8-coordinate: ③₂-●-2 bent metallocene

OC₆H₃Prⁱ₂-2,6 (di-isopropylphenoxy-2,6)

Attached groups:

Cl (chloro)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ce«V⁴C⁸O^IVE¹⁶B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Ce(μ₂-SPh)(Cp*)₂]₂

Formula Unicode styled:

[Ce(μ₂-SPh)(Cp*)₂]₂

Compound name(s):

bis-[(μ₂-Phenylthiolato)-bis(η⁵-pentamethyl-cyclopentadienyl)-cerium]

Central atom:

Attached groups:

SPh (μ₂-phenylthio)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ce«V³C⁸O^IIIE¹⁷B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Ce(μ₂-OMe){η⁵-C₅H₃(Buᵗ)₂}₂]₂

Formula Unicode styled:

[Ce(μ₂-OMe){η⁵-C₅H₃(Buᵗ)₂}₂]₂

Compound name(s):

bis-[(μ₂-Methoxo)-bis(η⁵-1,3-di-t-butyl-cyclopentadienyl)-cerium]

Central atom:

Attached groups:

OMe (μ₂-methoxy)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ce«V³C⁸O^IIIE¹⁷B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Ce(μ₂-Me)(η⁵-C₅H₄Buᵗ)₂]₂

Formula Unicode styled:

[Ce(μ₂-Me)(η⁵-C₅H₄Buᵗ)₂]₂

Compound name(s):

bis-[(μ₂-methyl)-bis(η⁵-t-butyl-cyclopentadienyl)-cerium]

Central atom:

C₅H₄Buᵗ (η⁵-t-butyl-cyclopentadienyl)

Attached groups:

Me (μ₂-methyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ce«V³C⁸O^IIIE¹⁷B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Ce(μ₂-I)(η⁵-C₅H₄Buᵗ)₂]₂

Formula Unicode styled:

[Ce(μ₂-I)(η⁵-C₅H₄Buᵗ)₂]₂

Compound name(s):

bis-[(μ₂-Iodo)-bis(η⁵-t-butyl-cyclopentadienyl)-cerium]

Central atom:

C₅H₄Buᵗ (η⁵-t-butyl-cyclopentadienyl)

Attached groups:

I (μ₂-iodo)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ce«V³C⁸O^IIIE¹⁷B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Ce(μ₂-H){η⁵-C₅H₃(Buᵗ)₂}₂]₂

Formula Unicode styled:

[Ce(μ₂-H){η⁵-C₅H₃(Buᵗ)₂}₂]₂

Compound name(s):

bis-[(μ₂-Hydrido)-bis(η⁵-1,3-di-t-butyl-cyclopentadienyl)-cerium]

Central atom:

Attached groups:

H (μ₂-hydrido)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ce«V³C⁸O^IIIE¹⁷B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Ce(μ₂-Cl){η⁵-C₅H₃(Buᵗ)₂}₂]₂

Formula Unicode styled:

[Ce(μ₂-Cl){η⁵-C₅H₃(Buᵗ)₂}₂]₂

Compound name(s):

bis-[(μ₂-Chloro)-bis(η⁵-1,3-di-t-butyl-cyclopentadienyl)-cerium]

Central atom:

Attached groups:

Cl (μ₂-chloro)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ce«V³C⁸O^IIIE¹⁷B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[La(μ₂-SePh)(Cp*)₂]₂

Formula Unicode styled:

[La(μ₂-SePh)(Cp*)₂]₂

Compound name(s):

bis-[(μ₂-Phenylselenolato)-bis(η⁵-pentamethyl-cyclopentadienyl)-lanthanum]

Central atom:

Attached groups:

SePh (μ₂-phenylseleno)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

La«V³C⁸O^IIIE¹⁶B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[La(μ₂-OMe){η⁵-C₅H₃(SiMe₃)₂}₂]₂

Formula Unicode styled:

[La(μ₂-OMe){η⁵-C₅H₃(SiMe₃)₂}₂]₂

Compound name(s):

bis-[(μ-methoxy)-bis(bis(trimethylsilyl)cyclopentadienyl)-lanthanum]

Central atom:

C₅H₃(SiMe₃)₂ (η⁵-bis(trimethylsilyl)cyclopentadienyl)

Attached groups:

OMe (μ₂-methoxy)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

La«V³C⁸O^IIIE¹⁶B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[La(μ₂-I){η⁵-C₅H₃(SiMe₃)₂}₂]₂

Formula Unicode styled:

[La(μ₂-I){η⁵-C₅H₃(SiMe₃)₂}₂]₂

Compound name(s):

bis-[(μ₂-iodo)-bis(η⁵-1,3-bis(trimethylsilyl)cyclopentadienyl)-lanthanum]

Central atom:

C₅H₃(SiMe₃)₂ (η⁵-bis(trimethylsilyl)cyclopentadienyl)

Attached groups:

I (μ₂-iodo)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

La«V³C⁸O^IIIE¹⁶B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[La(μ₂-I){η⁵-C₅H₃(Buᵗ)₂}₂]₂

