5-coordinate: trigonal bipyramid (TBPY-5)

NEt₂ (diethylamino: planar)

Attached groups:

I (iodo)

I (μ₂-iodo)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 14

Summary of calculated classifications:

Zr«V⁴C⁵O^IVE¹⁴B⁷Z⁰X⁴L³»

[MLXZ]𝘲 class:

[MX₄L₃]

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

[Zr(Cl)₃(μ₂-NSiMe₃)]₂²⊖

Formula Unicode styled:

[Zr(Cl)₃(μ₂-NSiMe₃)]₂²⊖

Compound name(s):

bis-[(μ₂-trimethylsilylimido)-trichloro-titanium(1-)]

Central atom:

Attached groups:

NSiMe₃ (μ₂-trimethylsilylimino X₂L)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 12

Summary of calculated classifications:

Zr«V⁴C⁵O^IVE¹²B⁶Z⁰X⁵L¹»^⊖

[MLXZ]𝘲 class:

[MX₅L₁]^-

MLXZ class (ENC, equivalent neutral class):

MX₄L₂

[Zr(Cl)(NMe₂)(μ₂-NMe₂)₂]₂

Formula Unicode styled:

[Zr(Cl)(NMe₂)(μ₂-NMe₂)₂]₂

Compound name(s):

bis-[(μ₂-Dimethylamido)-chloro-dimethylamido-zirconium]

Central atom:

Attached groups:

NMe₂ (dimethylamino)

NMe₂ (μ₂-dimethylamino)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

NBuᵗ (μ₂-t-butylimino X₂L)

Coordination Number (CN, sum of attached group denticities):

CN: 6

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 12

Summary of calculated classifications:

Zr«V⁴C⁶O^IVE¹²B⁶Z⁰X⁴L²»

[MLXZ]𝘲 class:

[MX₄L₂]

MLXZ class (ENC, equivalent neutral class):

MX₄L₂

[W(Me)₂(⭀NBuᵗ)(μ₂-NBuᵗ)]₂

Formula Unicode styled:

[W(Me)₂(⭀NBuᵗ)(μ₂-NBuᵗ)]₂

Compound name(s):

bis-[(μ₂-t-Butylimido)-(t-butylimido)-dimethyl-tungsten]

Central atom:

Tungsten

Attached groups:

Me (methyl)

⭀NBuᵗ (⭀N t-butylimino)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (VI)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Summary of calculated classifications:

W«V⁶C⁵O^VIE¹⁶B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[V(OPrⁱ)₃(μ₂-OPrⁱ)]₂

Formula Unicode styled:

[V(OPrⁱ)₃(μ₂-OPrⁱ)]₂

Compound name(s):

bis-[(μ₂-Isopropoxo)-tris(isopropoxy)-vanadium]

Central atom:

Vanadium

Attached groups:

OPrⁱ (isopropoxy)

OPrⁱ (μ₂-isopropoxy)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 11

Summary of calculated classifications:

V«V⁴C⁵O^IVE¹¹B⁵Z⁰X⁴L¹»

[MLXZ]𝘲 class:

[MX₄L₁]

MLXZ class (ENC, equivalent neutral class):

MX₄L₁

[V(Cl)(⭀NPh)₂(PMe₃)₂]

Formula Unicode styled:

[V(Cl)(⭀NPh)₂(PMe₃)₂]

Compound name(s):

chloro-bis(phenylimino)-bis(trimethylphosphine)-vanadium

Central atom:

Vanadium

Attached groups:

PMe₃ (trimethylphosphane)

⭀NPh (phenylimino)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 5

Oxidation Number (ON) (Roman numerals):

ON: (V)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 18

Summary of calculated classifications:

V«V⁵C⁵O^VE¹⁸B⁹Z⁰X⁵L⁴»

[MLXZ]𝘲 class:

[MX₅L₄]

MLXZ class (ENC, equivalent neutral class):

MX₅L₄

catena–1D-trans–[Zr(μ₂-Cl)(CH₂Buᵗ)₃]

Formula Unicode styled:

catena–1D-trans–[Zr(μ₂-Cl)(CH₂Buᵗ)₃]

Compound name(s):

catena-[(μ₂-Chloro)-tris(neopentyl)-zirconium]

Central atom:

Attached groups:

Cl (μ₂-chloro)

CH₂Buᵗ (t-butylmethyl)

Charge on central atom:

0

Compound type:

Catena-1D

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Zr«V⁴C⁵O^IVE¹⁰B⁵Z⁰X⁴L¹»

[MLXZ]𝘲 class:

[MX₄L₁]

MLXZ class (ENC, equivalent neutral class):

MX₄L₁

trans–[Hf(Cl)₂(C₆Cl₅)₃]⊖

Formula Unicode styled:

trans–[Hf(Cl)₂(C₆Cl₅)₃]⊖

Compound name(s):

dichloro-tris(pentachlorophenyl)-hafnium(1-)

Central atom:

Hafnium

Attached groups:

C₆Cl₅ (pentachlorophenyl)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Hf«V⁴C⁵O^IVE¹⁰B⁵Z⁰L⁰X⁵»^⊖

[MLXZ]𝘲 class:

[MX₅]^-

MLXZ class (ENC, equivalent neutral class):

MX₄L₁

[Ti(Cl)₂(OPh)(μ₂-OPh)]₂

Formula Unicode styled:

[Ti(Cl)₂(OPh)(μ₂-OPh)]₂

Compound name(s):

bis-[Dichloro-diphenoxy-titanium]

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ti«V⁴C⁵O^IVE¹⁰B⁵Z⁰X⁴L¹»

[MLXZ]𝘲 class:

[MX₄L₁]

MLXZ class (ENC, equivalent neutral class):

MX₄L₁

[Ti(Cl)₂(OEt)(μ₂-OEt)]₂

Formula Unicode styled:

[Ti(Cl)₂(OEt)(μ₂-OEt)]₂

Compound name(s):

bis-[(μ₂-Ethoxo)-dichloro-ethoxy-titanium]

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

NMe₂ (dimethylamino: planar)

Summary of calculated classifications:

Ti«V⁴C⁵O^IVE¹⁰B⁵Z⁰X⁴L¹»

[MLXZ]𝘲 class:

[MX₄L₁]

MLXZ class (ENC, equivalent neutral class):

MX₄L₁

[Ta(NMe₂)₃(μ₂-NSiMe₃)]₂

Formula Unicode styled:

[Ta(NMe₂)₃(μ₂-NSiMe₃)]₂

Compound name(s):

bis-[(μ₂-(trimethylsilyl)imido)-tris(dimethylamido)-tantalum]

Central atom:

Tantalum

Attached groups:

NSiMe₃ (μ₂-trimethylsilylimino X₂L)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 5

Oxidation Number (ON) (Roman numerals):

ON: (V)

Coordination Number (CN, sum of attached group denticities):

N(SiMe₃)₂ (bis(trimethylsilyl)amino: planar)

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 18

Summary of calculated classifications:

Ta«V⁵C⁵O^VE¹⁸B⁹Z⁰X⁵L⁴»

[MLXZ]𝘲 class:

[MX₅L₄]

MLXZ class (ENC, equivalent neutral class):

MX₅L₄

[Ta(Br)(μ₂-Br){N(SiMe₃)₂}₂]₂

Formula Unicode styled:

[Ta(Br)(μ₂-Br){N(SiMe₃)₂}₂]₂

Compound name(s):

bis-[(μ₂-bromo)-bromo-bis(trimethylsilylimido)-tantalum]

Central atom:

Tantalum

Attached groups:

Br (bromo)

Br (μ₂-bromo)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 15

Summary of calculated classifications:

Ta«V⁴C⁵O^IVE¹⁵B⁷Z⁰X⁴L³»

[MLXZ]𝘲 class:

[MX₄L₃]

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

[Mo(OPrⁱ)₂(NO)(μ₂-OPrⁱ)]₂

Formula Unicode styled:

[Mo(OPrⁱ)₂(NO)(μ₂-OPrⁱ)]₂

Compound name(s):

bis-[(μ₂-isopropoxy)-nitrosyl-bis(isopropoxy)-molybdenum]

Central atom:

Molybdenum

Attached groups:

OPrⁱ (isopropoxy)

NO (nitrosyl, linear)

OPrⁱ (μ₂-isopropoxy)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

NBuᵗ (μ₂-t-butylimino X₂L)

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 14

Summary of calculated classifications:

Mo«V⁶C⁵O^IIE¹⁴B⁷X⁴L²Z¹»

[MLXZ]𝘲 class:

[MX₄L₂Z₁]

MLXZ class (ENC, equivalent neutral class):

MX₆L₁

[Mo(Me)₂(⭀NBuᵗ)(μ₂-NBuᵗ)]₂

Formula Unicode styled:

[Mo(Me)₂(⭀NBuᵗ)(μ₂-NBuᵗ)]₂

Compound name(s):

bis-[(μ-N-t-Butylimido)-(N-t-butylimido))-dimethyl-molybdenum]

Central atom:

Molybdenum

Attached groups:

Me (methyl)

⭀NBuᵗ (⭀N t-butylimino)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (VI)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Summary of calculated classifications:

Mo«V⁶C⁵O^VIE¹⁶B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[Cr(Cl)(μ₂-N₃)(⭀NBuᵗ)₂]₂

Formula Unicode styled:

[Cr(Cl)(μ₂-N₃)(⭀NBuᵗ)₂]₂

Compound name(s):

bis-[(μ₂-Azido)-bis(t-butylimido)-chloro-chromium]

Central atom:

Chromium

Attached groups:

N₃ (μ₂-azido)

⭀NBuᵗ (⭀N t-butylimino)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (VI)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 18

Summary of calculated classifications:

Cr«V⁶C⁵O^VIE¹⁸B⁹Z⁰X⁶L³»

[MLXZ]𝘲 class:

[MX₆L₃]

MLXZ class (ENC, equivalent neutral class):

MX₆L₃

[Sr{Si(SiMe₃)₃}₂(Thf)₃]

Formula Unicode styled:

[Sr{Si(SiMe₃)₃}₂(Thf)₃]

Compound name(s):

tris(tetrahydrofuran)-bis(tris(trimethylsilyl)silyl)-strontium

Central atom:

Si(SiMe₃)₃ (tris-trimethylsilyl-silyl)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Sr«V²C⁵O^IIE¹⁰B⁵Z⁰X²L³»

[MLXZ]𝘲 class:

[MX₂L₃]

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

[Sr{Si(SiMe₃)₃}₂(Thf)(TMEDA-κ²N)]

Formula Unicode styled:

[Sr{Si(SiMe₃)₃}₂(Thf)(TMEDA-κ²N)]

Compound name(s):

(tetrahydrofuran)-(N,N,N',N'-tetramethylethylenediamine)-bis(tris(trimethylsilyl))-strontium

Central atom:

Si(SiMe₃)₃ (tris-trimethylsilyl-silyl)

Attached groups:

TMEDA (tetramethylethylenediamine-κ²N)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Sr«V²C⁵O^IIE¹⁰B⁵Z⁰X²L³»

[MLXZ]𝘲 class:

[MX₂L₃]

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

[Sr{Ge(SiMe₃)₃}₂(Thf)₃]

Formula Unicode styled:

[Sr{Ge(SiMe₃)₃}₂(Thf)₃]

Compound name(s):

bis(tris(Trimethylsilyl)germyl)-tris(tetrahydrofuran)-strontium

Central atom:

Ge(SiMe₃)₃ (tris(trimethylsilyl)germyl)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Sr«V²C⁵O^IIE¹⁰B⁵Z⁰X²L³»

[MLXZ]𝘲 class:

[MX₂L₃]

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

[Sr{CH(SiMe₃)₂}₂(Thf)₃]

Formula Unicode styled:

[Sr{CH(SiMe₃)₂}₂(Thf)₃]

Compound name(s):

bis(bis(Trimethylsilyl)methyl)-tris(tetrahydrofuran)-strontium

Central atom:

CH(SiMe₃)₂ (bistrimethylsilylmethyl)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Sr«V²C⁵O^IIE¹⁰B⁵Z⁰X²L³»

[MLXZ]𝘲 class:

[MX₂L₃]

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

[Sr(OC₆H₃Ph₂-2,6)₂(Thf)₃]

Formula Unicode styled:

[Sr(OC₆H₃Ph₂-2,6)₂(Thf)₃]

Compound name(s):

bis-(2,6-diphenylphenolato-O)-tris(tetrahydrofuran)-strontium

Central atom:

OC₆H₃Ph₂-2,6 (diphenylphenoxy-2,6)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: