NSiMe₃ (μ₂-trimethylsilylimino X₂L)

[U(μ₂-NSiMe₃)(η⁵-C₅H₄Me)₂]₂

Formula Unicode styled: 
[U(μ₂-NSiMe₃)(η⁵-C₅H₄Me)₂]₂
Compound name(s): 
bis-[bis(η⁵-Methylcyclopentadienyl)-(μ₂-trimethylsilylimido)-uranium]
Central atom: 
Uranium
Attached groups: 
NSiMe₃ (μ₂-trimethylsilylimino X₂L)
C₅H₄Me (η⁵-methylcyclopentadienyl)
Charge on central atom: 
0
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 8
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 20
Summary of calculated classifications: 
U«V4C8OIVE20B9Z0X4L5»
[MLXZ]𝘲 class: 
[MX4L5]
MLXZ class (ENC, equivalent neutral class): 
MX4L5

[Zr(Cl)₃(μ₂-NSiMe₃)]₂²⊖

Formula Unicode styled: 
[Zr(Cl)₃(μ₂-NSiMe₃)]₂²⊖
Compound name(s): 
bis-[(μ₂-trimethylsilylimido)-trichloro-titanium(1-)]
Central atom: 
Zirconium
Attached groups: 
Cl (chloro)
NSiMe₃ (μ₂-trimethylsilylimino X₂L)
Charge on central atom: 
-1
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 12
Summary of calculated classifications: 
Zr«V4C5OIVE12B6Z0X5L1»⊖
[MLXZ]𝘲 class: 
[MX5L1]-
MLXZ class (ENC, equivalent neutral class): 
MX4L2

[Ta(NMe₂)₃(μ₂-NSiMe₃)]₂

Formula Unicode styled: 
[Ta(NMe₂)₃(μ₂-NSiMe₃)]₂
Compound name(s): 
bis-[(μ₂-(trimethylsilyl)imido)-tris(dimethylamido)-tantalum]
Central atom: 
Tantalum
Attached groups: 
NMe₂ (dimethylamino: planar)
NSiMe₃ (μ₂-trimethylsilylimino X₂L)
Charge on central atom: 
0
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 5
Oxidation Number (ON) (Roman numerals): 
ON: (V)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Ta«V5C5OVE18B9Z0X5L4»
[MLXZ]𝘲 class: 
[MX5L4]
MLXZ class (ENC, equivalent neutral class): 
MX5L4

[Ta(Cl){N(SiMe₃)₂}(μ₂-NSiMe₃)]₂

Formula Unicode styled: 
[Ta(Cl){N(SiMe₃)₂}(μ₂-NSiMe₃)]₂
Compound name(s): 
bis-[(μ₂-Trimethylsilylamido)-chloro-(bis(trimethylsilyl)amido)-tantalum(Ta—Ta)]
Central atom: 
Tantalum
Attached groups: 
Cl (chloro)
N(SiMe₃)₂ (bis(trimethylsilyl)amino: planar)
NSiMe₃ (μ₂-trimethylsilylimino X₂L)
Charge on central atom: 
0
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 5
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 14
Summary of calculated classifications: 
Ta«V5C5OIVE14B7Z0X5L2»
[MLXZ]𝘲 class: 
[MX5L2]
MLXZ class (ENC, equivalent neutral class): 
MX5L2

[Cr(=NSiMe₃)(μ₂-NSiMe₃)(Cp)]₂

Formula Unicode styled: 
[Cr(=NSiMe₃)(μ₂-NSiMe₃)(Cp)]₂
Compound name(s): 
bis-[(μ₂-Trimethylsilylimido)-(η⁵-cyclopentadienyl)-trimethylsilylimido-chromium(Cr—Cr)]
Central atom: 
Chromium
Attached groups: 
=NSiMe₃ (trimethylsilylimino)
NSiMe₃ (μ₂-trimethylsilylimino X₂L)
Cp (η⁵-cyclopentadienyl)
Charge on central atom: 
0
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 6
Oxidation Number (ON) (Roman numerals): 
ON: (V)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Cr«V6C7OVE18B9Z0X6L3»
[MLXZ]𝘲 class: 
[MX6L3]
MLXZ class (ENC, equivalent neutral class): 
MX6L3