5-coordinate: trigonal bipyramid (TBPY-5)

Attached groups:

PMe₃ (trimethylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ru«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

trans–[Ru(CO)₂(C₈H₁₄)₃]

Formula Unicode styled:

trans–[Ru(CO)₂(C₈H₁₄)₃]

Compound name(s):

Dicarbonyl-tris(η²-cyclo-octene)-ruthenium

Central atom:

Attached groups:

C₈H₁₄ (cyclooctene)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ru«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

[Ru(OH)₂(O)₃]²⊖

Formula Unicode styled:

[Ru(OH)₂(O)₃]²⊖

Compound name(s):

dihydroxotrioxoruthenium(2-)

Central atom:

Attached groups:

OH (hydroxo)

O (oxo X₂)

Charge on central atom:

-2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 6

Oxidation Number (ON) (Roman numerals):

ON: (VI)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ru«V⁶C⁵O^VIE¹⁸B⁸Z⁰L⁰X⁸»^2⊖

[MLXZ]𝘲 class:

[MX₈]^2-

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[Ru(O₂)(CO)₂(PPh₃)₂]

Formula Unicode styled:

[Ru(O₂)(CO)₂(PPh₃)₂]

Compound name(s):

Dicarbonyl-peroxo-bis(triphenylphosphine)-ruthenium

Central atom:

Attached groups:

O₂ (peroxo)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ru«V²C⁵O^IIE¹⁸B⁶Z⁰X²L⁴»

[MLXZ]𝘲 class:

[MX₂L₄]

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

[Ru(NO)(Dppe-κ²P)₂]⊕

Formula Unicode styled:

[Ru(NO)(Dppe-κ²P)₂]⊕

Compound name(s):

Nitrosyl-bis(1,2-bis(diphenylphosphino)ethane)-ruthenium(1+)

Central atom:

Dppe (1,2-bis-(diphenylphosphino)ethane-κ²P)

Attached groups:

NO (nitrosyl, linear)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ru«V⁴C⁵O^OE¹⁸B⁷X¹L⁵Z¹»^⊕

[MLXZ]𝘲 class:

[MX₁L₅Z₁]⁺

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

[Ru(CPh=CHPh)(Cl)(CO)(PPh₃)₂]

Formula Unicode styled:

[Ru(CPh=CHPh)(Cl)(CO)(PPh₃)₂]

Compound name(s):

Carbonyl-chloro-(cis-1,2-diphenylethenyl)-bis(triphenylphosphine)-ruthenium

Central atom:

Attached groups:

CPh=CHPh (diphenylvinyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Summary of calculated classifications:

Ru«V²C⁵O^IIE¹⁶B⁵Z⁰X²L³»

[MLXZ]𝘲 class:

[MX₂L₃]

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

[Ru(CO)₃(η⁴-Cot)]

Formula Unicode styled:

[Ru(CO)₃(η⁴-Cot)]

Compound name(s):

(Cyclo-octatetraene)-tricarbonyl-ruthenium

Central atom:

Attached groups:

Cot (η⁴-cyclooctatetraene)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ru«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

[Ru(CO)₂(PPh₃)(η⁴-Cod)]

Formula Unicode styled:

[Ru(CO)₂(PPh₃)(η⁴-Cod)]

Compound name(s):

Dicarbonyl-(η⁴-cyclo-octa-1,5-diene)-triphenylphosphine-ruthenium

Central atom:

Attached groups:

Cod (η²,η²-cycloocta-1,5-diene)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ru«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

[Ru(CO)₂(PEt₃)₃]

Formula Unicode styled:

[Ru(CO)₂(PEt₃)₃]

Compound name(s):

Dicarbonyl-tris(triethylphosphine)-ruthenium

Central atom:

Attached groups:

PEt₃ (triethylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ru«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

[Ru(CO)₂(PEt₃)₂(PhC≡CPh)]

Formula Unicode styled:

[Ru(CO)₂(PEt₃)₂(PhC≡CPh)]

Compound name(s):

Dicarbonyl-(η²-1,2-diphenylethyne)-bis(triethylphosphine)-ruthenium

Central atom:

Attached groups:

PEt₃ (triethylphosphane)

PhC≡CPh (diphenylethyne)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ru«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

[Ru(CO)(Dmpe)₂]

Formula Unicode styled:

[Ru(CO)(Dmpe)₂]

Compound name(s):

Carbonyl-bis(1,2-bis(dimethylphosphino)-ethane-P,P')-ruthenium

Central atom:

Attached groups:

Dmpe (1,2-bis-(dimethylphosphino)ethane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ru«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

[Ru(Cl)₃(O)₂]⊖

Formula Unicode styled:

[Ru(Cl)₃(O)₂]⊖

Compound name(s):

trichloro-dioxo-ruthenium(1-)

Central atom:

Attached groups:

O (oxo X₂)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 6

Oxidation Number (ON) (Roman numerals):

ON: (VI)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Summary of calculated classifications:

Ru«V⁶C⁵O^VIE¹⁶B⁷Z⁰L⁰X⁷»^⊖

[MLXZ]𝘲 class:

[MX₇]^-

MLXZ class (ENC, equivalent neutral class):

MX₆L₁

[Ru(Cl)(SXylyl)₃(NCMe)]

Formula Unicode styled:

[Ru(Cl)(SXylyl)₃(NCMe)]

Compound name(s):

Acetonitrile-chloro-tris(2,6-dimethylphenylthiolato)-ruthenium

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 14

Summary of calculated classifications:

Ru«V⁴C⁵O^IVE¹⁴B⁵Z⁰X⁴L¹»

[MLXZ]𝘲 class:

[MX₄L₁]

MLXZ class (ENC, equivalent neutral class):

MX₄L₁

[Ru(Cl)(SO₂-κS)(PPh₃)₂(NO)]

Formula Unicode styled:

[Ru(Cl)(SO₂-κS)(PPh₃)₂(NO)]

Compound name(s):

Chloro-nitrosyl-(η²-sulfur dioxide)-bis(triphenylphosphine)-ruthenium

Central atom:

Attached groups:

SO₂ (dioxo-sulfur-κS)

NO (nitrosyl, linear)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ru«V⁴C⁵O^OE¹⁸B⁷X²L⁴Z¹»

[MLXZ]𝘲 class:

[MX₂L₄Z₁]

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

[Ru(Cl)(PPh₃)₂(SO)(NO)]

Formula Unicode styled:

[Ru(Cl)(PPh₃)₂(SO)(NO)]

Compound name(s):

Chloro-nitrosyl-(sulfur monoxide)-bis(triphenylphosphine)-ruthenium

Central atom:

Attached groups:

SO (oxido-sulfur L type)

NO (nitrosyl, linear)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ru«V⁴C⁵O^OE¹⁸B⁷X²L⁴Z¹»

[MLXZ]𝘲 class:

[MX₂L₄Z₁]

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

[Ru(C₂H₄)(PMe₃)₄]

Formula Unicode styled:

[Ru(C₂H₄)(PMe₃)₄]

Compound name(s):

(η²-Ethene)-tetrakis(trimethylphosphine)-ruthenium

Central atom:

PMe₃ (trimethylphosphane)

Attached groups:

C₂H₄ (ethene X₂)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 6

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ru«V²C⁶O^IIE¹⁸B⁶Z⁰X²L⁴»

[MLXZ]𝘲 class:

[MX₂L₄]

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

[Ru(C₂F₄)(CO)₂(PPh₃)₂]

Formula Unicode styled:

[Ru(C₂F₄)(CO)₂(PPh₃)₂]

Compound name(s):

(η²Tetrafluoroethylene)-dicarbonyl-bis(triphenylphosphine)-ruthenium

Central atom:

Attached groups:

C₂F₄ (tetrafluoroethene)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ru«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

[Ru(C≡CTol)(Cl)(SXylyl)₃]⊖

Formula Unicode styled:

[Ru(C≡CTol)(Cl)(SXylyl)₃]⊖

Compound name(s):

chloro-(4-methylphenylacetylide)-tris(2,6-dimethylphenylthiolato)-ruthenium(1-)

Central atom:

Attached groups:

C≡CTol (tolylethynyl)

SXylyl (xylylthio)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 14

Summary of calculated classifications:

Ru«V⁴C⁵O^IVE¹⁴B⁵Z⁰L⁰X⁵»^⊖

[MLXZ]𝘲 class:

[MX₅]^-

MLXZ class (ENC, equivalent neutral class):

MX₄L₁

[Ru(=CF₂)(CO)₂(PPh₃)₂]

Formula Unicode styled:

[Ru(=CF₂)(CO)₂(PPh₃)₂]

Compound name(s):

Dicarbonyl-difluorocarbene-bis(triphenylphosphine)-ruthenium

Central atom:

=CF₂ (difluoromethylidene)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ru«V²C⁵O^IIE¹⁸B⁶Z⁰X²L⁴»

[MLXZ]𝘲 class:

[MX₂L₄]

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

equatorial–[Ru{Fe(CO)₄}(CO)₄]²⊖

Formula Unicode styled:

equatorial–[Ru{Fe(CO)₄}(CO)₄]²⊖

Compound name(s):

(tetracarbonyl-iron)-tetracarbonyl-ruthenium(2-)

Central atom:

Fe(CO)₄ (tetracarbonyliron)

Attached groups:

(CO)₄ (tetracarbonyl, (C≡O)₄ trigonal bipyramidal C3v Ⓢ)

Charge on central atom:

-2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (-II)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: