5-coordinate: square-based pyramid (SPY-5)

[Cu(N₂C₃H₄)(Phen)₂]²⊕

Formula Unicode styled: 
[Cu(N₂C₃H₄)(Phen)₂]²⊕
Compound name(s): 
(Imidazole)-bis(1,10-phenanthroline)-copper(2+)
Central atom: 
Copper
Attached groups: 
N₂C₃H₄ (Imidazole)
Phen (phenanthroline)
Charge on central atom: 
2
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 19
Summary of calculated classifications: 
Cu«V2C5OIIE19B5Z0X0L5»2⊕
[MLXZ]𝘲 class: 
[ML5]2+
MLXZ class (ENC, equivalent neutral class): 
MX2L3

cis,cis–[Cu(Ox)(OH₂)(Bpy)]

Formula Unicode styled: 
cis,cis–[Cu(Ox)(OH₂)(Bpy)]
Compound name(s): 
Aqua-(2,2'-bipyridyl)-(oxalato-O,O')-copper
Central atom: 
Copper
Attached groups: 
Ox (oxalato)
OH₂ (aqua)
Bpy (bipyridine)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 19
Summary of calculated classifications: 
Cu«V2C5OIIE19B5Z0X2L3»
[MLXZ]𝘲 class: 
[MX2L3]
MLXZ class (ENC, equivalent neutral class): 
MX2L3

cis,cis–[Cu(OH₂)(Acac)(Bpy)]⊕

Formula Unicode styled: 
cis,cis–[Cu(OH₂)(Acac)(Bpy)]⊕
Compound name(s): 
Acetylacetonato-aqua-(2,2'-bipyridine)-copper(1+)
Central atom: 
Copper
Attached groups: 
OH₂ (aqua)
Acac (acetylacetonato)
Bpy (bipyridine)
Charge on central atom: 
1
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 19
Summary of calculated classifications: 
Cu«V2C5OIIE19B5Z0X1L4»⊕
[MLXZ]𝘲 class: 
[MX1L4]+
MLXZ class (ENC, equivalent neutral class): 
MX2L3

cis–[Cu(Ox)(N₂C₃H₄)₂(OH₂)]

Formula Unicode styled: 
cis–[Cu(Ox)(N₂C₃H₄)₂(OH₂)]
Compound name(s): 
bis(Imidazole)-aqua-oxalato-copper
Central atom: 
Copper
Attached groups: 
Ox (oxalato)
N₂C₃H₄ (Imidazole)
OH₂ (aqua)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 19
Summary of calculated classifications: 
Cu«V2C5OIIE19B5Z0X2L3»
[MLXZ]𝘲 class: 
[MX2L3]
MLXZ class (ENC, equivalent neutral class): 
MX2L3

catena–1D-[Cu(ONO₂-κO)₂{μ₂-N(CH)₄N}₂]

Formula Unicode styled: 
catena–1D-[Cu(ONO₂-κO)₂{μ₂-N(CH)₄N}₂]
Compound name(s): 
catena-[(μ₂-Pyrimidine-N,N')-dinitrato-(pyrimidine-N)-copper]
Central atom: 
Copper
Attached groups: 
NO₃ (nitrato-κO)
N(CH)₄N (μ₂-pyrimidine)
Charge on central atom: 
0
Compound type: 
Catena-1D
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 21
Summary of calculated classifications: 
Cu«V2C6OIIE21B6Z0X2L4»
[MLXZ]𝘲 class: 
[MX2L4]
MLXZ class (ENC, equivalent neutral class): 
MX2L4

catena–1D-[Cu(μ₂-N₃)(Py)₃]⊕

Formula Unicode styled: 
catena–1D-[Cu(μ₂-N₃)(Py)₃]⊕
Compound name(s): 
catena-[(μ₂-Azido-N,N'')-tripyridyl-copper(1+)]
Central atom: 
Copper
Attached groups: 
N₃ (μ₂-azido)
Py (pyridine)
Charge on central atom: 
1
Compound type: 
Catena-1D
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 19
Summary of calculated classifications: 
Cu«V2C5OIIE19B5Z0X1L4»⊕
[MLXZ]𝘲 class: 
[MX1L4]+
MLXZ class (ENC, equivalent neutral class): 
MX2L3

catena–1D-[Cu(Cl)(μ₂-Cl)(Bpy)]

Formula Unicode styled: 
catena–1D-[Cu(Cl)(μ₂-Cl)(Bpy)]
Compound name(s): 
catena-[(μ2-Chloro)-(2,2'-bipyridine-N,N')-chloro-copper]
Central atom: 
Copper
Attached groups: 
Cl (chloro)
Cl (μ₂-chloro)
Bpy (bipyridine)
Charge on central atom: 
0
Compound type: 
Catena-1D
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 19
Summary of calculated classifications: 
Cu«V2C5OIIE19B5Z0X2L3»
[MLXZ]𝘲 class: 
[MX2L3]
MLXZ class (ENC, equivalent neutral class): 
MX2L3

catena–1D-[Cu(Br)(μ₂-O₂CMe)(NH₃)₂]

Formula Unicode styled: 
catena–1D-[Cu(Br)(μ₂-O₂CMe)(NH₃)₂]
Compound name(s): 
catena-[(μ₂-Acetato-O,O')-bromo-diammine-copper]
Central atom: 
Copper
Attached groups: 
Br (bromo)
O₂CMe (μ₂-acetato)
NH₃ (ammine)
Charge on central atom: 
0
Compound type: 
Catena-1D
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 19
Summary of calculated classifications: 
Cu«V2C5OIIE19B5Z0X2L3»
[MLXZ]𝘲 class: 
[MX2L3]
MLXZ class (ENC, equivalent neutral class): 
MX2L3

[Gd(OC₆H₃Prⁱ₂-2,6)₃(Thf)₃]

Formula Unicode styled: 
[Gd(OC₆H₃Prⁱ₂-2,6)₃(Thf)₃]
Compound name(s): 
bis(Tetrahydrofuran)-tris(2,6-di-isopropylphenoxy)-gadolinium
Central atom: 
Gadolinium
Attached groups: 
OC₆H₃Prⁱ₂-2,6 (di-isopropylphenoxy-2,6)
Thf (tetrahydrofuran)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 19
Summary of calculated classifications: 
Gd«V3C6OIIIE19B6Z0X3L3»
[MLXZ]𝘲 class: 
[MX3L3]
MLXZ class (ENC, equivalent neutral class): 
MX3L3

[Eu(OC₆H₃Buᵗ₂-2,6)₂(Thf)₃]

Formula Unicode styled: 
[Eu(OC₆H₃Buᵗ₂-2,6)₂(Thf)₃]
Compound name(s): 
bis(2,6-Di-t-butylphenolato)-tris(tetrahydrofuran)-europium
Central atom: 
Europium
Attached groups: 
OC₆H₃Buᵗ₂-2,6 (di-t-butylphenoxy-2,6)
Thf (tetrahydrofuran)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 17
Summary of calculated classifications: 
Eu«V2C5OIIE17B5Z0X2L3»
[MLXZ]𝘲 class: 
[MX2L3]
MLXZ class (ENC, equivalent neutral class): 
MX2L3

[Nd{N(SiHMe₂)₂}₃(Phen)]

Formula Unicode styled: 
[Nd{N(SiHMe₂)₂}₃(Phen)]
Compound name(s): 
tris(bis(Dimethylsilyl)amido)-(1,10-phenanthroline)-neodymium
Central atom: 
Neodymium
Attached groups: 
N(SiHMe₂)₂ (bis(dimethylsilyl)amino: planar)
Phen (phenanthroline)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 19
Summary of calculated classifications: 
Nd«V3C5OIIIE19B8Z0X3L5»
[MLXZ]𝘲 class: 
[MX3L5]
MLXZ class (ENC, equivalent neutral class): 
MX3L5

[Nd(OC₆H₃Ph₂-2,6)₃(Dme)]

Formula Unicode styled: 
[Nd(OC₆H₃Ph₂-2,6)₃(Dme)]
Compound name(s): 
(1,2-Dimethoxyethane)-tris(2,6-diphenolato)-neodymium
Central atom: 
Neodymium
Attached groups: 
OC₆H₃Ph₂-2,6 (diphenylphenoxy-2,6)
Dme (dimethoxyethane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 13
Summary of calculated classifications: 
Nd«V3C5OIIIE13B5Z0X3L2»
[MLXZ]𝘲 class: 
[MX3L2]
MLXZ class (ENC, equivalent neutral class): 
MX3L2

[Pd(SCH=CHS)₂]₂

Formula Unicode styled: 
[Pd(SCH=CHS)₂]₂
Compound name(s): 
bis-[di(ethylene-1,2-dithiolene) palladium]
Central atom: 
Palladium
Attached groups: 
SCH=CHS (ethenedithiolato-κ²S)
Charge on central atom: 
0
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 5
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 15
Summary of calculated classifications: 
Pd«V5C5OIVE15B5Z0L0X5»
[MLXZ]𝘲 class: 
[MX5]
MLXZ class (ENC, equivalent neutral class): 
MX5

[Pd(Dpae-κ²As)([9]aneS₃-κ³S)]²⊕

Formula Unicode styled: 
[Pd(Dpae-κ²As)([9]aneS₃-κ³S)]²⊕
Compound name(s): 
(1,2-bis(Diphenylarsino)ethane-As,As')-(1,4,7-trithionane)-palladium(2+)
Central atom: 
Palladium
Attached groups: 
Dpae (bis(diphenylarsino)ethane-κ²As)
[9]aneS₃ (1,4,7-trithiocyclononane-κ³S)
Charge on central atom: 
2
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Pd«V2C5OIIE18B5Z0X0L5»2⊕
[MLXZ]𝘲 class: 
[ML5]2+
MLXZ class (ENC, equivalent neutral class): 
MX2L3

[Pd(Cl)₂(PMe₂Ph)₃]

Formula Unicode styled: 
[Pd(Cl)₂(PMe₂Ph)₃]
Compound name(s): 
Dichloro-tris(dimethylphenylphosphine) palladium
Central atom: 
Palladium
Attached groups: 
Cl (chloro)
PMe₂Ph (dimethylphenylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Pd«V2C5OIIE18B5Z0X2L3»
[MLXZ]𝘲 class: 
[MX2L3]
MLXZ class (ENC, equivalent neutral class): 
MX2L3

trans,trans–[Rh(NO)(O₂CC₆F₅-κO)₂(PPh₃)₂]

Formula Unicode styled: 
trans,trans–[Rh(NO)(O₂CC₆F₅-κO)₂(PPh₃)₂]
Compound name(s): 
Nitrosyl-bis(trifluoroacetato-O)-bis(triphenylphosphine)-rhodium
Central atom: 
Rhodium
Attached groups: 
NO (nitrosyl X)
O₂CC₆F₅ (pentafluorobenzoato-κO)
PPh₃ (triphenylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 16
Summary of calculated classifications: 
Rh«V3C5OIIIE16B5Z0X3L2»
[MLXZ]𝘲 class: 
[MX3L2]
MLXZ class (ENC, equivalent neutral class): 
MX3L2

trans,trans–[Rh(I)₂(Ph)(PPh₃)₂]

Formula Unicode styled: 
trans,trans–[Rh(I)₂(Ph)(PPh₃)₂]
Compound name(s): 
Diiodo-bis(triphenylphosphine)-phenyl-rhodium
Central atom: 
Rhodium
Attached groups: 
I (iodo)
Ph (phenyl)
PPh₃ (triphenylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 16
Summary of calculated classifications: 
Rh«V3C5OIIIE16B5Z0X3L2»
[MLXZ]𝘲 class: 
[MX3L2]
MLXZ class (ENC, equivalent neutral class): 
MX3L2

trans,trans–[Rh(I)₂(Me)(PPh₃)₂]

Formula Unicode styled: 
trans,trans–[Rh(I)₂(Me)(PPh₃)₂]
Compound name(s): 
Di-iodo-methyl-bis(triphenylphosphine)-rhodium
Central atom: 
Rhodium
Attached groups: 
I (iodo)
Me (methyl)
PPh₃ (triphenylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 16
Summary of calculated classifications: 
Rh«V3C5OIIIE16B5Z0X3L2»
[MLXZ]𝘲 class: 
[MX3L2]
MLXZ class (ENC, equivalent neutral class): 
MX3L2

trans,trans–[Rh(Cl)₂(Ph)(PPh₃)₂]

Formula Unicode styled: 
trans,trans–[Rh(Cl)₂(Ph)(PPh₃)₂]
Compound name(s): 
Dichloro-phenyl-bis(triphenylphosphine)-rhodium
Central atom: 
Rhodium
Attached groups: 
Cl (chloro)
Ph (phenyl)
PPh₃ (triphenylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 16
Summary of calculated classifications: 
Rh«V3C5OIIIE16B5Z0X3L2»
[MLXZ]𝘲 class: 
[MX3L2]
MLXZ class (ENC, equivalent neutral class): 
MX3L2

trans,trans–[Rh(Cl)₂(H)(PPrⁱ₃)₂]

Formula Unicode styled: 
trans,trans–[Rh(Cl)₂(H)(PPrⁱ₃)₂]
Compound name(s): 
Dichloro-hydrido-bis(tri-isopropylphosphine)-rhodium
Central atom: 
Rhodium
Attached groups: 
Cl (chloro)
H (hydrido)
PPrⁱ₃ (triisopropylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 16
Summary of calculated classifications: 
Rh«V3C5OIIIE16B5Z0X3L2»
[MLXZ]𝘲 class: 
[MX3L2]
MLXZ class (ENC, equivalent neutral class): 
MX3L2