Formula Unicode styled:

[La(μ₂-I){η⁵-C₅H₃(Buᵗ)₂}₂]₂

Compound name(s):

bis-[(μ-Iodo)-bis(η5-1,3-di-t-butylcyclopentadienyl)-lanthanum]

Central atom:

Attached groups:

I (μ₂-iodo)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

La«V³C⁸O^IIIE¹⁶B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[La(μ₂-CH₂CN)(Cp*)₂]₂

Formula Unicode styled:

[La(μ₂-CH₂CN)(Cp*)₂]₂

Compound name(s):

bis-[(μ₂-Cyanomethyl)-bis(η⁵-pentamethyl-cyclopentadienyl)-lanthanum)

Central atom:

Attached groups:

CH₂CN (μ₂-cyanomethyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

TMEDA (tetramethylethylenediamine-κ²N)

Summary of calculated classifications:

La«V³C⁸O^IIIE¹⁶B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Pb(TMEDA-κ²N)(Cp)₂]

Formula Unicode styled:

[Pb(TMEDA-κ²N)(Cp)₂]

Compound name(s):

bis(η⁵-Cyclopentadienyl)-tetramethylethylenediamine-lead

Central atom:

Lead

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (II)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Dmpe (1,2-bis-(dimethylphosphino)ethane)

Summary of calculated classifications:

Pb«V²C⁸O^IIE¹⁸B⁸Z⁰X²L⁶»

[MLXZ]𝘲 class:

[MX₂L₆]

MLXZ class (ENC, equivalent neutral class):

MX₂L₆

[Mn(Dmpe)(Cp₂)]

Formula Unicode styled:

[Mn(Dmpe)(Cp₂)]

Compound name(s):

bis(η-Cyclopentadienyl)-1,2-bis(dimethylphosphino)ethane-manganese

Central atom:

Manganese

Attached groups:

(Cp₂) (bis-(η⁵-cyclopentadienyl) X₂L₃ Ⓢ)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (II)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 19

Summary of calculated classifications:

Mn«V²C⁸O^IIE¹⁹B⁷Z⁰X²L⁵»

[MLXZ]𝘲 class:

[MX₂L₅]

MLXZ class (ENC, equivalent neutral class):

MX₂L₅

[Re(Br)₂(Cp)₂]⊕

Formula Unicode styled:

[Re(Br)₂(Cp)₂]⊕

Compound name(s):

bis(pi-Cyclopentadienyl)dibromo-rhenium(1+)

Central atom:

Rhenium

Attached groups:

Br (bromo)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 5

Oxidation Number (ON) (Roman numerals):

ON: (V)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Re«V⁵C⁸O^VE¹⁸B⁸Z⁰X⁴L⁴»^⊕

[MLXZ]𝘲 class:

[MX₄L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

[Mo(Me)(NO)(Cp)₂]

Formula Unicode styled:

[Mo(Me)(NO)(Cp)₂]

Compound name(s):

methyl-nitrosyl-bis(cyclopentadienyl)-molybdenum

Central atom:

Attached groups:

NO (nitrosyl X)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V⁴C⁸O^IVE¹⁸B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Nb(Cp-κC)₂(Cp)₂]

Formula Unicode styled:

[Nb(Cp-κC)₂(Cp)₂]

Compound name(s):

bis((η⁵-Cyclopentadienyl)-(cyclopentadienyl))-niobium

Central atom:

Niobium

Attached groups:

Cp (cyclopentadienyl-κC)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Nb«V⁴C⁸O^IVE¹⁷B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Mo(Me)₂(Cp*)₂]

Formula Unicode styled:

[Mo(Me)₂(Cp*)₂]

Compound name(s):

Dimethyl-bis(η-pentamethylcyclopentadienyl)-molybdenum

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V⁴C⁸O^IVE¹⁸B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Mo(Me)(PPh₃)(Cp)₂]⊕

Formula Unicode styled:

[Mo(Me)(PPh₃)(Cp)₂]⊕

Compound name(s):

bis(η-Cyclopentadienyl)-methyl-triphenylphosphine-molybdenum(1+)

Central atom:

Attached groups:

PPh₃ (triphenylphosphane)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V⁴C⁸O^IVE¹⁸B⁸Z⁰X³L⁵»^⊕

[MLXZ]𝘲 class:

[MX₃L₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Mo(Me)(NO)(Cp)(Cp*)]

Formula Unicode styled:

[Mo(Me)(NO)(Cp)(Cp*)]

Compound name(s):

(η-Cyclopentadienyl)-(η-pentamethyl-cyclopentadienyl)-methyl-nitrosyl-molybdenum

Central atom:

Attached groups:

(Cp)(Cp*) ((η⁵-cyclopentadienyl) + η⁵-pentamethylcyclopentadienyl) X₂L₃ Ⓢ)

NO (nitrosyl, linear)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 6

Oxidation Number (ON) (Roman numerals):

ON: (II)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: