe₃)₂(PhC≡CPh)]

[W(Cl)₂(⭀NBuᵗ)₂(Bpy)] Tungsten VN: 6 CN: 6 ON: (VI) EN: 18 Cl (chloro), (⭀NBuᵗ)₂ (di(⭀NBuᵗ t-butylimino)-cis X₄L Ⓢ), Bpy (bipyridine) Molecular 6-coordinate: octahedron (OC-6)

[W(Cl)₂(⭀NBuᵗ)₂(Bpy)]

[W(Cl)₂(⭀NBuᵗ)₂(Py)₂] Tungsten VN: 6 CN: 6 ON: (VI) EN: 18 Cl (chloro), (⭀NBuᵗ)₂ (di(⭀NBuᵗ t-butylimino)-cis X₄L Ⓢ), Py (pyridine) Molecular 6-coordinate: octahedron (OC-6)

[W(Cl)₂(⭀NBuᵗ)₂(Py)₂]