8-coordinate: ③₂-●-2 bent metallocene

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

C₅H₄(SiMe₃) (η⁵-(trimethylsilyl)cyclopentadienyl)

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 29

Summary of calculated classifications:

Yb«V³C⁸O^IIIE²⁹B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Yb(μ₂-Cl){η⁵-C₅H₄(SiMe₃)}₂]₂

Formula Unicode styled:

[Yb(μ₂-Cl){η⁵-C₅H₄(SiMe₃)}₂]₂

Compound name(s):

bis-[(μ₂-Chloro)-(η⁵-trimethylsilyl-cyclopentadienyl))-ytterbium]

Central atom:

Ytterbium

Attached groups:

Cl (μ₂-chloro)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 29

Summary of calculated classifications:

Yb«V³C⁸O^IIIE²⁹B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Y(μ₂-PHPh)(Cp*)₂]₂

Formula Unicode styled:

[Y(μ₂-PHPh)(Cp*)₂]₂

Compound name(s):

bis-[(μ₂-Phenylphosphino)-bis(η⁵-pentamethyl-cyclopentadienyl)-yttrium]

Central atom:

PHPh (μ₂-phenylphosphanyl)

Attached groups:

Cp* (η⁵-pentamethylcyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Y«V³C⁸O^IIIE¹⁶B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Y(Cl)(Thf)(Ind*)₂]

Formula Unicode styled:

[Y(Cl)(Thf)(Ind*)₂]

Compound name(s):

bis(η⁵-1,2,3,4,5,6,7-Heptamethylindenyl)-chloro-(tetrahydrofuran)-yttrium

Central atom:

Attached groups:

Cl (chloro)

Ind* (η⁵-heptamethylindenyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Y«V³C⁸O^IIIE¹⁶B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Y(C≡CPh)(Thf)(Cp)(Tp*-κ³N)]

Formula Unicode styled:

[Y(C≡CPh)(Thf)(Cp)(Tp*-κ³N)]

Compound name(s):

(Hydrogen tris(3,5-dimethylpyrazolyl)borato)-(η⁵-cyclopentadienyl)-(phenylethynyl)-tetrahydrofuran-yttrium

Central atom:

Attached groups:

C≡CPh (phenylethynyl)

Tp* (hydrotris(3,5-dimethylpyrazolyl)borato-κ³N)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Y«V³C⁸O^IIIE¹⁶B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Y(Bz)(Thf)(Cp)(Tp*-κ³N)]

Formula Unicode styled:

[Y(Bz)(Thf)(Cp)(Tp*-κ³N)]

Compound name(s):

(Hydrogen tris(3,5-dimethylpyrazolyl)borato)-(η⁵-cyclopentadienyl)-(benzyl)-tetrahydrofuran-yttrium

Central atom:

Attached groups:

Bz (phenylmethanido-κC)

Tp* (hydrotris(3,5-dimethylpyrazolyl)borato-κ³N)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Y«V³C⁸O^IIIE¹⁶B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Ti(Me)₂(Ind)₂]

Formula Unicode styled:

[Ti(Me)₂(Ind)₂]

Compound name(s):

bis(η⁵-Indenyl)-dimethyl-titanium

Central atom:

Titanium

Attached groups:

Me (methyl)

Ind (η⁵-indenyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ti«V⁴C⁸O^IVE¹⁶B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Ti(CO)₂(Ind)₂]

Formula Unicode styled:

[Ti(CO)₂(Ind)₂]

Compound name(s):

Dicarbonyl-bis(η⁵-indenyl)-titanium

Central atom:

Titanium

Attached groups:

CO (carbonyl)

Ind (η⁵-indenyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (II)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

CH₂SiMe₃ (trimethylsilylmethyl)

Summary of calculated classifications:

Ti«V²C⁸O^IIE¹⁸B⁸Z⁰X²L⁶»

[MLXZ]𝘲 class:

[MX₂L₆]

MLXZ class (ENC, equivalent neutral class):

MX₂L₆

[Ti(Cl)(CH₂SiMe₃)(Cp)(Ind)]

Formula Unicode styled:

[Ti(Cl)(CH₂SiMe₃)(Cp)(Ind)]

Compound name(s):

(η⁵-Cyclopentadienyl)-(η⁵-indenyl)-chloro-(trimethylsilylmethyl)-titanium

Central atom:

Titanium

Attached groups:

Cl (chloro)

Ind (η⁵-indenyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ti«V⁴C⁸O^IVE¹⁶B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Lu(Cl)(Thf)(η⁵-C₅Me₄Prⁱ)₂]

Formula Unicode styled:

[Lu(Cl)(Thf)(η⁵-C₅Me₄Prⁱ)₂]

Compound name(s):

Chloro-bis(η⁵-tetramethyl-isopropyl-cyclopentadienyl)-tetrahydrofuran-lutetium

Central atom:

Lutetium

Attached groups:

Cl (chloro)

C₅Me₄Prⁱ (η⁵-tetramethyl-isopropyl-cyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Lu«V³C⁸O^IIIE¹⁶B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Lu(Me)(Thf)(η⁵-C₅Me₄Prⁱ)₂]

Formula Unicode styled:

[Lu(Me)(Thf)(η⁵-C₅Me₄Prⁱ)₂]

Compound name(s):

Methyl-bis(η⁵-tetramethyl-isopropyl-cyclopentadienyl)-tetrahydrofuran-lutetium

Central atom:

Lutetium

Attached groups:

Me (methyl)

C₅Me₄Prⁱ (η⁵-tetramethyl-isopropyl-cyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

C₅Me₄Buᵗ (η⁵-tetramethyl-t-butyl-cyclopentadienyl)

Summary of calculated classifications:

Lu«V³C⁸O^IIIE¹⁶B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Lu(μ₂-O₂CMe)(η⁵-C₅Me₄Buᵗ)₂]

Formula Unicode styled:

[Lu(μ₂-O₂CMe)(η⁵-C₅Me₄Buᵗ)₂]

Compound name(s):

bis(η5-1-t-Butyl-2,3,4,5-tetramethyl-cyclopentadienyl)-(acetato-O,O')-lutetium

Central atom:

Lutetium

Attached groups:

O₂CMe (μ₂-acetato)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Lu«V³C⁸O^IIIE¹⁶B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[U(SO₃CF₃-κO)₂(η⁵-C₅HPrⁱ₄)₂]

Formula Unicode styled:

[U(SO₃CF₃-κO)₂(η⁵-C₅HPrⁱ₄)₂]

Compound name(s):

bis-trifluoromethanesulfonato-bis(tetraisopropyl-cyclopentadienyl)-uranium

Central atom:

OSO₂CF₃ (trifluoromethanesulfonato-κO)

Attached groups:

C₅HPrⁱ₄ (η⁵-tetraisopropylcyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

U«V⁴C⁸O^IVE¹⁸B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[U(μ₂-NCO-κN,κO)(η⁵-C₅HPrⁱ₄)₂]₄

Formula Unicode styled:

[U(μ₂-NCO-κN,κO)(η⁵-C₅HPrⁱ₄)₂]₄

Compound name(s):

tetra-[isocyanato-bis(tetraisopropyl-cyclopentadienyl)-uranium]

Central atom:

C₅HPrⁱ₄ (η⁵-tetraisopropylcyclopentadienyl)

Attached groups:

NCO (μ₂-cyanato-κN,κO)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 19

Summary of calculated classifications:

U«V³C⁸O^IIIE¹⁹B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[U(PHMes)₂(Cp*)₂]

Formula Unicode styled:

[U(PHMes)₂(Cp*)₂]

Compound name(s):

bis(hydrido(mesityl)phosphide)-bis(pentamethyl-cyclopentadienyl)-uranium

Central atom:

PHMes (mesitylphosphanyl)

Attached groups:

Cp* (η⁵-pentamethylcyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

U«V⁴C⁸O^IVE¹⁸B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[U(N₃)₂(η⁵-C₅HPrⁱ₄)₂]

Formula Unicode styled:

[U(N₃)₂(η⁵-C₅HPrⁱ₄)₂]

Compound name(s):

di-azido-bis(tetraisopropyl-cyclopentadienyl)-uranium

Central atom:

C₅HPrⁱ₄ (η⁵-tetraisopropylcyclopentadienyl)

Attached groups:

N₃ (azido)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

U«V⁴C⁸O^IVE¹⁸B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[U(μ₂-OH){η⁵-C₅H₃(SiMe₃)₂}₂]₂

Formula Unicode styled:

[U(μ₂-OH){η⁵-C₅H₃(SiMe₃)₂}₂]₂

Compound name(s):

bis-[(μ₂-Hydroxo)-bis(η⁵-1,3-di-trimethylsilyl-cyclopentadienyl)-uranium]

Central atom:

C₅H₃(SiMe₃)₂ (η⁵-bis(trimethylsilyl)cyclopentadienyl)

Attached groups:

OH (μ₂-hydroxy)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 19

Summary of calculated classifications:

U«V³C⁸O^IIIE¹⁹B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[U(μ₂–O){η⁵-C₅H₃(SiMe₃)₂}₂]₂

Formula Unicode styled:

[U(μ₂–O){η⁵-C₅H₃(SiMe₃)₂}₂]₂

Compound name(s):

bis-[(μ₂-Oxo)-bis(η⁵-1,3-bis(trimethylsilyl)cyclopentadienyl)-uranium]

Central atom:

C₅H₃(SiMe₃)₂ (η⁵-bis(trimethylsilyl)cyclopentadienyl)

Attached groups:

O (μ₂–oxo X+X)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

U«V⁴C⁸O^IVE¹⁸B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[U(μ₂–O){η⁵-C₅H₃(Buᵗ)₂}₂]₂

Formula Unicode styled:

[U(μ₂–O){η⁵-C₅H₃(Buᵗ)₂}₂]₂

Compound name(s):

bis-[(μ₂-Oxo)-bis(η⁵-1,3-di-t-butyl-cyclopentadienyl)-uranium]

Central atom:

C₅H₃(Buᵗ)₂ (η⁵-bis(t-butyl)cyclopentadienyl)

Attached groups:

O (μ₂–oxo X+X)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

U«V⁴C⁸O^IVE¹⁸B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[U(F)₂{η⁵-C₅H₃(Buᵗ)₂}₂]

Formula Unicode styled:

[U(F)₂{η⁵-C₅H₃(Buᵗ)₂}₂]

Compound name(s):

bis(η⁵-1,3-Di-t-butylcyclopentadienyl)-difluoro-uranium

Central atom:

C₅H₃(Buᵗ)₂ (η⁵-bis(t-butyl)cyclopentadienyl)

Attached groups:

F (fluoro)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: