8-coordinate: ③₂-●-2 bent metallocene

Attached groups:

C₅H₃(Buᵗ)₂ (η⁵-bis(t-butyl)cyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (II)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 22

Summary of calculated classifications:

Sm«V²C⁸O^IIE²²B⁸Z⁰X²L⁶»

[MLXZ]𝘲 class:

[MX₂L₆]

MLXZ class (ENC, equivalent neutral class):

MX₂L₆

[Sm(Thf)₂(Cp*)₂]⊕

Formula Unicode styled:

[Sm(Thf)₂(Cp*)₂]⊕

Compound name(s):

bis(η⁵-Pentamethyl-cyclopentadienyl)-bis(tetrahydrofuran-O)-samarium(1+)

Central atom:

Attached groups:

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Sm«V³C⁸O^IIIE²¹B⁸Z⁰X²L⁶»^⊕

[MLXZ]𝘲 class:

[MX₂L₆]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Sm(Thf)₂(Cp*)₂]

Formula Unicode styled:

[Sm(Thf)₂(Cp*)₂]

Compound name(s):

bis(η⁵-Pentamethyl-cyclopentadienyl)-bis(tetrahydrofuran-O)-samarium

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (II)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 22

Summary of calculated classifications:

Sm«V²C⁸O^IIE²²B⁸Z⁰X²L⁶»

[MLXZ]𝘲 class:

[MX₂L₆]

MLXZ class (ENC, equivalent neutral class):

MX₂L₆

[Sm(TePh)(Thf)(Cp*)₂]

Formula Unicode styled:

[Sm(TePh)(Thf)(Cp*)₂]

Compound name(s):

bis(η⁵-Pentamethylcyclopentadienyl)-(phenyltellurolato)-(tetrahydrofuran)-samarium

Central atom:

Attached groups:

TePh (phenyltellanyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Sm«V³C⁸O^IIIE²¹B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Sm(TeMes)(Thf)(Cp*)₂]

Formula Unicode styled:

[Sm(TeMes)(Thf)(Cp*)₂]

Compound name(s):

(Mesityltelluro)-bis(η⁵-pentamethyl-cyclopentadienyl)-(tetrahydrofuran)-samarium

Central atom:

Attached groups:

TeMes (mesityltellanyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Sm«V³C⁸O^IIIE²¹B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Sm(SPh)(Thf)(Cp*)₂]

Formula Unicode styled:

[Sm(SPh)(Thf)(Cp*)₂]

Compound name(s):

bis(η⁵-Pentamethylcyclopentadienyl)-(phenylthiolato)-(tetrahydrofuran)-samarium

Central atom:

Attached groups:

SPh (phenylthio)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Sm«V³C⁸O^IIIE²¹B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Sm(SiMe₃)₂(Cp)₂]⊖

Formula Unicode styled:

[Sm(SiMe₃)₂(Cp)₂]⊖

Compound name(s):

bis(η⁵-cyclopentadienyl)-bis-(trimethylsilyl)-samarium(1-)

Central atom:

Attached groups:

SiMe₃ (trimethylsilyl)

Cp (η⁵-cyclopentadienyl)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Sm«V³C⁸O^IIIE²¹B⁸Z⁰X⁴L⁴»^⊖

[MLXZ]𝘲 class:

[MX₄L₄]^-

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Sm(SePh)(Thf)(Cp*)₂]

Formula Unicode styled:

[Sm(SePh)(Thf)(Cp*)₂]

Compound name(s):

bis(η⁵-Pentamethylcyclopentadienyl)-(phenylselenolato)-(tetrahydrofuran)-samarium

Central atom:

Attached groups:

SePh (phenylselenyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Sm«V³C⁸O^IIIE²¹B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Sm(Py)₂(Cp*)₂]⊕

Formula Unicode styled:

[Sm(Py)₂(Cp*)₂]⊕

Compound name(s):

bis(η⁵-Pentamethyl-cyclopentadienyl)-bis(pyridyl)-samarium(1+)

Central atom:

Attached groups:

Py (pyridine)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Sm«V³C⁸O^IIIE²¹B⁸Z⁰X²L⁶»^⊕

[MLXZ]𝘲 class:

[MX₂L₆]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Sm(Ph)(Thf)(Cp*)₂]

Formula Unicode styled:

[Sm(Ph)(Thf)(Cp*)₂]

Compound name(s):

bis(η⁵-Pentamethyl-cyclopentadienyl)-phenyl-tetrahydrofuran-samarium

Central atom:

Attached groups:

Ph (phenyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Sm«V³C⁸O^IIIE²¹B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Sm(OPh)(Thf)(Cp*)₂]

Formula Unicode styled:

[Sm(OPh)(Thf)(Cp*)₂]

