8-coordinate: ③₂-●-2 bent metallocene

N(PPh₂)₂ (bis(diphenylphosphanyl)amino XL)

Attached groups:

Cl (chloro)

Charge on central atom:

0

Compound type:

Molecular

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 18

Summary of calculated classifications:

Zr«V⁴C⁸O^IVE¹⁸B⁹Z⁰X⁴L⁵»

[MLXZ]𝘲 class:

[MX₄L₅]

MLXZ class (ENC, equivalent neutral class):

MX₄L₅

[Zr(μ₂-Cl)(η⁵-C₅H₄Me)₂]₂²⊕

Formula Unicode styled:

[Zr(μ₂-Cl)(η⁵-C₅H₄Me)₂]₂²⊕

Compound name(s):

bis-[(μ₂-Chloro)-bis(η⁵-methylcyclopentadienyl)-zirconium(1+)]

Central atom:

Attached groups:

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Zr«V⁴C⁸O^IVE¹⁶B⁸Z⁰X³L⁵»^⊕

[MLXZ]𝘲 class:

[MX₃L₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Zr(μ₂-Cl)(Cp)₂]₂²⊕

Formula Unicode styled:

[Zr(μ₂-Cl)(Cp)₂]₂²⊕

Compound name(s):

bis-[(μ₂-Chloro)-bis(η⁵-cyclopentadienyl)-zirconium(1+)]

Central atom:

Attached groups:

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Zr«V⁴C⁸O^IVE¹⁶B⁸Z⁰X³L⁵»^⊕

[MLXZ]𝘲 class:

[MX₃L₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Zr(μ₂-C≡CSiMe₃)(Cp)₂]₂

Formula Unicode styled:

[Zr(μ₂-C≡CSiMe₃)(Cp)₂]₂

Compound name(s):

bis-[(μ₂-η²-Trimethylsilylethynyl)-bis(η⁵-cyclopentadienyl)-zirconium]

Central atom:

C≡CSiMe₃ (μ₂-trimethylsilylalkynyl)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Zr«V³C⁸O^IIIE¹⁷B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Zr(μ₂-C≡CPh)(η⁵-C₅H₄Me)₂]₂

Formula Unicode styled:

[Zr(μ₂-C≡CPh)(η⁵-C₅H₄Me)₂]₂

Compound name(s):

bis-[(μ₂-η²,σ¹-Phenylethynyl)-bis(η⁵-methylcyclopentadienyl)-zirconium]

Central atom:

Attached groups:

C≡CPh (μ₂-phenylethynyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Zr«V³C⁸O^IIIE¹⁷B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Ti(Te group)₂(η⁵-C₅H₄Me)₂]₂

Formula Unicode styled:

[Ti(Te group)₂(η⁵-C₅H₄Me)₂]₂

Compound name(s):

bis-[(μ₂-Ditellurido)-bis(η⁵-methylcyclopentadienyl)-titanium]

Central atom:

Attached groups:

Te group (X type)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ti«V⁴C⁸O^IVE¹⁶B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Ti(μ₂-SiH₂)(Cp)₂]₂

Formula Unicode styled:

[Ti(μ₂-SiH₂)(Cp)₂]₂

Compound name(s):

bis-[(μ₂-silyleno)-bis(η⁵-cyclopentadienyl)-titanium]

Central atom:

Attached groups:

SiH₂ (μ₂-silylene)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ti«V⁴C⁸O^IVE¹⁶B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Ti(μ₂-Se₂)(η⁵-C₅H₄Me)₂]₂

Formula Unicode styled:

[Ti(μ₂-Se₂)(η⁵-C₅H₄Me)₂]₂

Compound name(s):

bis-[(μ₂-Diselenido)-bis(η⁵-methylcyclopentadienyl)-titanium]

Central atom:

Attached groups:

Se₂ (μ₂-perseleno)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ti«V⁴C⁸O^IVE¹⁶B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Ti(μ₂-SbEt₂)(Cp)₂]₂

Formula Unicode styled:

[Ti(μ₂-SbEt₂)(Cp)₂]₂

Compound name(s):

bis-[(μ₂-diethylantimony)-bis(η⁵-cyclopentadienyl)-titanium]

Central atom:

SbEt₂ (μ₂-diethylstibanyl)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ti«V³C⁸O^IIIE¹⁷B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Ti(μ₂-PMe₂)(Cp)₂]₂

Formula Unicode styled:

[Ti(μ₂-PMe₂)(Cp)₂]₂

Compound name(s):

bis-[(μ₂-Dimethylphosphido)-titanocene]

Central atom:

PMe₂ (μ₂-dimethylphosphanyl)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ti«V³C⁸O^IIIE¹⁷B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Ti(μ₂-PCy₂)(Cp)₂]₂

Formula Unicode styled:

[Ti(μ₂-PCy₂)(Cp)₂]₂

Compound name(s):

bis-[(μ₂-Cyclohexylphosphido)-bis(η⁵-cyclopentadienyl)-titanium]

Central atom:

PCy₂ (μ₂-dicyclohexylphosphanyl)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ti«V³C⁸O^IIIE¹⁷B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Ti(μ₂-OMe)(Cp)₂]₂

Formula Unicode styled:

[Ti(μ₂-OMe)(Cp)₂]₂

Compound name(s):

bis-[(μ₂-Methoxo)-bis(η⁵-cyclopentadienyl)-titanium]

Central atom:

Attached groups:

OMe (μ₂-methoxy)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ti«V³C⁸O^IIIE¹⁷B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Ti(μ₂-OEt)(Cp)₂]₂

Formula Unicode styled:

[Ti(μ₂-OEt)(Cp)₂]₂

Compound name(s):

bis-[(μ₂-Ethoxo)-(η⁵-cyclopentadienyl)-titanium]

Central atom:

Attached groups:

OEt (μ₂-ethoxy)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ti«V³C⁸O^IIIE¹⁷B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Ti(μ₂-NCNCN){η⁵-C₅H₄(SiMe₃)}₂]₂

Formula Unicode styled:

[Ti(μ₂-NCNCN){η⁵-C₅H₄(SiMe₃)}₂]₂

Compound name(s):

bis-[(μ₂-Dicyanamido)-bis(η⁵-trimethylsilyl-cyclopentadienyl)-titanium]

Central atom:

C₅H₄(SiMe₃) (η⁵-(trimethylsilyl)cyclopentadienyl)

Attached groups:

NCNCN (μ₂-dicyanamido⊖)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ti«V³C⁸O^IIIE¹⁷B⁸Z⁰X²L⁶»^⊕

[MLXZ]𝘲 class:

[MX₂L₆]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Ti(FAsF₅)₂(Cp)₂]

Formula Unicode styled:

[Ti(FAsF₅)₂(Cp)₂]

Compound name(s):

bis-(eta-Cyclopentadienyl)-bis(hexafluoroarsenato-F)-titanium

Central atom:

FAsF₅ (hexafluoroarsenate)

Attached groups:

Charge on central atom:

2

Compound type:

Molecular

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ti«V⁴C⁸O^IVE¹⁶B⁸Z⁰X²L⁶»^2⊕

[MLXZ]𝘲 class:

[MX₂L₆]²⁺

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Ti(μ₂-Cl){η⁵-C₅H₄(SiMe₃)}₂]₂

Formula Unicode styled:

[Ti(μ₂-Cl){η⁵-C₅H₄(SiMe₃)}₂]₂

Compound name(s):

bis-[(μ₂-Chloro)-bis(η⁵-trimethylsilyl-cyclopentadienyl)-titanium]

Central atom:

Attached groups:

C₅H₄(SiMe₃) (η⁵-(trimethylsilyl)cyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ti«V³C⁸O^IIIE¹⁷B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Ti(μ₂-Cl)(Cp)₂]₂

Formula Unicode styled:

[Ti(μ₂-Cl)(Cp)₂]₂

Compound name(s):

bis-[(μ₂-Chloro)-bis(bis(η⁵-cyclopentadienyl)-titanium]

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ti«V³C⁸O^IIIE¹⁷B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Ti(μ₂-C≡CSiMe₃)(Cp)₂]₂

Formula Unicode styled:

[Ti(μ₂-C≡CSiMe₃)(Cp)₂]₂

Compound name(s):

bis-[(μ₂-η²-Trimethylsilylacetylene)-bis(titanocene]

Central atom:

C≡CSiMe₃ (μ₂-trimethylsilylalkynyl)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ti«V³C⁸O^IIIE¹⁷B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Ti(μ₂-Br)(η⁵-C₅H₄Me)₂]₂

Formula Unicode styled:

[Ti(μ₂-Br)(η⁵-C₅H₄Me)₂]₂

Compound name(s):

bis-[μ₂-bromo-bis(bis(η⁵-methylcyclopentadienyl) titanium]

Central atom:

Attached groups:

Br (μ₂-bromo)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

SiBuᵗ₂H (di-t-butylsilyl)

Summary of calculated classifications:

Ti«V³C⁸O^IIIE¹⁷B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Ta(SiBuᵗ₂H)(Cp)₂]

Formula Unicode styled:

[Ta(SiBuᵗ₂H)(Cp)₂]

Compound name(s):

Di-t-butylsilyl-trimethylphosphine-tantalocene

Central atom:

Tantalum

Attached groups:

Charge on central atom:

0

Compound type:

Molecular

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 7

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: