8-coordinate: ③₂-●-2 bent metallocene

C₅H₃(SiMe₃)₂ (η⁵-bis(trimethylsilyl)cyclopentadienyl)

Attached groups:

F (μ₂-fluoro)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

U«V³C⁸O^IIIE¹⁹B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[U(F)(=NMes)(Cp)₂]

Formula Unicode styled:

[U(F)(=NMes*)(Cp*)₂]

Compound name(s):

fluoro-bis(η⁵-pentamethylcyclopentadienyl)-(2,4,6-tri-t-butylphenylimido)-uranium

Central atom:

=NMes* (supermesitylimino)

Attached groups:

F (fluoro)

Cp* (η⁵-pentamethylcyclopentadienyl)

Charge on central atom:

0

Compound type:

Molecular

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 5

Oxidation Number (ON) (Roman numerals):

ON: (V)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

U«V⁵C⁸O^VE¹⁹B⁹Z⁰X⁵L⁴»

[MLXZ]𝘲 class:

[MX₅L₄]

MLXZ class (ENC, equivalent neutral class):

MX₅L₄

[U(μ₂-Cl){η⁵-C₅H₃(SiMe₃)₂}₂]₂

Formula Unicode styled:

[U(μ₂-Cl){η⁵-C₅H₃(SiMe₃)₂}₂]₂

Compound name(s):

bis-[(μ₂-Chloro)-bis{η⁵-1,3-bis(trimethylsilyl)-cyclopentadienyl}-uranium]

Central atom:

C₅H₃(SiMe₃)₂ (η⁵-bis(trimethylsilyl)cyclopentadienyl)

Attached groups:

Cl (μ₂-chloro)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

U«V³C⁸O^IIIE¹⁹B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[U(μ₂-Cl){η⁵-C₅H₃(Buᵗ)₂}₂]₂

Formula Unicode styled:

[U(μ₂-Cl){η⁵-C₅H₃(Buᵗ)₂}₂]₂

Compound name(s):

bis-[(μ₂-Chloro)-bis(η⁵-1,3-di-t-butyl-cyclopentadienyl)-uranium]

Central atom:

C₅H₃(Buᵗ)₂ (η⁵-bis(t-butyl)cyclopentadienyl)

Attached groups:

Cl (μ₂-chloro)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

U«V³C⁸O^IIIE¹⁹B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[U(μ₂-Br){η⁵-C₅H₃(SiMe₃)₂}₂]₂

Formula Unicode styled:

[U(μ₂-Br){η⁵-C₅H₃(SiMe₃)₂}₂]₂

Compound name(s):

bis-[(μ₂-Bromo)-bis{η⁵-1,3-bis(trimethylsilyl)-cyclopentadienyl}-uranium]

Central atom:

C₅H₃(SiMe₃)₂ (η⁵-bis(trimethylsilyl)cyclopentadienyl)

Attached groups:

Br (μ₂-bromo)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

U«V³C⁸O^IIIE¹⁹B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[U(μ₂-NSiMe₃)(η⁵-C₅H₄Me)₂]₂

Formula Unicode styled:

[U(μ₂-NSiMe₃)(η⁵-C₅H₄Me)₂]₂

Compound name(s):

bis-[bis(η⁵-Methylcyclopentadienyl)-(μ₂-trimethylsilylimido)-uranium]

Central atom:

NSiMe₃ (μ₂-trimethylsilylimino X₂L)

Attached groups:

C₅H₄Me (η⁵-methylcyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 20

Summary of calculated classifications:

U«V⁴C⁸O^IVE²⁰B⁹Z⁰X⁴L⁵»

[MLXZ]𝘲 class:

[MX₄L₅]

MLXZ class (ENC, equivalent neutral class):

MX₄L₅

[Th(μ₃-Se){η⁵-C₅H₃(Buᵗ)₂}₂]₂

Formula Unicode styled:

[Th(μ₃-Se){η⁵-C₅H₃(Buᵗ)₂}₂]₂

Compound name(s):

bis-[(μ-seleno)-bis(1,3-di-t-butyl-cyclopentadienyl)-thorium]

Central atom:

C₅H₃(Buᵗ)₂ (η⁵-bis(t-butyl)cyclopentadienyl)

Attached groups:

Se (μ₃-seleno X₂L)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Th«V⁴C⁸O^IVE¹⁸B⁹Z⁰X⁴L⁵»

[MLXZ]𝘲 class:

[MX₄L₅]

MLXZ class (ENC, equivalent neutral class):

MX₄L₅

[Th(μ₂-S){η⁵-C₅H₂(Buᵗ)₃}₂]₂

Formula Unicode styled:

[Th(μ₂-S){η⁵-C₅H₂(Buᵗ)₃}₂]₂

Compound name(s):

bis-[(μ₂-thio)-bis(η⁵-1,2,4-tri-t-butyl-cyclopentadienyl)-thorium ]

Central atom:

C₅H₂(Buᵗ)₃ (η⁵-tris(t-butyl)cyclopentadienyl)

Attached groups:

S (μ₂-thio)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Th«V⁴C⁸O^IVE¹⁸B⁹Z⁰X⁴L⁵»

[MLXZ]𝘲 class:

[MX₄L₅]

MLXZ class (ENC, equivalent neutral class):

MX₄L₅

[Th(μ₂–O){η⁵-C₅H₃(Buᵗ)₂}₂]₂

Formula Unicode styled:

[Th(μ₂–O){η⁵-C₅H₃(Buᵗ)₂}₂]₂

Compound name(s):

bis-[(μ-oxo)-bis(1,3-di-t-butyl-cyclopentadienyl)-thorium]

Central atom:

C₅H₃(Buᵗ)₂ (η⁵-bis(t-butyl)cyclopentadienyl)

Attached groups:

O (μ₂–oxo X₂L)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Th«V⁴C⁸O^IVE¹⁸B⁹Z⁰X⁴L⁵»

[MLXZ]𝘲 class:

[MX₄L₅]

MLXZ class (ENC, equivalent neutral class):

MX₄L₅

[Th(μ₂–O){η⁵-C₅H₂(Buᵗ)₃}₂]₂

Formula Unicode styled:

[Th(μ₂–O){η⁵-C₅H₂(Buᵗ)₃}₂]₂

Compound name(s):

bis-[(μ₂-Oxo)-bis(η⁵-1,2,4-tri-t-butyl-cyclopentadienyl)-thorium ]

Central atom:

C₅H₂(Buᵗ)₃ (η⁵-tris(t-butyl)cyclopentadienyl)

Attached groups:

O (μ₂–oxo X₂L)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Th«V⁴C⁸O^IVE¹⁸B⁹Z⁰X⁴L⁵»

[MLXZ]𝘲 class:

[MX₄L₅]

MLXZ class (ENC, equivalent neutral class):

MX₄L₅

[Zr(μ₂-PBuᵗH)(η⁵-C₅H₄Me)₂]₂

Formula Unicode styled:

[Zr(μ₂-PBuᵗH)(η⁵-C₅H₄Me)₂]₂

Compound name(s):

bis-[(μ₂-t-Butylphosphido)-bis(η⁵-methyl-cyclopentadienyl)-zirconium]

Central atom:

PBuᵗH (μ₂-t-butylphosphanyl)

Attached groups:

C₅H₄Me (η⁵-methylcyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Zr«V³C⁸O^IIIE¹⁷B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Zr(SCH₂CH₂CH₂S)(Cp)₂]₂

Formula Unicode styled:

[Zr(SCH₂CH₂CH₂S)(Cp)₂]₂

Compound name(s):

bis-[(bis(η⁵-Cyclopentadienyl)-(μ₂-propane-1,3-dithiolato)-zirconium]

Central atom:

SCH₂CH₂CH₂S (propanedithiolato-κ²S)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Summary of calculated classifications:

Zr«V⁴C⁸O^IVE¹⁶B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Zr(μ₂-S)(Cp)₂]₂

Formula Unicode styled:

[Zr(μ₂-S)(Cp)₂]₂

Compound name(s):

bis-[(μ₂-Sulfido)-zirconocene]

Central atom:

Attached groups:

S (μ₂-thio)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Zr«V⁴C⁸O^IVE¹⁸B⁹Z⁰X⁴L⁵»

[MLXZ]𝘲 class:

[MX₄L₅]

MLXZ class (ENC, equivalent neutral class):

MX₄L₅

[Zr(μ₂-PMe₂)(Cp)₂]₂

Formula Unicode styled:

[Zr(μ₂-PMe₂)(Cp)₂]₂

Compound name(s):

bis-[bis-(η⁵-Cyclopentadienyl)-(μ₂-dimethylphosphino-P,P)-zirconium]

Central atom:

PMe₂ (μ₂-dimethylphosphanyl)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Zr«V⁴C⁸O^IIIE¹⁸B⁹Z⁰X⁴L⁵»

[MLXZ]𝘲 class:

[MX₄L₅]

MLXZ class (ENC, equivalent neutral class):

MX₄L₅

[Zr(μ₂-PHPh)(Cp)₂]₂

Formula Unicode styled:

[Zr(μ₂-PHPh)(Cp)₂]₂

Compound name(s):

bis-[bis-(η⁵-Cyclopentadienyl)-((μ₂-phenylphosphido-P,P)-zirconium]

Central atom:

PHPh (μ₂-phenylphosphanyl)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Zr«V³C⁸O^IIIE¹⁷B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Zr(μ₂-PCyH)(Cp)₂]₂

Formula Unicode styled:

[Zr(μ₂-PCyH)(Cp)₂]₂

Compound name(s):

bis-[(bis(η⁵-Cyclopentadienyl)-(μ₂-cyclohexylphosphido)-zirconium]

Central atom:

PCyH (μ₂-cyclohexylphosphanyl)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Zr«V³C⁸O^IIIE¹⁷B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Zr(μ₂-I){η⁵-C₅H₄(SiMe₃)}₂]₂

Formula Unicode styled:

[Zr(μ₂-I){η⁵-C₅H₄(SiMe₃)}₂]₂

Compound name(s):

bis-[(μ₂-Iodo)-bis((η⁵-trimethylsilyl-cyclopentadienyl)-zirconium]

Central atom:

C₅H₄(SiMe₃) (η⁵-(trimethylsilyl)cyclopentadienyl)

Attached groups:

I (μ₂-iodo)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Zr«V³C⁸O^IIIE¹⁷B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Zr(μ₂-I)(η⁵-C₅H₄Me)₂]₂

Formula Unicode styled:

[Zr(μ₂-I)(η⁵-C₅H₄Me)₂]₂

Compound name(s):

bis-[(μ₂-Iodo)-bis((η⁵-methylcyclopentadienyl)-zirconium]

Central atom:

C₅H₄Me (η⁵-methylcyclopentadienyl)

Attached groups:

I (μ₂-iodo)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Zr«V³C⁸O^IIIE¹⁷B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Zr(μ₂-I)(Cp)₂]₂

Formula Unicode styled:

[Zr(μ₂-I)(Cp)₂]₂

Compound name(s):

bis-[(bis(η⁵-Cyclopentadienyl)-(μ₂-iodo)-zirconium]

Central atom:

Attached groups:

I (μ₂-iodo)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Zr«V³C⁸O^IIIE¹⁷B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Zr(μ₂-Cl){η⁵-C₅H₄(SiMe₃)}₂]₂

Formula Unicode styled:

[Zr(μ₂-Cl){η⁵-C₅H₄(SiMe₃)}₂]₂

Compound name(s):

bis-[(μ₂-Chloro)-bis(η⁵-methylcyclopentadienyl)-zirconium]

Central atom:

C₅H₄(SiMe₃) (η⁵-(trimethylsilyl)cyclopentadienyl)

Attached groups:

Cl (μ₂-chloro)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: