5-coordinate: trigonal bipyramid (TBPY-5)

N(SiMe₃)₂ (bis(trimethylsilyl)amino: planar)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

OC₆H₃Buᵗ₂-2,6 (di-t-butylphenoxy-2,6)

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 23

Summary of calculated classifications:

Dy«V³C⁵O^IIIE²³B⁷Z⁰X³L⁴»

[MLXZ]𝘲 class:

[MX₃L₄]

MLXZ class (ENC, equivalent neutral class):

MX₃L₄

[Dy(OC₆H₃Buᵗ₂-2,6)₂(Thf)(μ₂-OH)]₂

Formula Unicode styled:

[Dy(OC₆H₃Buᵗ₂-2,6)₂(Thf)(μ₂-OH)]₂

Compound name(s):

bis-[(μ-hydroxo)-bis(2,6-di-t-butylphenolato)-(tetrahydrofuran)-dysprosium]

Central atom:

Dysprosium

Attached groups:

OH (μ₂-hydroxy)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 19

Summary of calculated classifications:

Dy«V³C⁵O^IIIE¹⁹B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

trans–[Ho(CH₂SiMe₃)₃(OPCy₃)₂]

Formula Unicode styled:

trans–[Ho(CH₂SiMe₃)₃(OPCy₃)₂]

Compound name(s):

bis[tricyclohexyl(oxo)-phosphine]-tris[(trimethylsilyl)methyl]-holmium

Central atom:

Holmium

Attached groups:

OPCy₃ (tricyclohexylphosphane oxide)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 20

Summary of calculated classifications:

Ho«V³C⁵O^IIIE²⁰B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

trans–[Ho(CH₂SiMe₃)₃(Thf)₂]

Formula Unicode styled:

trans–[Ho(CH₂SiMe₃)₃(Thf)₂]

Compound name(s):

bis(tetrahydrofuran)-tris[(trimethylsilyl)methyl]-holmium

Central atom:

Holmium

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 20

Summary of calculated classifications:

Ho«V³C⁵O^IIIE²⁰B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

trans–[Tm(CH₂SiMe₃)₃(Thf)₂]

Formula Unicode styled:

trans–[Tm(CH₂SiMe₃)₃(Thf)₂]

Compound name(s):

bis(tetrahydrofuran)-tris[(trimethylsilyl)methyl]-thulium

Central atom:

Thulium

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 22

Summary of calculated classifications:

Tm«V³C⁵O^IIIE²²B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

trans–[Tb(CH₂SiMe₃)₃(Thf)₂]

Formula Unicode styled:

trans–[Tb(CH₂SiMe₃)₃(Thf)₂]

Compound name(s):

bis(tetrahydrofuran)-tris[(trimethylsilyl)methyl]-terbium

Central atom:

Terbium

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

NPh₂ (diphenylamino: planar)

Summary of calculated classifications:

Tb«V³C⁵O^IIIE¹⁸B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[U(NPh₂)₃(μ₂–O)]₂²⊖

Formula Unicode styled:

[U(NPh₂)₃(μ₂–O)]₂²⊖

Compound name(s):

bis-[(μ₂-oxo-tris(diphenylamido)-uranium(-1)]

Central atom:

Uranium

Attached groups:

O (μ₂–oxo X+X)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

NEt₂ (diethylamino: planar)

Summary of calculated classifications:

U«V⁴C⁵O^IVE¹⁸B⁸Z⁰X⁵L³»^⊖

[MLXZ]𝘲 class:

[MX₅L₃]^-

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[U(NEt₂)₃(μ₂-NEt₂)]₂

Formula Unicode styled:

[U(NEt₂)₃(μ₂-NEt₂)]₂

Compound name(s):

bis-[μ₂-diethylamido-tris(diethylamido-uranium]

Central atom:

Uranium

Attached groups:

NEt₂ (μ₂-diethylamino)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

N(SiMe₃)₂ (bis(trimethylsilyl)amino: planar)

Summary of calculated classifications:

U«V⁴C⁵O^IVE¹⁸B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[U(F){N(SiMe₃)₂}₃(=NSiMe₃)]

Formula Unicode styled:

[U(F){N(SiMe₃)₂}₃(=NSiMe₃)]

Compound name(s):

Fluoro-tris(bis(trimethylsilyl)amido)-trimethylsilylimido-uranium

Central atom:

Uranium

Attached groups:

F (fluoro)

=NSiMe₃ (trimethylsilylimino)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 6

Oxidation Number (ON) (Roman numerals):

ON: (VI)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

U«V⁶C⁵O^VIE¹⁸B⁹Z⁰X⁶L³»

[MLXZ]𝘲 class:

[MX₆L₃]

MLXZ class (ENC, equivalent neutral class):

MX₆L₃

[Tl(Mes)₂{(Cl)₃Tl(Mes)}]

Formula Unicode styled:

[Tl(Mes)₂{(Cl)₃Tl(Mes)}]

Compound name(s):

Dimesityl-thallium(1+)

Central atom:

Thallium

Attached groups:

Mes (mesityl)

Charge on central atom:

1

Compound type:

Catena-1D

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 10

Summary of calculated classifications:

Tl«V³C⁵O^IIIE¹⁰B⁵Z⁰X²L³»^⊕

[MLXZ]𝘲 class:

[MX₂L₃]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Cr(Ph)₅]²⊖

Formula Unicode styled:

[Cr(Ph)₅]²⊖

Compound name(s):

pentaphenylchromium(2-)

Central atom:

Chromium

Attached groups:

Ph (phenyl)

Charge on central atom:

-2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 13

Summary of calculated classifications:

Cr«V³C⁵O^IIIE¹³B⁵Z⁰L⁰X⁵»^2⊖

[MLXZ]𝘲 class:

[MX₅]^2-

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Tc(Cl)₂(Dppe-κ²P)]₂

Formula Unicode styled:

[Tc(Cl)₂(Dppe-κ²P)]₂

Compound name(s):

bis-[(μ₂-1,2-bis(Diphenylphosphino)ethane)-dichloro-technetium(Tc≡Tc)]

Central atom:

Attached groups:

Dppe (1,2-bis-(diphenylphosphino)ethane-κ²P)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Tc«V⁵C⁵O^IIE¹⁶B⁷Z⁰X⁵L²»

[MLXZ]𝘲 class:

[MX₅L₂]

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

[Tc(Cl)₂(PMePh₂)₂]₂

Formula Unicode styled:

[Tc(Cl)₂(PMePh₂)₂]₂

Compound name(s):

bis-[dichloro-bis-(methyldiphenylphosphine)-technetium(Tc≡Tc)]

Central atom:

Attached groups:

PMePh₂ (methyldiphenylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Tc«V⁵C⁵O^IIE¹⁶B⁷Z⁰X⁵L²»

[MLXZ]𝘲 class:

[MX₅L₂]

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

[Tc(Cl)₂(PMe₃)₂]₂

Formula Unicode styled:

[Tc(Cl)₂(PMe₃)₂]₂

Compound name(s):

bis-[dichloro-bis-(trimethylphosphine)-technetium(Tc≡Tc)]

Central atom:

Attached groups:

PMe₃ (trimethylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Tc«V⁵C⁵O^IIE¹⁶B⁷Z⁰X⁵L²»

[MLXZ]𝘲 class:

[MX₅L₂]

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

[Tc(Cl)₂(PMe₂Ph)₂]₂

Formula Unicode styled:

[Tc(Cl)₂(PMe₂Ph)₂]₂

Compound name(s):

bis-[dichloro-bis-(dimethylphenylphosphine)-technetium(Tc≡Tc)]

Central atom:

Attached groups:

PMe₂Ph (dimethylphenylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Tc«V⁵C⁵O^IIE¹⁶B⁷Z⁰X⁵L²»

[MLXZ]𝘲 class:

[MX₅L₂]

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

[Tc(Cl)₂(PEt₃)₂]₂

Formula Unicode styled:

[Tc(Cl)₂(PEt₃)₂]₂

Compound name(s):

bis-[dichloro-bis-(triethylphosphine)-technetium(Tc≡Tc)]

Central atom:

Attached groups:

PEt₃ (triethylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

(CO)₄ (tetracarbonyl, (C≡O)₄ trigonal bipyramidal C3v Ⓢ)

Summary of calculated classifications:

Tc«V⁵C⁵O^IIE¹⁶B⁷Z⁰X⁵L²»

[MLXZ]𝘲 class:

[MX₅L₂]

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

[Os(CO)₄]₂²⊖

Formula Unicode styled:

[Os(CO)₄]₂²⊖

Compound name(s):

bis-[tetracarbonyl-osmium(1-)] (Os—Os)

Central atom:

Osmium

Attached groups:

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (-I)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

NC₅H₃Me₂ (3,5-diimethylpyridine)

Summary of calculated classifications:

Os«V⁴C⁵O^-IE¹⁸B⁷X¹L⁴Z²»^⊖

[MLXZ]𝘲 class:

[MX₁L₄Z₂]^-

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

[Ni(NCS-κN)₂(NC₅H₃Me₂)₃]

Formula Unicode styled:

[Ni(NCS-κN)₂(NC₅H₃Me₂)₃]

Compound name(s):

tris(3,5-Dimethylpiperidine)-bis(isothiocyanato)-nickel

Central atom:

Nickel

Attached groups:

NCS (isothiocyanato-κN)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ni«V²C⁵O^IIE¹⁸B⁵Z⁰X²L³»

[MLXZ]𝘲 class:

[MX₂L₃]

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

axial–[Fe{S(CH₂)₄S-κS}(CO)₄]

Formula Unicode styled:

axial–[Fe{S(CH₂)₄S-κS}(CO)₄]

Compound name(s):

1,3-Dithiane-tetracarbonyl-iron

Central atom:

Iron

Attached groups:

S(CH₂)₄S (dithiane-κS)

CO (carbonyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 0

Oxidation Number (ON) (Roman numerals):

ON: (O)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

NMe₂ (dimethylamino: planar)

Summary of calculated classifications:

Fe«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

[Zr(I)(NMe₂)₂(μ₂-NMe₂)]₂

Formula Unicode styled:

[Zr(I)(NMe₂)₂(μ₂-NMe₂)]₂

Compound name(s):

bis-[(μ₂-Dimethylamido)-bis(dimethylamido)-iodo-zirconium]

Central atom:

Zirconium

Attached groups:

I (iodo)

NMe₂ (μ₂-dimethylamino)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):