5-coordinate: trigonal bipyramid (TBPY-5)

[Nd(OC₆H₃Ph₂-2,6)₃(Py)₂]

Formula Unicode styled: 
[Nd(OC₆H₃Ph₂-2,6)₃(Py)₂]
Compound name(s): 
tris(2,6-diphenylphenolato)-bis(pyridine)-neodymium
Central atom: 
Neodymium
Attached groups: 
OC₆H₃Ph₂-2,6 (diphenylphenoxy-2,6)
Py (pyridine)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 13
Summary of calculated classifications: 
Nd«V3C5OIIIE13B5Z0X3L2»
[MLXZ]𝘲 class: 
[MX3L2]
MLXZ class (ENC, equivalent neutral class): 
MX3L2

[Ce(μ₂-Cl)(Thf){N(SiMe₃)₂}₂]₂

Formula Unicode styled: 
[Ce(μ₂-Cl)(Thf){N(SiMe₃)₂}₂]₂
Compound name(s): 
bis-[(μ₂-Chloro)-bis(bis(trimethylsilyl)amido)-(tetrahydrofuran)-cerium]
Central atom: 
Cerium
Attached groups: 
Cl (μ₂-chloro)
Thf (tetrahydrofuran)
N(SiMe₃)₂ (bis(trimethylsilyl)amino: planar)
Charge on central atom: 
0
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 15
Summary of calculated classifications: 
Ce«V3C5OIIIE15B7Z0X3L4»
[MLXZ]𝘲 class: 
[MX3L4]
MLXZ class (ENC, equivalent neutral class): 
MX3L4

[Pd(I)(μ₂-I)(Dppm-κ²P)]₂

Formula Unicode styled: 
[Pd(I)(μ₂-I)(Dppm-κ²P)]₂
Compound name(s): 
bis-[(μ₂-bis(Dimethylphosphino)methane)-(μ₂-iodo)-iodo-palladium]
Central atom: 
Palladium
Attached groups: 
I (iodo)
I (μ₂-iodo)
Dppm (bis-(diphenylphosphino)methane-κ²P)
Charge on central atom: 
0
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Pd«V2C5OIIE18B5Z0X2L3»
[MLXZ]𝘲 class: 
[MX2L3]
MLXZ class (ENC, equivalent neutral class): 
MX2L3

trans–[Rh(I)(CO)₂(PPh₃)₂]

Formula Unicode styled: 
trans–[Rh(I)(CO)₂(PPh₃)₂]
Compound name(s): 
Dicarbonyl-iodo-bis(triphenylphosphine)-rhodium
Central atom: 
Rhodium
Attached groups: 
I (iodo)
CO (carbonyl)
PPh₃ (triphenylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 1
Oxidation Number (ON) (Roman numerals): 
ON: (I)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V1C5OIE18B5Z0X1L4»
[MLXZ]𝘲 class: 
[MX1L4]
MLXZ class (ENC, equivalent neutral class): 
MX1L4

trans–[Rh(H)(I){Si(OEt)₃}(PPh₃)₂]

Formula Unicode styled: 
trans–[Rh(H)(I){Si(OEt)₃}(PPh₃)₂]
Compound name(s): 
Hydrido-iodo-triethoxysilyl-bis(triphenylphosphine)-rhodium
Central atom: 
Rhodium
Attached groups: 
H (hydrido)
I (iodo)
Si(OEt)₃ (tri-ethoxy-silyl)
PPh₃ (triphenylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 16
Summary of calculated classifications: 
Rh«V3C5OIIIE16B5Z0X3L2»
[MLXZ]𝘲 class: 
[MX3L2]
MLXZ class (ENC, equivalent neutral class): 
MX3L2

trans–[Rh(CO)₃(PPh₃)₂]⊕

Formula Unicode styled: 
trans–[Rh(CO)₃(PPh₃)₂]⊕
Compound name(s): 
Tricarbonyl-bis(triphenylphosphine)-rhodium(1+)
Central atom: 
Rhodium
Attached groups: 
CO (carbonyl)
PPh₃ (triphenylphosphane)
Charge on central atom: 
1
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 1
Oxidation Number (ON) (Roman numerals): 
ON: (I)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V1C5OIE18B5Z0X0L5»⊕
[MLXZ]𝘲 class: 
[ML5]+
MLXZ class (ENC, equivalent neutral class): 
MX1L4

[Rh(η⁴-Nbd)(Tp*-κ³N)]

Formula Unicode styled: 
[Rh(η⁴-Nbd)(Tp*-κ³N)]
Compound name(s): 
(hydrogen-tris(3,5-dimethylpyrazolyl)borate-N,N',N'')-(η²,η²-norbornadiene)-rhodium
Central atom: 
Rhodium
Attached groups: 
Nbd (η⁴-norbornadiene)
Tp* (hydrotris(3,5-dimethylpyrazolyl)borato-κ³N)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 1
Oxidation Number (ON) (Roman numerals): 
ON: (I)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V1C5OIE18B5Z0X1L4»
[MLXZ]𝘲 class: 
[MX1L4]
MLXZ class (ENC, equivalent neutral class): 
MX1L4

[Rh(SPh)(PMe₃)₃]

Formula Unicode styled: 
[Rh(SPh)(PMe₃)₃]
Compound name(s): 
tris(trimethylphosphino)-(phenylthiolato)-rhodium
Central atom: 
Rhodium
Attached groups: 
SPh (phenylthio)
PMe₃ (trimethylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 1
Oxidation Number (ON) (Roman numerals): 
ON: (I)
Coordination Number (CN, sum of attached group denticities): 
CN: 4
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 16
Summary of calculated classifications: 
Rh«V1C4OIE16B4Z0X1L3»
[MLXZ]𝘲 class: 
[MX1L3]
MLXZ class (ENC, equivalent neutral class): 
MX1L3

[Rh(PMe₃)₅]⊕

Formula Unicode styled: 
[Rh(PMe₃)₅]⊕
Compound name(s): 
pentakis(Trimethylphosphine)-rhodium(1+)
Central atom: 
Rhodium
Attached groups: 
PMe₃ (trimethylphosphane)
Charge on central atom: 
1
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 1
Oxidation Number (ON) (Roman numerals): 
ON: (I)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V1C5OIE18B5Z0X0L5»⊕
[MLXZ]𝘲 class: 
[ML5]+
MLXZ class (ENC, equivalent neutral class): 
MX1L4

[Rh(O₂)(PMe₃)₂(Tp*-κ²N]

Formula Unicode styled: 
[Rh(O₂)(PMe₃)₂(Tp*-κ²N]
Compound name(s): 
(Hydrotris(3,5-dimethylpyrazolyl)borato-N,N')-(peroxo)-bis(trimethylphosphine)-rhodium
Central atom: 
Rhodium
Attached groups: 
O₂ (peroxo)
PMe₃ (trimethylphosphane)
Tp* (hydrotris(3,5-dimethylpyrazolyl)borato-κ²N)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V3C5OIIIE18B6Z0X3L3»
[MLXZ]𝘲 class: 
[MX3L3]
MLXZ class (ENC, equivalent neutral class): 
MX3L3

[Rh(O₂)(PMe₂Ph)₄]⊕

Formula Unicode styled: 
[Rh(O₂)(PMe₂Ph)₄]⊕
Compound name(s): 
Dioxygen-tetra(dimethylphenylphosphine)-rhodium(1+)
Central atom: 
Rhodium
Attached groups: 
O₂ (peroxo)
PMe₂Ph (dimethylphenylphosphane)
Charge on central atom: 
1
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V3C5OIIIE18B6Z0X2L4»⊕
[MLXZ]𝘲 class: 
[MX2L4]+
MLXZ class (ENC, equivalent neutral class): 
MX3L3

[Rh(O₂)(PEt₃)(Tp*-κ³N)]

Formula Unicode styled: 
[Rh(O₂)(PEt₃)(Tp*-κ³N)]
Compound name(s): 
(Hydrogen-tris(3,5-dimethylpyrazolyl)borate)-(peroxo-O,O')-(triethylphosphine)-rhodium
Central atom: 
Rhodium
Attached groups: 
O₂ (peroxo)
PEt₃ (triethylphosphane)
Tp* (hydrotris(3,5-dimethylpyrazolyl)borato-κ³N)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V3C5OIIIE18B6Z0X3L3»
[MLXZ]𝘲 class: 
[MX3L3]
MLXZ class (ENC, equivalent neutral class): 
MX3L3

[Rh(COPh)(Cl)(H)(PPrⁱ₃)₂]

Formula Unicode styled: 
[Rh(COPh)(Cl)(H)(PPrⁱ₃)₂]
Compound name(s): 
Benzoyl-chloro-hydrido-bis(tri-isopropylphosphine)-rhodium
Central atom: 
Rhodium
Attached groups: 
COPh (benzoyl)
Cl (chloro)
H (hydrido)
PPrⁱ₃ (triisopropylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 16
Summary of calculated classifications: 
Rh«V3C5OIIIE16B5Z0X3L2»
[MLXZ]𝘲 class: 
[MX3L2]
MLXZ class (ENC, equivalent neutral class): 
MX3L2

[Rh(CO)₃{P(c-C₅H₉)₃}]₂

Formula Unicode styled: 
[Rh(CO)₃{P(c-C₅H₉)₃}]₂
Compound name(s): 
bis-[tricarbonyl-(tricyclopentylphosphine)-rhodium]
Central atom: 
Rhodium
Attached groups: 
CO (carbonyl)
P(c-C₅H₉)₃ (tricyclopentylphosphane)
Charge on central atom: 
0
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 1
Oxidation Number (ON) (Roman numerals): 
ON: (O)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V1C5OOE18B5Z0X1L4»
[MLXZ]𝘲 class: 
[MX1L4]
MLXZ class (ENC, equivalent neutral class): 
MX1L4

[Rh(CO)₃(PPrⁱ₃)]₂

Formula Unicode styled: 
[Rh(CO)₃(PPrⁱ₃)]₂
Compound name(s): 
bis-[tricarbonyl-(tri-isopropylphosphine)-rhodium]
Central atom: 
Rhodium
Attached groups: 
CO (carbonyl)
PPrⁱ₃ (triisopropylphosphane)
Charge on central atom: 
0
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 1
Oxidation Number (ON) (Roman numerals): 
ON: (O)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V1C5OOE18B5Z0X1L4»
[MLXZ]𝘲 class: 
[MX1L4]
MLXZ class (ENC, equivalent neutral class): 
MX1L4

[Rh(CO)₂([9]aneN₃-1,4,7-Me₃-κ³N)]⊕

Formula Unicode styled: 
[Rh(CO)₂([9]aneN₃-1,4,7-Me₃-κ³N)]⊕
Compound name(s): 
Dicarbonyl-(1,4,7-trimethyl-1,4,7-triazacyclononane)-rhodium(1+)
Central atom: 
Rhodium
Attached groups: 
CO (carbonyl)
[9]aneN₃-1,4,7-Me₃ (1,4,7-trimethyl-1,4,7-triazacyclononane-κ³N)
Charge on central atom: 
1
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 1
Oxidation Number (ON) (Roman numerals): 
ON: (I)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V1C5OIE18B5Z0X0L5»⊕
[MLXZ]𝘲 class: 
[ML5]+
MLXZ class (ENC, equivalent neutral class): 
MX1L4

[Rh(CO)(PPh₃)([9]aneS₃-κ³S)]⊕

Formula Unicode styled: 
[Rh(CO)(PPh₃)([9]aneS₃-κ³S)]⊕
Compound name(s): 
Carbonyl-triphenylphosphine-(1,4,7-trithiacyclononane)-rhodium(1+)
Central atom: 
Rhodium
Attached groups: 
CO (carbonyl)
PPh₃ (triphenylphosphane)
[9]aneS₃ (1,4,7-trithiocyclononane-κ³S)
Charge on central atom: 
1
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 1
Oxidation Number (ON) (Roman numerals): 
ON: (I)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V1C5OIE18B5Z0X0L5»⊕
[MLXZ]𝘲 class: 
[ML5]+
MLXZ class (ENC, equivalent neutral class): 
MX1L4

[Rh(Cl)(O₂)(PPh₃)₃]

Formula Unicode styled: 
[Rh(Cl)(O₂)(PPh₃)₃]
Compound name(s): 
Chloro(dioxygen)tris(triphenylphosphine)-rhodium
Central atom: 
Rhodium
Attached groups: 
Cl (chloro)
O₂ (dioxygen)
PPh₃ (triphenylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 1
Oxidation Number (ON) (Roman numerals): 
ON: (I)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V1C5OIE18B5Z0X1L4»
[MLXZ]𝘲 class: 
[MX1L4]
MLXZ class (ENC, equivalent neutral class): 
MX1L4

[Rh(μ₂-Cl)(O₂)(PPh₃)₂]₂

Formula Unicode styled: 
[Rh(μ₂-Cl)(O₂)(PPh₃)₂]₂
Compound name(s): 
bis-[(μ₂-Chloro)-(dioxygen)-bis(triphenylphosphine)-rhodium]
Central atom: 
Rhodium
Attached groups: 
Cl (μ₂-chloro)
O₂ (dioxygen)
PPh₃ (triphenylphosphane)
Charge on central atom: 
0
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 1
Oxidation Number (ON) (Roman numerals): 
ON: (I)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Rh«V1C5OIE18B5Z0X1L4»
[MLXZ]𝘲 class: 
[MX1L4]
MLXZ class (ENC, equivalent neutral class): 
MX1L4

[Rh(Cl)(H)₂(PPrⁱ₃)₂]

Formula Unicode styled: 
[Rh(Cl)(H)₂(PPrⁱ₃)₂]
Compound name(s): 
Chloro-dihydrido-bis(tri-isopropylphosphine)-rhodium
Central atom: 
Rhodium
Attached groups: 
Cl (chloro)
H (hydrido)
PPrⁱ₃ (triisopropylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 16
Summary of calculated classifications: 
Rh«V3C5OIIIE16B5Z0X3L2»
[MLXZ]𝘲 class: 
[MX3L2]
MLXZ class (ENC, equivalent neutral class): 
MX3L2