Compound name(s):

bis(η⁵-Pentamethylcyclopentadienyl)-(phenoxy)-(tetrahydrofuran)-samarium

Central atom:

Attached groups:

OPh (phenoxy)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Sm«V³C⁸O^IIIE²¹B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Sm(O=CMe₂)₂(Cp*)₂]⊕

Formula Unicode styled:

[Sm(O=CMe₂)₂(Cp*)₂]⊕

Compound name(s):

bis(η⁵-Pentamethyl-cyclopentadienyl)-bis(acetone)-samarium(1+)

Central atom:

Attached groups:

O=CMe₂ (acetone)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Sm«V³C⁸O^IIIE²¹B⁸Z⁰X²L⁶»^⊕

[MLXZ]𝘲 class:

[MX₂L₆]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Sm(NHPh)(Thf)(Cp*)₂]

Formula Unicode styled:

[Sm(NHPh)(Thf)(Cp*)₂]

Compound name(s):

bis(η⁵-Pentamethyl-cyclopentadienyl)-anilido-tetrahydrofuran-samarium

Central atom:

NHPh (phenylamino: planar)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 23

Summary of calculated classifications:

Sm«V³C⁸O^IIIE²³B⁹Z⁰X³L⁶»

[MLXZ]𝘲 class:

[MX₃L₆]

MLXZ class (ENC, equivalent neutral class):

MX₃L₆

[Sm(Me)(Thf)(Cp*)₂]

Formula Unicode styled:

[Sm(Me)(Thf)(Cp*)₂]

Compound name(s):

(Tetrahydrofuran-O)-methyl-bis(η⁵-pentamethyl-cyclopentadienyl)-samarium

Central atom:

Attached groups:

Me (methyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Sm«V³C⁸O^IIIE²¹B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Sm(I)(Thf){η⁵-C₅H₃(SiMe₃)₂}₂]

Formula Unicode styled:

[Sm(I)(Thf){η⁵-C₅H₃(SiMe₃)₂}₂]

Compound name(s):

bis(η⁵-1,3-bis(Trimethylsilyl)-cyclopentadienyl)-iodo-tetrahydrofuran-samarium

Central atom:

Attached groups:

I (iodo)

C₅H₃(SiMe₃)₂ (η⁵-bis(trimethylsilyl)cyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Sm«V³C⁸O^IIIE²¹B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Sm(I)(Thf)(Cp*)₂]

Formula Unicode styled:

[Sm(I)(Thf)(Cp*)₂]

Compound name(s):

Iodo-bis(η⁵-pentamethyl-cyclopentadienyl)-tetrahydrofuran-samarium

Central atom:

Attached groups:

I (iodo)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Sm«V³C⁸O^IIIE²¹B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Sm(Dme){η⁵-C₅H₃(SiMe₃)₂}₂]⊕

Formula Unicode styled:

[Sm(Dme){η⁵-C₅H₃(SiMe₃)₂}₂]⊕

Compound name(s):

bis(η⁵-1,3-bis(Trimethylsilyl)-cyclopentadienyl)-(dimethoxyethane)-samarium(1+)

Central atom:

C₅H₃(SiMe₃)₂ (η⁵-bis(trimethylsilyl)cyclopentadienyl)

Attached groups:

Dme (dimethoxyethane)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Sm«V³C⁸O^IIIE²¹B⁸Z⁰X²L⁶»^⊕

[MLXZ]𝘲 class:

[MX₂L₆]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Sm(Dme)(Cp*)₂]

Formula Unicode styled:

[Sm(Dme)(Cp*)₂]

Compound name(s):

bis(η⁵-Pentamethyl-cyclopentadienyl)-(1,2-dimethoxyethane-O,O')-samarium

Central atom:

Attached groups:

Dme (dimethoxyethane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (II)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 22

Summary of calculated classifications:

Sm«V²C⁸O^IIE²²B⁸Z⁰X²L⁶»

[MLXZ]𝘲 class:

[MX₂L₆]

MLXZ class (ENC, equivalent neutral class):

MX₂L₆

[Sm(Dmdtc)(Cp*)₂]

Formula Unicode styled:

[Sm(Dmdtc)(Cp*)₂]

Compound name(s):

(N,N-Dimethyldithiocarbamato)-bis(η⁵-pentamethyl-cyclopentadienyl)-samarium

Central atom:

Dmdtc (dimethyldithiocarbamato-κ²S)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Sm«V³C⁸O^IIIE²¹B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Sm(Dedtc)(Cp*)₂]

Formula Unicode styled:

[Sm(Dedtc)(Cp*)₂]

Compound name(s):

bis(η⁵-Pentamethylcyclopentadienyl)-(N,N-diethyldithiocarbamato-S,S')-samarium

Central atom:

Dedtc (diethyldithiocarbamato-κ²S)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: