5-coordinate: trigonal bipyramid (TBPY-5)

Attached groups:

Cl (chloro)

SbPh₃ (triphenylstibane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V¹C⁵O^IE¹⁸B⁵Z⁰X¹L⁴»

[MLXZ]𝘲 class:

[MX₁L₄]

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

[Rh(Cl)(C₂H₄)(PMe₃)₂]

Formula Unicode styled:

[Rh(Cl)(C₂H₄)(PMe₃)₂]

Compound name(s):

Chloro-bis(η²-ethylene)-bis(trimethylphosphine)-rhodium

Central atom:

Attached groups:

Cl (chloro)

PMe₃ (trimethylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 4

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Summary of calculated classifications:

Rh«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

[Rh(CF₃)(O₂)(CNXy)₂(PPh₃)]

Formula Unicode styled:

[Rh(CF₃)(O₂)(CNXy)₂(PPh₃)]

Compound name(s):

bis(2,6-dimethylphenylisocyano)-(peroxo)-(trifluoromethyl)-(triphenylphosphine)-rhodium

Central atom:

Attached groups:

CF₃ (trifluoromethyl)

O₂ (peroxo)

CNXy (xylyl isocyanide)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 3

Oxidation Number (ON) (Roman numerals):

ON: (III)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V³C⁵O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Rh(C₆F₅)₅]²⊖

Formula Unicode styled:

[Rh(C₆F₅)₅]²⊖

Compound name(s):

pentakis(pentafluorophenyl)-rhodium(2-)

Central atom:

Attached groups:

C₆F₅ (pentafluorophenyl)

Charge on central atom:

-2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 3

Oxidation Number (ON) (Roman numerals):

ON: (III)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Summary of calculated classifications:

Rh«V³C⁵O^IIIE¹⁶B⁵Z⁰L⁰X⁵»^2⊖

[MLXZ]𝘲 class:

[MX₅]^2-

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Rh(C₂H₄)₂([9]aneS₃-κ³S)]⊕

Formula Unicode styled:

[Rh(C₂H₄)₂([9]aneS₃-κ³S)]⊕

Compound name(s):

bis(η²-Ethylene)-(1,4,7-trithiacyclononane)-rhodium(1+)

Central atom:

Attached groups:

[9]aneS₃ (1,4,7-trithiocyclononane-κ³S)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V¹C⁵O^IE¹⁸B⁵Z⁰X⁰L⁵»^⊕

[MLXZ]𝘲 class:

[ML₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

[Rh(C₂H₄)(PEt₃)(Tp*-κ³N)]

Formula Unicode styled:

[Rh(C₂H₄)(PEt₃)(Tp*-κ³N)]

Compound name(s):

(η²-Ethene)-(hydrogen-tris(3,5-dimethylpyrazolyl)borate)-(triethylphosphine)-rhodium

Central atom:

Attached groups:

Tp* (hydrotris(3,5-dimethylpyrazolyl)borato-κ³N)

PEt₃ (triethylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V¹C⁵O^IE¹⁸B⁵Z⁰X¹L⁴»

[MLXZ]𝘲 class:

[MX₁L₄]

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

[Rh(C₂H₄)(CNXy)(Tp*-κ³N)]

Formula Unicode styled:

[Rh(C₂H₄)(CNXy)(Tp*-κ³N)]

Compound name(s):

(Ethylene)-(hydrogen tris(3,5-dimethylpyrazolyl)borato)-(2,6-dimethylphenylisocyanide)-rhodium

Central atom:

Attached groups:

Tp* (hydrotris(3,5-dimethylpyrazolyl)borato-κ³N)

CNXy (xylyl isocyanide)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V¹C⁵O^IE¹⁸B⁵Z⁰X¹L⁴»

[MLXZ]𝘲 class:

[MX₁L₄]

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

[Rh(C≡CPh)(PPh₃)₂(η⁴-Nbd)]

Formula Unicode styled:

[Rh(C≡CPh)(PPh₃)₂(η⁴-Nbd)]

Compound name(s):

(η⁴--2,5-Norbornadiene)-phenylacetylene-bis(triphenylphosphine)-rhodium

Central atom:

Attached groups:

C≡CPh (phenylethynyl)

Nbd (η⁴-norbornadiene)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V¹C⁵O^IE¹⁸B⁵Z⁰X¹L⁴»

[MLXZ]𝘲 class:

[MX₁L₄]

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

[Rh(C≡CPh)(PMe₃)₄]

Formula Unicode styled:

[Rh(C≡CPh)(PMe₃)₄]

Compound name(s):

(2-Phenylethynyl)-tetrakis(trimethylphosphine)-rhodium

Central atom:

PMe₃ (trimethylphosphane)

Attached groups:

C≡CPh (phenylethynyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V¹C⁵O^IE¹⁸B⁵Z⁰X¹L⁴»

[MLXZ]𝘲 class:

[MX₁L₄]

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

[Rh(C≡CPh)(NCMe)(PPh₃)₂(Tcne)]

Formula Unicode styled:

[Rh(C≡CPh)(NCMe)(PPh₃)₂(Tcne)]

Compound name(s):

Acetonitrile-(η²-tetracyanoethylene)-(2-phenylacetylide)-bis-(triphenylphosphine)-rhodium

Central atom:

Attached groups:

C≡CPh (phenylethynyl)

NCMe (acetonitrile)

Tcne (tetracyanoethene)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V¹C⁵O^IE¹⁸B⁵Z⁰X¹L⁴»

[MLXZ]𝘲 class:

[MX₁L₄]

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

equatorial–[Rh(O₂)(AsMe₂Ph)₄]⊕

Formula Unicode styled:

equatorial–[Rh(O₂)(AsMe₂Ph)₄]⊕

Compound name(s):

Dioxygen-tetra(dimethylphenylarsine) rhodium(1+)

Central atom:

AsMe₂Ph (dimethylphenylarsane)

Attached groups:

O₂ (peroxo)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 3

Oxidation Number (ON) (Roman numerals):

ON: (III)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V³C⁵O^IIIE¹⁸B⁶Z⁰X²L⁴»^⊕

[MLXZ]𝘲 class:

[MX₂L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

equatorial–[Rh(I)(CO)(SbPh₃)₃]

Formula Unicode styled:

equatorial–[Rh(I)(CO)(SbPh₃)₃]

Compound name(s):

Carbonyl-iodo-tris(triphenylstibine-kappaSb)-rhodium

Central atom:

Attached groups:

I (iodo)

SbPh₃ (triphenylstibane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V¹C⁵O^IE¹⁸B⁵Z⁰X¹L⁴»

[MLXZ]𝘲 class:

[MX₁L₄]

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

equatorial–[Rh(H)(PF₃)(PPh₃)₃]

Formula Unicode styled:

equatorial–[Rh(H)(PF₃)(PPh₃)₃]

Compound name(s):

tris(Triphenylphosphine)(trifluorophosphine)-hydrido-rhodium

Central atom:

Attached groups:

PF₃ (trifluorophosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V¹C⁵O^IE¹⁸B⁵Z⁰X¹L⁴»

[MLXZ]𝘲 class:

[MX₁L₄]

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

equatorial–[Rh(H)(CO)(PPh₃)₃]

Formula Unicode styled:

equatorial–[Rh(H)(CO)(PPh₃)₃]

Compound name(s):

tris(Triphenylphosphine)-carbonyl-hydrido-rhodium

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V¹C⁵O^IE¹⁸B⁵Z⁰X¹L⁴»

[MLXZ]𝘲 class:

[MX₁L₄]

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

equatorial–[Rh(COMe)(CO)(SbPh₃)₃]

Formula Unicode styled:

equatorial–[Rh(COMe)(CO)(SbPh₃)₃]

Compound name(s):

Acetyl-carbonyl-tris(triphenyl-antimony)-rhodium

Central atom:

Attached groups:

COMe (acetyl)

SbPh₃ (triphenylstibane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V¹C⁵O^IE¹⁸B⁵Z⁰X¹L⁴»

[MLXZ]𝘲 class:

[MX₁L₄]

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

equatorial–[Rh(CO)(Dppm-κ²P)₂]⊕

Formula Unicode styled:

equatorial–[Rh(CO)(Dppm-κ²P)₂]⊕

Compound name(s):

bis(bis(Diphenylphosphino)methane)-carbonyl-rhodium(1+)

Central atom:

Attached groups:

Dppm (bis-(diphenylphosphino)methane-κ²P)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V¹C⁵O^IE¹⁸B⁵Z⁰X⁰L⁵»^⊕

[MLXZ]𝘲 class:

[ML₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

equatorial–[Rh(Cl)(OPPh₃)₄]

Formula Unicode styled:

equatorial–[Rh(Cl)(OPPh₃)₄]

Compound name(s):

Chloro-tetrakis(diphenylphosphine oxide)-rhodium

Central atom:

OPPh₃ (triphenylphosphane oxide)

Attached groups:

Cl (chloro)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V¹C⁵O^IE¹⁸B⁵Z⁰X¹L⁴»

[MLXZ]𝘲 class:

[MX₁L₄]

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

axial–[Rh(H)(PMePh₂)₄]

Formula Unicode styled:

axial–[Rh(H)(PMePh₂)₄]

Compound name(s):

tetrakis(Diphenylmethylphosphine)-hydrido-rhodium

Central atom:

Attached groups:

PMePh₂ (methyldiphenylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V¹C⁵O^IE¹⁸B⁵Z⁰X¹L⁴»

[MLXZ]𝘲 class:

[MX₁L₄]

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

axial–[Rh(H)(PMe₂Ph)₄]

Formula Unicode styled:

axial–[Rh(H)(PMe₂Ph)₄]

Compound name(s):

tetrakis(Dimethylphenylphosphine)-hydrido-rhodium

Central atom:

Attached groups:

PMe₂Ph (dimethylphenylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V¹C⁵O^IE¹⁸B⁵Z⁰X¹L⁴»

[MLXZ]𝘲 class:

[MX₁L₄]

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

trans–[Ru(CO)₃(PPh₃)₂]

Formula Unicode styled:

trans–[Ru(CO)₃(PPh₃)₂]

Compound name(s):

Tricarbonyl-bis(triphenylphosphine)-ruthenium

Central atom:

Ruthenium

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 0

Oxidation Number (ON) (Roman numerals):

ON: (O)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: