8-coordinate: ③₂-●-2 bent metallocene

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

C₅H₃(Buᵗ)₂ (η⁵-bis(t-butyl)cyclopentadienyl)

Summary of calculated classifications:

Y«V³C⁸O^IIIE¹⁶B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Tm(μ₂-I){η⁵-C₅H₃(Buᵗ)₂}₂]₂

Formula Unicode styled:

[Tm(μ₂-I){η⁵-C₅H₃(Buᵗ)₂}₂]₂

Compound name(s):

bis-[μ₂-Iodo)-bis(η⁵-1,3-bis(t-butyl)cyclopentadienyl)-thulium]

Central atom:

Thulium

Attached groups:

I (μ₂-iodo)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 28

Summary of calculated classifications:

Tm«V³C⁸O^IIIE²⁸B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Tm(μ₂-Cl){η⁵-C₅H₃(SiMe₃)₂}₂]₂

Formula Unicode styled:

[Tm(μ₂-Cl){η⁵-C₅H₃(SiMe₃)₂}₂]₂

Compound name(s):

bis-[(μ₂-chloro)-bis(1,3-bis(trimethylsilylcyclopentadienyl)-thulium]

Central atom:

Thulium

Attached groups:

C₅H₃(SiMe₃)₂ (η⁵-bis(trimethylsilyl)cyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 28

Summary of calculated classifications:

Tm«V³C⁸O^IIIE²⁸B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Sc(μ₂-Cl)(Cp)₂]₂

Formula Unicode styled:

[Sc(μ₂-Cl)(Cp)₂]₂

Compound name(s):

bis-[μ-chloro-bis(cyclopentadienyl-scandium]

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Sc«V³C⁸O^IIIE¹⁶B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Sc(μ₂-SPh)(η⁵-C₅HMe₄)₂]₂

Formula Unicode styled:

[Sc(μ₂-SPh)(η⁵-C₅HMe₄)₂]₂

Compound name(s):

bis-[(μ₂-benzenethiolato)-bis(η⁵-tetramethyl-cyclopentadienyl)-scandium]

Central atom:

C₅HMe₄ (η⁵-tetramethylcyclopentadienyl)

Attached groups:

SPh (μ₂-phenylthio)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Sc«V³C⁸O^IIIE¹⁶B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Sc(μ₂-F)(Cp)₂]₃

Formula Unicode styled:

[Sc(μ₂-F)(Cp)₂]₃

Compound name(s):

tris-[(bis(η⁵-cyclopentadienyl)-fluoro-scandium]

Central atom:

Attached groups:

F (μ₂-fluoro)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Sc«V³C⁸O^IIIE¹⁶B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Sc(Cl)(Thf)(η⁵-C₅HMe₄)₂]

Formula Unicode styled:

[Sc(Cl)(Thf)(η⁵-C₅HMe₄)₂]

Compound name(s):

chloro-bis(η⁵-tetramethylcyclopentadienyl)-(tetrahydrofuran)-scandium

Central atom:

Attached groups:

Cl (chloro)

C₅HMe₄ (η⁵-tetramethylcyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Sc«V³C⁸O^IIIE¹⁶B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Lu(SePh)₂(Cp)₂]⊖

Formula Unicode styled:

[Lu(SePh)₂(Cp)₂]⊖

Compound name(s):

bis(Phenylseleno)-bis(η⁵-cyclopentadienyl)-lutetium(1-)

Central atom:

Attached groups:

SePh (phenylselenyl)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Lu«V³C⁸O^IIIE¹⁶B⁸Z⁰X⁴L⁴»^⊖

[MLXZ]𝘲 class:

[MX₄L₄]^-

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Lu(SBuᵗ)₂(Cp*)₂]⊖

Formula Unicode styled:

[Lu(SBuᵗ)₂(Cp*)₂]⊖

Compound name(s):

bis(μ₂-t-Butylsulfido-S,S')-bis(η⁵-pentamethyl-cyclopentadienyl)-lutetium(1-)

Central atom:

Attached groups:

SBuᵗ (t-butylthio)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Lu«V³C⁸O^IIIE¹⁶B⁸Z⁰X⁴L⁴»^⊖

[MLXZ]𝘲 class:

[MX₄L₄]^-

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Lu(PPh₂)₂(Cp)₂]⊖

Formula Unicode styled:

[Lu(PPh₂)₂(Cp)₂]⊖

Compound name(s):

bis(Diphenylphosphine)-bis(η⁵-cyclopentadienyl)-lutetium(1-)

Central atom:

PPh₂ (diphenylphosphanyl)

Attached groups:

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Lu«V³C⁸O^IIIE¹⁶B⁸Z⁰X⁴L⁴»^⊖

[MLXZ]𝘲 class:

[MX₄L₄]^-

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Lu(μ₂-OH){η⁵-C₅H₄(SiMe₃)}₂]₂

Formula Unicode styled:

[Lu(μ₂-OH){η⁵-C₅H₄(SiMe₃)}₂]₂

Compound name(s):

bis-[(μ₂-Hydroxo)-bis(η⁵-trimethylsilylcyclopentadienyl)-lutetium]

Central atom:

C₅H₄(SiMe₃) (η⁵-(trimethylsilyl)cyclopentadienyl)

Attached groups:

OH (μ₂-hydroxy)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Lu«V³C⁸O^IIIE¹⁶B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Lu(μ₂-OH){η⁵-C₅H₃(SiMe₃)₂}₂]₂

Formula Unicode styled:

[Lu(μ₂-OH){η⁵-C₅H₃(SiMe₃)₂}₂]₂

Compound name(s):

bis-[bis(1,3-bis(Trimethylsilyl)-(η⁵-cyclopentadienyl)-(μ₂-hydroxo)-lutetium]

Central atom:

C₅H₃(SiMe₃)₂ (η⁵-bis(trimethylsilyl)cyclopentadienyl)

Attached groups:

OH (μ₂-hydroxy)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Lu«V³C⁸O^IIIE¹⁶B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Lu(Me)(Thf)(Cp*)₂]

Formula Unicode styled:

[Lu(Me)(Thf)(Cp*)₂]

Compound name(s):

methyl-bis(pentamethyl-cyclopentadienyl)-tetrahydrofuran-lutetium

Central atom:

Attached groups:

Me (methyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Lu«V³C⁸O^IIIE¹⁶B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Lu(I)(Thf){η⁵-C₅H₄(SiMe₃)}{η⁵-C₅H₃(SiMe₃)₂}]

Formula Unicode styled:

[Lu(I)(Thf){η⁵-C₅H₄(SiMe₃)}{η⁵-C₅H₃(SiMe₃)₂}]

Compound name(s):

(η⁵-1,3-bis(Trimethylsilyl)-cyclopentadienyl)-(η⁵-trimethylsilyl-cyclopentadienyl)-iodo-tetrahydrofuran-lutetium

Central atom:

Attached groups:

I (iodo)

C₅H₄(SiMe₃) (η⁵-(trimethylsilyl)cyclopentadienyl)

C₅H₃(SiMe₃)₂ (η⁵-bis(trimethylsilyl)cyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Lu«V³C⁸O^IIIE¹⁶B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Lu(μ₂-Cl){η⁵-C₅H₄(SiMe₃)}₂]₂

Formula Unicode styled:

[Lu(μ₂-Cl){η⁵-C₅H₄(SiMe₃)}₂]₂

Compound name(s):

bis-[(μ₂-Chloro)-di(η⁵-trimethylsilyl-cyclopentadienyl)-lutetium]

Central atom:

Attached groups:

C₅H₄(SiMe₃) (η⁵-(trimethylsilyl)cyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Lu«V³C⁸O^IIIE¹⁶B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Lu(μ₂-Cl){η⁵-C₅H₃(SiMe₃)₂}₂]₂

Formula Unicode styled:

[Lu(μ₂-Cl){η⁵-C₅H₃(SiMe₃)₂}₂]₂

Compound name(s):

bis-[(μ₂-Chloro)-di(η⁵-1,3-bis(trimethylsilyl)-cyclopentadienyl)-lutetium]

Central atom:

Attached groups:

C₅H₃(SiMe₃)₂ (η⁵-bis(trimethylsilyl)cyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Lu«V³C⁸O^IIIE¹⁶B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Lu(C≡CPh)₂(Cp*)₂]⊖

Formula Unicode styled:

[Lu(C≡CPh)₂(Cp*)₂]⊖

Compound name(s):

bis(η⁵-pentamethyl-cyclopentadienyl)-bis(2-phenylacetylenyl)-lutetium

Central atom:

Attached groups:

C≡CPh (phenylethynyl)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Lu«V³C⁸O^IIIE¹⁶B⁸Z⁰X⁴L⁴»^⊖

[MLXZ]𝘲 class:

[MX₄L₄]^-

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Lu(AsPh₂)₂(Cp)₂]⊖

Formula Unicode styled:

[Lu(AsPh₂)₂(Cp)₂]⊖

Compound name(s):

bis(Diphenylarsino)-bis(η⁵-cyclopentadienyl)-lutetium(1-)

Central atom:

Attached groups:

AsPh₂ (diphenylarsanyl)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Lu«V³C⁸O^IIIE¹⁶B⁸Z⁰X⁴L⁴»^⊖

[MLXZ]𝘲 class:

[MX₄L₄]^-

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Ho(μ₂-NH₂)(Cp)₂]₂

Formula Unicode styled:

[Ho(μ₂-NH₂)(Cp)₂]₂

Compound name(s):

bis-[(μ₂-Amido)-bis(η⁵-cyclopentadienyl)-holmium]

Central atom:

Holmium

Attached groups:

NH₂ (μ₂-amino)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 26

Summary of calculated classifications:

Ho«V³C⁸O^IIIE²⁶B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Ho(Cl)(Thf)(Cp*)₂]

Formula Unicode styled:

[Ho(Cl)(Thf)(Cp*)₂]

Compound name(s):

Chloro-bis(η⁵-pentamethyl-cyclopentadienyl)-(tetrahydrofuran-O)-holmium

Central atom:

Holmium

Attached groups:

Cl (chloro)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):